Generator-collector double electrode systems: a review.

A variety of generator-collector systems are reviewed, from the original rotating ring-disc electrodes developed in the 1950s, to very recent developments using new geometries and microelectrodes. An overview of both theoretical and experimental aspects are given, and the power of these double electrode systems in analytical electrochemistry is illustrated with a range of applications.

[1]  S. Bruckenstein,et al.  Ring-disc electrodes. Part 4.—Diffusion layer titration curves , 1966 .

[2]  C. Goss,et al.  Lateral diffusion in organized bilayer assemblies of electroactive amphiphiles: Influence of the oxidation state of the amphiphile investigated by steady-state methods involving an interdigitated micro-electrode array device , 1991 .

[3]  L. Nekrasov Detection and identification of intermediate and final products of electrochemical reactions by means of the rotating ring-disc electrode method , 1973 .

[4]  C. Amatore,et al.  Electrochemical time-of-flight responses at double-band generator-collector devices under pulsed conditions , 2006 .

[5]  E. Calvo,et al.  Ring–disc electrodes. Part 21.—pH measurement with the ring , 1983 .

[6]  F. Marken,et al.  Coupled triple phase boundary processes: Liquid–liquid generator–collector electrodes , 2010 .

[7]  Francesc Xavier Muñoz,et al.  Current collection efficiency of micro-and nano-ring-recessed disk electrodes and of arrays of these electrodes , 2009 .

[8]  C. G. Zoski Ultramicroelectrodes: Design, Fabrication, and Characterization , 2002 .

[9]  Koichi Aoki,et al.  Quantitative analysis of reversible diffusion-controlled currents of redox soluble species at interdigitated array electrodes under steady-state conditions , 1988 .

[10]  David E. Williams,et al.  Theory and practice of electrochemical titrations with dual microband electrodes , 2001 .

[11]  R. Compton,et al.  The dissolution of calcite in acid waters: mass transport versus surface control , 1989 .

[12]  C. Brett,et al.  Wall jet electrodes: the importance of radial diffusion , 1993 .

[13]  F. Marken,et al.  Microwave-enhanced electroanalytical processes: generator-collector voltammetry at paired gold electrode junctions. , 2009, The Analyst.

[14]  Christian Amatore,et al.  Theory and experiments of transport at channel microband electrodes under laminar flows. 2. Electrochemical regimes at double microband assemblies under steady state. , 2008, Analytical chemistry.

[15]  Tsutomu Horiuchi,et al.  Limiting Current Enhancement by Self‐Induced Redox Cycling on a Micro‐Macro Twin Electrode , 1991 .

[16]  R. Compton,et al.  Effect of carboxylic acids on the dissolution of calcite in aqueous solution. Part 3.—Polymaleic acid , 1990 .

[17]  W. Blaedel,et al.  Study of anodic stripping voltammetry with collection at tubular electrodes , 1977 .

[18]  R. Compton,et al.  A general computational method for mass-transport problems involving wall-jet electrodes and its application to simple electron-transfer, ECE and DISP1 reactions , 1990 .

[19]  D. Chin,et al.  Mass Transfer to an Impinging Jet Electrode , 1978 .

[20]  C. Brett,et al.  Voltammetric studies and stripping voltammetry of Mn(II) at the wall-jet ring-disc electrode , 1989 .

[21]  C. Brett,et al.  Transient measurements at the wall-jet ring disc electrode , 1992 .

[22]  J. Zen,et al.  Disposable screen-printed ring disk carbon electrode coupled with wall-jet electrogenerated iodine for flow injection analysis of arsenic(III) , 2008 .

[23]  F. Marken,et al.  Paired gold junction electrodes with submicrometer gap , 2009 .

[24]  A. Damjanović,et al.  The Role of Hydrogen Peroxide in Oxygen Reduction at Platinum in H 2 SO 4 Solution , 1967 .

[25]  W. Blaedel,et al.  Anodic stripping voltammetry with collection at tubular electrodes for the analysis of tap water , 1978 .

[26]  H. Sasaki,et al.  Enhanced Dissolution Rate of Pt from a Pt–Zn Compound Measured by Channel Flow Double Electrode , 2010 .

[27]  R. Compton,et al.  The photoelectrochemical reduction of p-bromo-nitrobenzene: An ECEE, ECE or DISP process? Mechanistic resolution via channel electrode voltammetry , 1994 .

