Reduced model for the planar solid oxide fuel cell

Abstract 3D modeling for fuel cells is generally computationally expensive, especially for stacks. In order to reduce computational cost, spatial smoothing over the parallel plain channels in flow fields is introduced and applied to a 3D steady-state isothermal planar solid oxide fuel cell model, which is validated with experiment from literature. The 3D model is reduced to 2D coupled with effective parameters and correlation factors, and then asymptotically reduced to parabolic PDEs and ODEs associated with space marching. The correlation factors, which are derived based on a full set of governing equations for electrokenitics over a cell cross section, can handle not only variations in diffusion pathways due to ribs but also the coupling effect between governing equations. The reduced models are verified with the 3D counterpart in view of global and local properties. Good agreement with a quantitative loss of information is achieved. The reduction in computational cost is investigated.

[1]  Paola Costamagna,et al.  Modeling of Solid Oxide Heat Exchanger Integrated Stacks and Simulation at High Fuel Utilization , 1998 .

[2]  C. Hong,et al.  Multiscale Parametric Studies on the Transport Phenomenon of a Solid Oxide Fuel Cell , 2005 .

[3]  Kuan-Zong Fung,et al.  The Effect of Porous Composite Electrode Structure on Solid Oxide Fuel Cell Performance I. Theoretical Analysis , 1997 .

[4]  Thomas Hocker,et al.  Efficient simulation of fuel cell stacks with the volume averaging method , 2003 .

[5]  D. Stolten,et al.  Modeling of Mass and Heat Transport in Planar Substrate Type SOFCs , 2003 .

[6]  H. Tu,et al.  One-dimensional Dynamic Modeling and Simulation of a Planar Direct Internal Reforming Solid Oxide Fuel Cell , 2009 .

[7]  Junxiang Shi,et al.  CFD analysis of a symmetrical planar SOFC with heterogeneous electrode properties , 2010 .

[8]  Xiangyang Zhou,et al.  Mathematical analysis of planar solid oxide fuel cells , 2008 .

[9]  Ibrahim Dincer,et al.  A general electrolyte–electrode-assembly model for the performance characteristics of planar anode-supported solid oxide fuel cells , 2009 .

[10]  R. O’Hayre,et al.  Fuel Cell Fundamentals , 2005 .

[11]  Vincent Giovangigli,et al.  Mass conservation and singular multicomponent diffusion algorithms , 1990, IMPACT Comput. Sci. Eng..

[12]  M. Khaleel,et al.  Three-dimensional thermo-fluid electrochemical modeling of planar SOFC stacks , 2003 .

[13]  Khiam Aik Khor,et al.  Simulation of a composite cathode in solid oxide fuel cells , 2004 .

[14]  A. Chaisantikulwat,et al.  Dynamic modelling and control of planar anode-supported solid oxide fuel cell , 2008, Comput. Chem. Eng..

[15]  C. F. Curtiss Symmetric Gaseous Diffusion Coefficients , 1968 .

[16]  R. Herbin,et al.  Three-dimensional numerical simulation for various geometries of solid oxide fuel cells , 1996 .

[17]  Guilan Wang,et al.  3-D model of thermo-fluid and electrochemical for planar SOFC , 2007 .

[18]  Said Al-Hallaj,et al.  A novel design for solid oxide fuel cell stacks , 2004 .

[19]  Norman Munroe,et al.  A dynamic 1D model of a solid oxide fuel cell for real time simulation , 2007 .

[20]  S. Singhal,et al.  Polarization Effects in Intermediate Temperature, Anode‐Supported Solid Oxide Fuel Cells , 1999 .

[21]  I. Yasuda,et al.  3-D model calculation for planar SOFC , 2001 .

[22]  Stefano Ubertini,et al.  Modeling solid oxide fuel cell operation: Approaches, techniques and results , 2006 .

[23]  A. Virkar,et al.  Dependence of polarization in anode-supported solid oxide fuel cells on various cell parameters , 2005 .

[24]  S. Chan,et al.  A complete polarization model of a solid oxide fuel cell and its sensitivity to the change of cell component thickness , 2001 .

