Utilization of waste cooking oil in a light-duty DI diesel engine for cleaner emissions using bio-derived propanol

Abstract Waste cooking oil from restaurants could be efficiently reused in diesel engines by adding alcohols to make it less dense and viscous instead of preheating or trans-esterification to biodiesel. This study aims to replace diesel with waste cooking oil (WCO) as a reuse fuel and n-propanol as a renewable fuel by up to 50 %vol. Three blends D50-WCO45-PR5, D50-WCO40-PR10 and D50-WCO30-PR20 were prepared with this objective. n-propanol addition was expected to reduce the viscosity of WCO, the carcinogenic smoke emission (via its inbound oxygen) and the greenhouse gas NOx (via its higher vaporization latent heat). Fuel property tests by standard methods indicated that n-propanol reduced viscosity of WCO by 4.5 times along with densities comparable to diesel. Engine testing at the entire load spectrum revealed that, addition of n-propanol reduced NOx, smoke, CO and CO2 emissions with respect to diesel. However, addition of n-propanol to D50-WCO50 caused an increase in BSFC for all blends. BTE improved with n-propanol addition to D50-WCO50 at all loads but remained lower than diesel. Smoke emissions gradually decreased with increase in n-propanol fraction for all blends. HC emissions increased for all blends and CO emissions lowered with n-propanol addition. Both the greenhouse gas emissions of CO2 and NOx reduced with n-propanol addition. Thus WCO could be efficiently reused to reduce harmful emissions and reduce fossil fuel dependence with n-propanol addition instead of being an environmental hazard contaminating land and water resources.

[1]  S. Saravanan,et al.  Use of higher alcohol biofuels in diesel engines: A review , 2016 .

[2]  K. Ramesh,et al.  Experimental evaluation on performance, combustion behavior and influence of in-cylinder temperature on NOx emission in a D.I diesel engine using thermal imager for various alternate fuel blends , 2017 .

[3]  S. Bari,et al.  Effects of preheating of crude palm oil (CPO) on injection system, performance and emission of a diesel engine , 2002 .

[4]  H. Sharon,et al.  Fueling a stationary direct injection diesel engine with diesel-used palm oil–butanol blends – An experimental study , 2013 .

[5]  Aleš Hribernik,et al.  Performance and Exhaust Emissions of an Indirect-Injection (IDI) Diesel Engine When Using Waste Cooking Oil as Fuel , 2009 .

[6]  Chun-de Yao,et al.  Effects of methanol to diesel ratio and diesel injection timing on combustion, performance and emissions of a methanol port premixed diesel engine , 2016 .

[7]  R. Moffat Using Uncertainty Analysis in the Planning of an Experiment , 1985 .

[8]  M. Kumar,et al.  A comprehensive study on performance, emission and combustion behavior of a compression ignition engine fuelled with WCO (waste cooking oil) emulsion as fuel , 2014 .

[9]  Zhen Huang,et al.  Regulated and unregulated emissions from a diesel engine fueled with biodiesel and biodiesel blended with methanol , 2009 .

[10]  B. Sethuramasamyraja,et al.  Diesel reformulation using bio-derived propanol to control toxic emissions from a light-duty agricultural diesel engine , 2017, Environmental Science and Pollution Research.

[11]  M. Nakajima,et al.  The effects of ethanol content and emulsifying agent concentration on the stability of vegetable oil-ethanol emulsions , 2001 .

[12]  Mark R. Riley,et al.  Pretreatment of yellow grease for efficient production of fatty acid methyl esters. , 2009 .

[13]  T. Doğan The testing of the effects of cooking conditions on the quality of biodiesel produced from waste cooking oils. , 2016 .

[14]  D. Rana,et al.  Effect of lignin-derived cyclohexanol on combustion, performance and emissions of a direct-injection agricultural diesel engine under naturally aspirated and exhaust gas recirculation (EGR) modes , 2016 .

[15]  D. Sabatini,et al.  Phase Behaviors of Vegetable Oil-Based Microemulsion Fuels: The Effects of Temperatures, Surfactants, Oils, and Water in Ethanol , 2013 .

[16]  Haji Hassan Masjuki,et al.  Emission and performance characteristics of an indirect ignition diesel engine fuelled with waste co , 2011 .

[17]  T Sabudak,et al.  Biodiesel production from waste frying oils and its quality control. , 2010, Waste management.

[18]  M. Pugazhvadivu,et al.  Investigations on the performance and exhaust emissions of a diesel engine using preheated waste frying oil as fuel , 2005 .

[19]  Erol Ileri,et al.  Experimental investigation of engine performance and exhaust emissions of a diesel engine fueled with diesel-n-butanol-vegetable oil blends. , 2014 .

[20]  Georgios Karavalakis,et al.  Biodiesel emissions profile in modern diesel vehicles. Part 2: Effect of biodiesel origin on carbonyl, PAH, nitro-PAH and oxy-PAH emissions. , 2011, The Science of the total environment.

[21]  B. Nas,et al.  Energy Potential of Biodiesel Generated from Waste Cooking Oil: An Environmental Approach , 2007 .

[22]  R. Dhanasekaran,et al.  A sustainable and eco-friendly fueling approach for direct-injection diesel engines using restaurant yellow grease and n-pentanol in blends with diesel fuel , 2017 .

[23]  Javed A. Chattha,et al.  Investigation of the Characteristics of the Fuel Injection Pump of a Diesel Engine Fuelled with Viscous Vegetable Oil-Diesel Oil Blends , 2006 .

[24]  Havva Balat,et al.  Progress in biodiesel processing , 2010 .

[25]  Saiful Bari,et al.  Filter clogging and power loss issues while running a diesel engine with waste cooking oil , 2002 .

[26]  Rajesh Gopinath,et al.  Solid acid catalyzed biodiesel production from waste cooking oil , 2008 .

[27]  Chun Shun Cheung,et al.  Influence of waste cooking oil biodiesel on combustion, unregulated gaseous emissions and particulate emissions of a direct-injection diesel engine , 2017 .