[28]  R. Compton,et al.  Double channel electrodes and the measurement of heterogeneous reaction rates at the solid-liquid interface , 1988 .

[29]  M. Rievaj,et al.  Indirect voltammetric detection of fluoride ions in toothpaste on a comb-shaped interdigitated microelectrode array. , 2011, Talanta.

[30]  David E. Williams,et al.  Hydrodynamic modulation using vibrating electrodes: Application to electroanalysis , 1997 .

[31]  David E. Williams,et al.  Electrochemical Sensor Design Using Coplanar and Elevated Interdigitated Array Electrodes. A Computational Study , 2005 .

[32]  A. Damjanović,et al.  Hydrogen peroxide formation in oxygen reduction at gold electrodes: I. Acid solution , 1967 .

[33]  O. Niwa,et al.  Quantitative analysis of the steady-state currents of reversible redox species at a microdisk array electrode embedded in a surface electrode , 1990 .

[34]  R. Compton,et al.  Theory of collection efficiencies in the double tubular hydrodynamic electrode , 2005 .

[35]  C. Amatore,et al.  Simulation of diffusion–convection processes in microfluidic channels equipped with double band microelectrode assemblies: approach through quasi-conformal mapping , 2004 .

[36]  H. Sasaki,et al.  Dissolution Rates of Au from Au–Zn Compounds Measured by Channel Flow Double Electrode Method , 2010 .

[37]  J. O'm. Bockris,et al.  The Mechanism of Oxygen Reduction at Platinum in Alkaline Solutions with Special Reference to H 2 O 2 , 1967 .

[38]  In situ and online monitoring of hydrodynamic flow profiles in microfluidic channels based upon microelectrochemistry: concept, theory, and validation. , 2005, Chemphyschem : a European journal of chemical physics and physical chemistry.

[39]  A. Mount,et al.  Ring–disc electrodes. Part 22.—Theory of the measurement of proton fluxes at the disc , 1989 .

[40]  H. Matsuda Zur Theorie der Elektrolyse mit Zwei Eng Benachbarten Elektroden in Strömungsanordnungen. Allgemeine Formel für die Übertragungsausbeute , 1968 .

[41]  C. Lefrou,et al.  Analytical expressions for quantitative scanning electrochemical microscopy (SECM). , 2010, Chemphyschem : a European journal of chemical physics and physical chemistry.

[42]  F. Matysik Voltammetric characterization of a dual-disc microelectrode in stationary solution , 1997 .

[43]  B. Hou,et al.  Catalytic activity of graphene-cobalt hydroxide composite for oxygen reduction reaction in alkaline media , 2012 .

[44]  S. Jursa,et al.  Titration of As(III) with electrogenerated iodine in the diffusion layer of an interdigitated microelectrode array , 1997 .

[45]  W. House,et al.  The effect of carboxylic acids on the dissolution of calcite in aqueous solution. Part 1.—Maleic and fumaric acids , 1989 .

[46]  A. Damjanović,et al.  Distinction between Intermediates Produced in Main and Side Electrodic Reactions , 1966 .

[47]  F. Marken,et al.  Electrochemical investigation of hemispherical microdroplets of N,N-didodecyl-N ',N '-diethylphenylenediamine immobilized as regular arrays on partially-blocked electrodes: A new approach to liquid vertical bar liquid voltammetry , 2007 .

[48]  M. R. Pluck,et al.  Mechanism of solid/liquid interfacial reactions: the dissolution of benzoic acid in aqueous solution , 1993 .

[49]  W. J. Albery Ring-disc electrodes. Part 8.—Transient currents and first-order kinetics , 1967 .

[50]  C. Hahn,et al.  Microelectrode Studies of the Reaction of Superoxide with Carbon Dioxide in Dimethyl Sulfoxide , 2001 .

[51]  S. Bruckenstein,et al.  Ring-disc electrodes: Part 3. - Current-voltage curves at the ring electrode with simultaneous currents at the disc electrode , 1966 .

[52]  S. Bruckenstein,et al.  Ring-disc electrodes. Part 5.—First-order kinetic collection effciencies at the ring electrode , 1966 .

[53]  W. J. Albery,et al.  Ring-disc electrodes: Part 2. - Theoretical and experimental collection efficiencies , 1966 .

[54]  D. O'Hare,et al.  Micro-optical ring electrode: development of a novel electrode for photoelectrochemistry , 1996 .

