论文信息 - Bis(3,5-dimethyl-1,2,4-triazolato-κ N 4 )bis(pivalic acid-κ O )copper(II) dihydrate

Bis(3,5-dimethyl-1,2,4-triazolato-κ N 4 )bis(pivalic acid-κ O )copper(II) dihydrate

The molecule of the title complex, [Cu(C4H6N3)2(C5H10O2)2]·2H2O, is situated about a site of symmetry 2/m and shows a trans-N2O2 square-planar coordination geometry for the CuII centre. The crystal structure exhibits a two-dimensional layer arrangement mediated by intermolecular hydrogen bonds.

[1] Bin Zhao,et al. Novel triazole-bridged cadmium coordination polymers varying from zero- to three-dimensionality. , 2004, Inorganic chemistry.

[2] Jie‐Peng Zhang,et al. Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: in situ formation of ligands by cycloaddition of nitriles and ammonia. , 2004, Angewandte Chemie.