[25]  Bengt Sundén,et al.  Review on modeling development for multiscale chemical reactions coupled transport phenomena in solid oxide fuel cells , 2010 .

[26]  Mustafa Fazil Serincan,et al.  Computational Thermal-Fluid Analysis of a Microtubular Solid Oxide Fuel Cell , 2008 .

[27]  Yixiang Shi,et al.  Modeling of an anode-supported Ni–YSZ|Ni–ScSZ|ScSZ|LSM–ScSZ multiple layers SOFC cell: Part I. Experiments, model development and validation , 2007 .

[28]  Masoud Soroush,et al.  Mathematical Modeling of Solid Oxide Fuel Cells: A Review , 2011 .

[29]  A. Bejan,et al.  Convection in Porous Media , 1992 .

[30]  G. Naterer,et al.  Thermodynamic analysis of a combined gas turbine power system with a solid oxide fuel cell through exergy , 2008 .

[31]  Michael Vynnycky,et al.  Validated Reduction and Accelerated Numerical Computation of a Model for the Proton Exchange Membrane Fuel Cell , 2009 .

[32]  I. Dincer,et al.  Mathematical modeling of planar solid oxide fuel cells , 2006 .

[33]  D. Jeon A comprehensive CFD model of anode-supported solid oxide fuel cells , 2009 .

[34]  Michael Vynnycky,et al.  Fuel cell model reduction through the spatial smoothing of flow channels , 2012 .

[35]  F. R. Foulkes,et al.  Fuel Cell Handbook , 1989 .

[36]  Subrata Mukherjee,et al.  On boundary conditions in the element-free Galerkin method , 1997 .

[37]  Ibrahim Dincer,et al.  Multi‐component mathematical model of solid oxide fuel cell anode , 2005 .

[38]  Y. Çengel Heat and Mass Transfer: Fundamentals and Applications , 2000 .

[39]  Yoshio Matsuzaki,et al.  Evaluation and modeling of performance of anode-supported solid oxide fuel cell , 2000 .

[40]  S. Chan,et al.  An Improved Anode Micro Model of SOFC , 2004 .

[41]  Yixiang Shi,et al.  Multi-level simulation platform of SOFC–GT hybrid generation system , 2010 .

[42]  M. Hussain Multi-Component and Multi-Dimensional Mathematical Modeling of Solid Oxide Fuel Cells , 2008 .

[43]  Francesco Calise,et al.  Simulation and exergy analysis of a hybrid Solid Oxide Fuel Cell (SOFC)–Gas Turbine System , 2006 .

[44]  S. Chan,et al.  Anode Micro Model of Solid Oxide Fuel Cell , 2001 .

[45]  R. Kee,et al.  A general mathematical model for analyzing the performance of fuel-cell membrane-electrode assemblies , 2003 .

[46]  Xingjian Xue,et al.  Mathematical Modeling Analysis of Regenerative Solid Oxide Fuel Cells in Switching Mode Conditions , 2010 .

[47]  Khiam Aik Khor,et al.  Cathode Micromodel of Solid Oxide Fuel Cell , 2004 .

[48]  Ioannis K. Kookos,et al.  Parametric and transient analysis of non-isothermal, planar solid oxide fuel cells , 2012 .

[49]  Hocine Ben Moussa,et al.  Study of species, temperature distributions and the solid oxide fuel cells performance in a 2-D model , 2011 .

[50]  Ayodeji Jeje,et al.  3D modeling of anode-supported planar SOFC with internal reforming of methane , 2007 .

[51]  Ibrahim Dincer,et al.  Mathematical modeling of transport phenomena in porous SOFC anodes , 2007 .

[52]  C. Adjiman,et al.  Comparison of two IT DIR-SOFC models: Impact of variable thermodynamic, physical, and flow properties. Steady-state and dynamic analysis , 2005 .

[53]  J. Chung,et al.  Physics-based modeling of a low-temperature solid oxide fuel cell with consideration of microstructure and interfacial effects , 2009 .