[55]  A. Nishikata,et al.  Application of channel flow double electrode to the study on platinum dissolution during potential cycling in sulfuric acid solution , 2011 .

[56]  R. Compton,et al.  Kinetics of the Langmuirian adsorption of CuII ions at the calcite/water interface , 1990 .

[57]  H. Gerischer,et al.  Elektrolyse im strömungskanal: Ein verfahren zur untersuchung von reaktions und zwischenprodukten , 1965 .

[58]  Ian J. Cutress,et al.  Electrochemical random-walk theory: Probing voltammetry with small numbers of molecules: Stochastic versus statistical (Fickian) diffusion , 2011 .

[59]  C. Boxall,et al.  The micro-optical ring electrode Part 2 : theory for the transport limited, steady-state photocurrent. , 2006 .

[60]  P. Bogdanoff,et al.  Effect of an Ammonia Treatment on Structure, Composition, and Oxygen Reduction Reaction Activity of Fe–N–C Catalysts , 2011 .

[61]  R. Compton,et al.  Microarrays of ring-recessed disk electrodes in transient generator-collector mode: theory and experiment. , 2009, Analytical chemistry.

[62]  C. Brett,et al.  The wall-jet ring-disc electrode: Part II. Collection efficiency, titration curves and anodic stripping voltammetry , 1983 .

[63]  R. Braun Stofftransport an einer Doppelelektrode in der wand eines Strömungskanals , 1968 .

[64]  Plane-recessed disk electrodes and their arrays in transient generator–collector mode: The measurement of the rate of the chemical reaction of electrochemically generated species , 2010 .

[65]  T. Cox,et al.  Chronoamperometry at channel electrodes. Experimental applications of double electrodes , 1994 .

[66]  Jiawei Yan,et al.  A strategy for selective detection based on interferent depleting and redox cycling using the plane-recessed microdisk array electrodes , 2011 .

[67]  Richard G. Compton,et al.  Dual-microdisk electrodes in transient generator–collector mode: Experiment and theory , 2011 .

[68]  P. Unwin,et al.  Dolomite dissolution kinetics at low pH: a channel-flow study , 1993 .

[69]  Mauro Bertotti,et al.  Design and characterisation of a thin-layered dual-band electrochemical cell , 2003 .

[70]  L. Anderson,et al.  Filar electrodes: steady-state currents and spectroelectrochemistry at twin interdigitated electrodes , 1985 .

[71]  D. Williams,et al.  Electrochemical titrations of thiosulfate, sulfite, dichromate and permanganate using dual microband electrodes. , 2001, The Analyst.

[72]  C. Brett,et al.  The wall-jet ring-disc electrode , 1983 .

[73]  R. Compton,et al.  Hydrodynamic voltammetry with channel microband electrodes : axial diffusion effects , 1996 .

[74]  R. Compton,et al.  Voltammetry under high mass transport conditions. The application of the high speed channel electrode to the reduction of pentafluoronitrobenzene , 1996 .

[75]  R. Compton,et al.  The multigrid method, mgd1: an efficient and stable approach to electrochemical modelling. the simulation of double electrode problems , 1996 .

[76]  S. Venkatesan,et al.  Nafion/lead oxide-manganese oxide combined catalyst for use as a highly efficient alkaline air electrode in zinc-air battery , 2011 .

[77]  S. Bruckenstein,et al.  Ring disc electrodes. Part 6.—Second-order reactions , 1966 .

[78]  P. Unwin The ECE-DISP1 problem : general resolution via double channel electrode collection efficiency measurements , 1991 .

[79]  James L. Melville,et al.  Hydrodynamics and Mass Transport in Wall Tube and Microjet Electrodes. Simulation and Experiment for Micrometer-Scale Electrodes , 2003 .

[80]  Perry N. Motsegood,et al.  Diffusional interactions at dual disk microelectrodes: comparison of experiment with three-dimensional random walk simulations , 2004 .

[81]  R. Compton,et al.  Double-channel electrodes. Beyond the Lévěque approximation , 1988 .

[82]  S. Bruckenstein,et al.  Unraveling reactions with rotating electrodes , 1977 .

[83]  Stanley Bruckenstein,et al.  Ring-disc electrodes: Part 7. - Homogeneous and heterogeneous kinetics , 1966 .

[84]  A. Damjanović,et al.  The Role of Hydrogen Peroxide in the Reduction of Oxygen at Platinum Electrodes , 1966 .

