The determination of urea in soil extracts and related samples—a review

Although the dominant methods for the determination of urea in clinical applications incorporate selective enzymatic hydrolysis of urea, the determination of urea in soil extracts is complicated by the presence of urease inhibitors. The spectrophotometric determination of urea with an acidic solution diacetyl monoxime and semicarbazide is a viable option but traditional manual procedures are time-consuming. New variations on these procedures, based on microplates or flow-injection analysis methodologies, allow a far greater number of samples to be analysed with high precision and sensitivity.

[1]  J. Balthrop,et al.  Liquid chromatographic determination of urea in water-soluble urea-formaldehyde fertilizer products and in aqueous urea solutions: collaborative study. , 2004, Journal of AOAC International.

[2]  Y. Hsu,et al.  A simple method to determine urea concentration using intact Helicobacter pylori and BromoCresol Purple as a pH indicator , 2000, Biotechnology Letters.

[3]  J. M. Bremner Recent research on problems in the use of urea as a nitrogen fertilizer , 1995, Fertilizer research.

[4]  K. Weier Nitrogen use and losses in agriculture in subtropical Australia , 2004, Fertilizer research.

[5]  R. Littell,et al.  New Tools for the Analysis and Characterization of Slow-Release Fertilizers , 2003 .

[6]  P. S. Francis,et al.  Monitoring urea levels during haemodialysis with a pulsed-flow chemiluminescence analyser , 2002 .

[7]  Paul S. Francis,et al.  Analytical methodology for the determination of urea: current practice and future trends , 2002 .

[8]  C. Watson Urease activity and inhibition - principles and practice. , 2000 .

[9]  W. H. Patrick,et al.  Modeling urea, ammonium, and nitrate transport and transformations in flooded soil columns , 1999 .

[10]  M. D. L. Castro,et al.  Nitrogen speciation analysis in solid samples by integrated pervaporation and detection , 1997 .

[11]  J. Lima,et al.  Potentiometric FIA System with Reactor Based on Natural Urease Source and Tubular Detector of Ammonium Ions. Determination of Urea in Fertilizers , 1997 .

[12]  W. Carlile,et al.  A MICROPLATE METHOD FOR DETERMINATION OF UREA AND ITS USE IN STUDIES OF NITROGEN MINERALISATION IN GROWING MEDIA , 1997 .

[13]  A. Aminot Assessment of Equipment for the Determination of Nutrients in Marine Waters: A Case Study of the Microplate Technique , 1996 .

[14]  N. Greenan,et al.  A microscale method for colorimetric determination of urea in soil extracts , 1995 .

[15]  W. Baethgen,et al.  A procedure for sampling the soil microenvironment at the site of fertilizer application , 1994 .

[16]  Xincheng Hu,et al.  Special Articles: Environmental Sciences and Analytical Chemistry. Sensitive determination of humic acid in natural water by chemiluminescence-flow injection method. , 1994 .

[17]  Y. Maeda,et al.  Determination of trace amounts of urea by using flow injection with chemiluminescence detection. , 1994, The Analyst.

[18]  P. Vadgama,et al.  Analytical Reviews in Clinical Biochemistry: The Estimation of Urea , 1992, Annals of clinical biochemistry.

[19]  F. Galgani,et al.  A new application of microplate reader in oceanography : colorimetric assays to determine some nitrogen forms , 1991 .

[20]  D. Sullivan,et al.  Flow injection analysis of urea nitrogen in soil extracts , 1991 .

[21]  G. Guilbault,et al.  A Urea Fiber Optic Biosensor Based on Absorption Measurement , 1990 .

[22]  A. Gómez-Hens,et al.  Kinetic determination of urea in serum by stopped-flow spectrophotometry , 1990 .

[23]  Praveen Kumar,et al.  A modification of Douglas and Bremner method for colorimetric estimation of urea , 1989 .

[24]  M. D. L. Castro,et al.  Simultaneous determination of ammonia and urea with an asymmetric merging zones/flow-injection configuration , 1989 .

[25]  C. Nagel,et al.  Colorimetric Determination of Urea in Wine , 1989, American Journal of Enology and Viticulture.

[26]  S. Goyal,et al.  Simultaneous Determination of Urea and Ammonia Nitrogen in Soil Extracts and Water by High Performance Liquid Chromatography , 1988 .

[27]  N. M. Price,et al.  Comparison of methods for the analysis of dissolved urea in seawater , 1987 .

