Technologies and logistics for phosphorus recovery from livestock waste

Phosphorus (P) runoff from livestock waste can trigger algal blooms that adversely affect aquatic life and human health. One strategy to mitigate this problem is to install nutrient recovery technologies that concentrate and mobilize nutrients from nutrient-rich regions to nutrient-deficient ones. We present supply chain design formulations to identify optimal types and locations for P recovery technologies. The formulations capture trade-offs in transportation costs, technology efficiency, investment/operational costs, revenue collected from different recovered products (struvite and nutrient cakes), and environmental impact. Our computational framework is used to analyze the impact of different scenarios for market prices of recovered products, recovery yields, and remediation costs. We find that transportation of waste alone (without any processing) can achieve significant reductions in environmental impact at low cost, but cannot achieve economic sustainability in the long run due to the lack of direct revenue streams. Mechanical separation technologies that recover P in the form of nutrient cakes are low-cost solutions that can achieve high environmental benefits and reduced transportation costs, but revenues are also limited due to low values of the cakes. Struvite crystallization in fluidized beds is found to be a highly attractive option under current struvite prices, but economic sustainability is strongly dependent on yield recoveries (which are currently highly uncertain).

[1]  J. Sáez,et al.  Nutrient removal and sludge production in the coagulation-flocculation process. , 2002, Water research.

[2]  J. Schröder,et al.  Towards global phosphorus security: a systems framework for phosphorus recovery and reuse options. , 2011, Chemosphere.

[3]  R. Gerritse,et al.  Phosphate distribution in animal waste slurries , 1984, The Journal of Agricultural Science.

[4]  R. O'Neill,et al.  The value of the world's ecosystem services and natural capital , 1997, Nature.

[5]  Z. Dou,et al.  Phosphorus concentration and solubility in dairy feces: variability and affecting factors. , 2004, Journal of dairy science.

[6]  Zhongqi He,et al.  Phosphorus distribution in dairy manures. , 2004, Journal of environmental quality.

[7]  K. Svardal,et al.  Effect of precipitating agents on centrifugation and ultrafiltration performance of thin stillage digestate , 2015 .

[8]  G. Yorgey,et al.  REVIEW OF EMERGING NUTRIENT RECOVERY TECHNOLOGIES FOR FARM-BASED ANAEROBIC DIGESTERS AND OTHER RENEWABLE ENERGY SYSTEMS , 2013 .

[9]  D. Cordell,et al.  The story of phosphorus: Global food security and food for thought , 2009 .

[10]  K. G. Karthikeyan,et al.  Influence of anaerobic digestion on dairy manure phosphorus extractability. , 2005 .

[11]  A. Vatn,et al.  Transferring environmental value estimates: Issues and alternatives , 2006 .

[12]  S. Parsons,et al.  Biologically and chemically mediated adsorption and precipitation of phosphorus from wastewater. , 2012, Current opinion in biotechnology.

[13]  Hongjian Lin,et al.  Phosphorus Removal and Recovery from Digestate after Biogas Production , 2015 .

[14]  D S Mavinic,et al.  Phosphorus recovery from wastewater through struvite formation in fluidized bed reactors: a sustainable approach. , 2008, Water science and technology : a journal of the International Association on Water Pollution Research.

[15]  Xiaomei Li,et al.  Nutrient removal from anaerobically digested cattle manure by struvite precipitation , 2006 .

[16]  Keshav Bhattarai,et al.  Geographic information systems (GIS) based model of dairy manure transportation and application with environmental quality consideration. , 2009, Waste management.

[17]  Shu-lin Chen,et al.  Releasing Phosphorus from Calcium for Struvite Fertilizer Production from Anaerobically Digested Dairy Effluent , 2010, Water environment research : a research publication of the Water Environment Federation.

[18]  I. Takács,et al.  Significance of Design and Operational Variables in Chemical Phosphorus Removal , 2008, Water environment research : a research publication of the Water Environment Federation.

[19]  Raymond J. Kopp,et al.  On measuring economic values for nature , 2000 .

[20]  D. B. Nedwell,et al.  Environmental costs of freshwater eutrophication in England and Wales. , 2003, Environmental science & technology.

[21]  Apoorva M. Sampat,et al.  Optimal integrated facility for waste processing , 2017 .

[22]  W. Dodds,et al.  Eutrophication of U.S. freshwaters: analysis of potential economic damages. , 2009, Environmental science & technology.

[23]  R. D. Schuiling,et al.  Recovery of struvite from calf manure , 1999 .

[24]  Erick León,et al.  Bio-waste selection and blending for the optimal production of power and fuels via anaerobic digestion , 2017 .

[25]  M C M van Loosdrecht,et al.  Phosphate and potassium recovery from source separated urine through struvite precipitation. , 2007, Water research.

[26]  Hui Zhang,et al.  Recovery of phosphorus from dairy manure: a pilot-scale study , 2015, Environmental technology.

[27]  L. Hylander,et al.  Phosphorus retention in filter materials for wastewater treatment and its subsequent suitability for plant production. , 2006, Bioresource technology.

[28]  T. Zaleski,et al.  Effect of reactive substrates used for the removal of phosphorus from wastewater on the fertility of acid soils. , 2008, Bioresource technology.

[29]  Klaus D. Timmerhaus,et al.  Plant design and economics for chemical engineers , 1958 .

[30]  K. G. Karthikeyan,et al.  PROBABLE PHOSPHORUS SOLID PHASES AND THEIR STABILITY IN ANAEROBICALLY DIGESTED DAIRY MANURE , 2005 .

[31]  J. Gustafsson,et al.  Phosphate removal by mineral-based sorbents used in filters for small-scale wastewater treatment. , 2008, Water research.

[32]  S. Parsons,et al.  Struvite formation, control and recovery. , 2002, Water research.

[33]  Jessica R. Corman,et al.  Sustainability Challenges of Phosphorus and Food: Solutions from Closing the Human Phosphorus Cycle , 2011 .

[34]  Z. Hu,et al.  Enhancing anaerobic digestibility and phosphorus recovery of dairy manure through microwave-based thermochemical pretreatment. , 2009, Water research.

[35]  K. Lo,et al.  Microwave treatment and struvite recovery potential of dairy manure , 2008, Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes.

[36]  Victor M. Zavala,et al.  Optimization formulations for multi-product supply chain networks , 2017, Comput. Chem. Eng..