[85]  R. Compton,et al.  Double-channel electrodes: Homogeneous kinetics and collection efficiency measurements , 1991 .

[86]  K. Kontturi,et al.  Micro ring–disk electrode probes for scanning electrochemical microscopy , 2002 .

[87]  R. Compton,et al.  The direct measurement of dissolution kinetics at the calcite/water interface , 1989 .

[88]  Hisao Tabei,et al.  Electrochemical behavior of reversible redox species at interdigitated array electrodes with different geometries: consideration of redox cycling and collection efficiency , 1990 .

[89]  R. Compton,et al.  Characterisation of the sonicated ring-pellet reactor and sono-ring-disc electrodes , 2001 .

[90]  Reconstruction of hydrodynamic flow profiles in a rectangular channel using electrochemical methods of analysis , 2007 .

[91]  M. Rievaj,et al.  Calibrationless determination of electroactive species using chronoamperograms at collector segment of interdigitated microelectrode array , 2006 .

[92]  R. Compton,et al.  Voltammetry in the absence of excess supporting electrolyte – ECE-DISP1 reactions: The electrochemical reduction of 2-nitrobromobenzene in acetonitrile solvent , 2011 .

[93]  R. Compton,et al.  Rotating-disc electrodes. ECE and DISP1 processes , 1987 .

[94]  R. Compton,et al.  The effect of carboxylic acids on the dissolution of calcite in aqueous solution. Part 2.—d-, l- and meso-Tartaric acids , 1990 .

[95]  A. Frumkin,et al.  Die anwendung der rotierenden scheibenelektrode mit einem ringe zur untersuchung von zwischenprodukten elektrochemischer reaktionen , 1959 .

[96]  Mark A. Taylor,et al.  Channel Flow Cell Studies of the Inhibiting Action of Gypsum on the Dissolution Kinetics of Calcite: A Laboratory Approach with Implications for Field Monitoring. , 2001, Journal of colloid and interface science.

[97]  G. Denuault,et al.  Three-dimensional random walk simulations of diffusion controlled electrode processes: (I) A hemisphere, disc and growing hemisphere , 1997 .

[98]  A. Hillman,et al.  Ring–disc electrodes. Part 19.—Adsorption studies at low frequency A.C. , 1979 .

[99]  V. Tvarozek,et al.  Application of redox cycling enhanced current at an interdigitated array electrode for iron-trace determination in ultrapure spectral carbon , 1995 .

[100]  F. Marken,et al.  Liquid–liquid ion transport junctions based on paired gold electrodes in generator–collector mode , 2009, Electrophoresis.

[101]  A. Fisher,et al.  Computational electrochemistry: three-dimensional boundary element simulations of double electrode geometries , 1999 .

[102]  K. Aoki,et al.  Hydrodynamic voltammetry at channel electrodes: Part II. Theory of first-order kinetic collection efficiencies , 1977 .

[103]  Ian J. Cutress,et al.  How many molecules are required to measure a cyclic voltammogram , 2011 .

[104]  F. Marken,et al.  Growth and characterisation of diffusion junctions between paired gold electrodes: diffusion effects in generator–collector mode , 2009 .

[105]  R. Compton,et al.  The wall-jet electrode and the study of electrode reaction mechanisms: The EC′ (catalytic) mechanism , 1991 .

[106]  H. Rajantie,et al.  Potentiometric titrations using dual microband electrodes. , 2001, The Analyst.

[107]  W. J. Albery Ring-disc electrodes. Part 1.—A new approach to the theory , 1966 .

[108]  Richard G. Compton,et al.  Channel Electrodes — A Review , 1998 .

[109]  H. Stone,et al.  Theoretical calculation of collection efficiencies for collector-generator microelectrode systems , 1997 .

[110]  Peter Tomčík,et al.  Determination of tetramethylthiuram disulfide on an interdigitated microelectrode array , 2001 .

[111]  Koichi Aoki,et al.  Time-dependence of diffusion-controlled currents of a soluble redox couple at interdigitated microarray electrodes , 1989 .

[112]  A. Berg,et al.  Simulation of Redox-Cycling Phenomena at Interdigitated Array (IDA) Electrodes: Amplification and Selectivity , 2008 .

[113]  Philip N. Bartlett,et al.  Electrochemical sensors: theory and experiment , 1986 .

[114]  J. Yamada,et al.  Limiting diffusion currents in hydrodynamic voltammetry: III. Wall jet electrodes , 1971 .