[28]  G. Elliott Urea Hydrolysis in Potting Media , 1986, Journal of the American Society for Horticultural Science.

[29]  R. W. Frei,et al.  Miniaturization of solid-phase reactors for on-line post-column derivatization in narrow-bore liquid chromatography , 1985 .

[30]  Dorita E. Menconi Determination of urea in fertilizers using ion chromatography coupled with conductometric detection , 1985 .

[31]  S. Patnaik,et al.  Determination of Urea-N by Steam Distillation , 1985 .

[32]  S. Uchiyama,et al.  Determination of urea by ion chromatography with an immobilized urease reactor , 1985 .

[33]  Michiko Sasaki,et al.  Liquid Chromatographic Determination of Ammoniacal and Urea Nitrogen in Fertilizer , 1984 .

[34]  Mark L. Dietz,et al.  Determination of ammonium, nitrate, and urea nitrogen in fertilizer by gas-phase molecular absorption spectrometry , 1983 .

[35]  M. Wilding,et al.  Spectrophotometric determination of urea in ammonium nitrate fertilizers , 1982 .

[36]  A. Butler,et al.  The chemistry of the diacetyl monoxime assay of urea in biological fluids. , 1981, Clinica chimica acta; international journal of clinical chemistry.

[37]  T. Yajima,et al.  Clinical Analysis of Urea Nitrogen. Chemical Structure of the Colored Reaction Product of Urea with Diacetylmonoxime and Thiosemicarbazide , 1981 .

[38]  A. Butler,et al.  Mechanistic studies in the chemistry of urea. Part 8. Reactions of urea, 1-methylurea, and 1,3-dimethylurea with some acyloins and butane-2,3-dione (diacetyl) in acid solution , 1981 .

[39]  M. Rahmatullah,et al.  Improvements in the determination of urea using diacetyl monoxime; methods with and without deproteinisation. , 1980, Clinica chimica acta; international journal of clinical chemistry.

[40]  J. M. Bremner,et al.  A modified diacetyl monoxime method for colorimetric determination of urea in soil extracts1 , 1979 .

[41]  W. Flaig,et al.  Colorimetric Determination of Urea in Soil Extracts Using an Automated System , 1978 .

[42]  A. Barbera,et al.  Determination of Free Urea in Fertilizers Containing Urea Formaldehyde Polymers , 1977 .

[43]  A. B. Onken,et al.  Colorimetric Determinations of Exchangeable Ammonium, Urea, Nitrate, and Nitrite in a Single Soil Extract1,2 , 1977 .

[44]  J. Falls,et al.  Direct Potentiometric Titration of Urea with Urease , 1976 .

[45]  A. Kyllingsbæk Extraction and Colorimetric Determination of Urea in Plants , 1975 .

[46]  T. Sawada,et al.  [Studies on chemical analysis by measurement of reaction rate. II. Conductivity method for determination of urea by using urease (author's transl)]. , 1974, Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan.

[47]  R. Thibert,et al.  A study of the reaction of urea with diacetyl monoxime and diacetyl. , 1972, Clinical biochemistry.

[48]  J. M. Bremner,et al.  A rapid method of evaluating different compounds as inhibitors of urease activity in soils , 1971 .

[49]  J. M. Bremner,et al.  Extraction and colorimetric determination of urea in soils. , 1970 .

[50]  J. M. Bremner,et al.  Colorimetric Determination of Microgram Quantities of Urea , 1970 .

[51]  F. Navari-Izzo,et al.  Spectrophotometric determination of urea in soils and plants. , 1970 .

[52]  Galaev IuV,et al.  Thiosemicarbazide modification of the Firone reaction and its use for carbamide determination , 1969 .

[53]  Y. Ueda,et al.  Color Reaction Product of Urea with Diacetyl Monoxime and Glucuronolactone. I. On the Reaction of Urea Derivatives with Diacetyl Monoxime and Glucuronolactone , 1968 .

[54]  J. M. Bremner,et al.  Determination and Isotope-Ratio Analysis of Different Forms of Nitrogen in Soils: 7. Urea1 , 1967 .

[55]  K. F. Finney,et al.  Spectrophotometric Determination of Urea, Thiourea, and Certain of Their Substitution Products with p-Dimethylaminobenzaldehyde and Diacetylmonoxime. , 1964 .

[56]  G. Watt,et al.  Spectrophotometric Method for Determination of Urea , 1954 .