Monovalent Cation Doping of CH$_{3}$NH$_{3}$PbI$_{3}$ for Efficient Perovskite Solar Cells

M. Abdi-Jalebi thanks Nava Technology Limited for a PhD scholarship. M.I. Dar and M. Gratzel thank the King Abdulaziz City for Science and Technology (KACST) and Swiss National Science Foundation (SNSF) for financial support. The authors would like to thank Dr. Pierre Mettraux in Molecular and Hybrid Materials Characterization Center, EPFL for carrying out XPS measurements. A. Sadhanala gratefully acknowledges financial support from the Indo-UK APEX project. S.P. Senanayak acknowledges Royal Society London for the Newton Fellowship. R.H. Friend, M. Abdi-Jalebi, and A. Sadhanala would like to acknowledge the support from EPSRC.

[1]  R. Friend,et al.  Impact of a Mesoporous Titania-Perovskite Interface on the Performance of Hybrid Organic-Inorganic Perovskite Solar Cells. , 2016, The journal of physical chemistry letters.

[2]  Mohammad Reza Mohammadi,et al.  Research Data Supporting "A facile low temperature route to deposit TiO2 scattering layer for efficient dye-sensitized solar cells" , 2016 .

[3]  S. Zakeeruddin,et al.  A vacuum flash–assisted solution process for high-efficiency large-area perovskite solar cells , 2016, Science.

[4]  A. Polman,et al.  Photovoltaic materials: Present efficiencies and future challenges , 2016, Science.

[5]  Anders Hagfeldt,et al.  Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5ee03874j Click here for additional data file. , 2016, Energy & environmental science.

[6]  Richard H. Friend,et al.  Photon recycling in lead iodide perovskite solar cells , 2016, Science.

[7]  R. Friend,et al.  Research data supporting "Impact of monovalent cation halide additives on the structural and optoelectronic properties of CH$_{3}$NH$_{3}$PbI$_{3}$ perovskite" , 2016 .

[8]  M. Grätzel,et al.  Understanding the Impact of Bromide on the Photovoltaic Performance of CH3NH3PbI3 Solar Cells , 2015, Advanced materials.

[9]  Henry J Snaith,et al.  Metal-halide perovskites for photovoltaic and light-emitting devices. , 2015, Nature nanotechnology.

[10]  Young Chan Kim,et al.  Compositional engineering of perovskite materials for high-performance solar cells , 2015, Nature.

[11]  H. Zeng,et al.  Strong covalency-induced recombination centers in perovskite solar cell material CH3NH3PbI3. , 2014, Journal of the American Chemical Society.

[12]  Prashant V. Kamat,et al.  Band filling with free charge carriers in organometal halide perovskites , 2014, Nature Photonics.

[13]  M. Green,et al.  The emergence of perovskite solar cells , 2014, Nature Photonics.

[14]  Mercouri G Kanatzidis,et al.  Anomalous band gap behavior in mixed Sn and Pb perovskites enables broadening of absorption spectrum in solar cells. , 2014, Journal of the American Chemical Society.

[15]  Peng Gao,et al.  Mixed-organic-cation perovskite photovoltaics for enhanced solar-light harvesting. , 2014, Angewandte Chemie.

[16]  Double-Layer TiO2 Electrodes with Controlled Phase Composition and Morphology for Efficient Light Management in Dye-Sensitized Solar Cells , 2014, Journal of Cluster Science.

[17]  Yanfa Yan,et al.  Unusual defect physics in CH3NH3PbI3 perovskite solar cell absorber , 2014 .

[18]  Laura M. Herz,et al.  Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber , 2013, Science.

[19]  M. Grätzel,et al.  Title: Long-Range Balanced Electron and Hole Transport Lengths in Organic-Inorganic CH3NH3PbI3 , 2017 .

[20]  H. Snaith Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells , 2013 .

[21]  N. Park,et al.  Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% , 2012, Scientific Reports.

[22]  Tsutomu Miyasaka,et al.  Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. , 2009, Journal of the American Chemical Society.