Optimal scheduling of biocide dosing for seawater-cooled power and desalination plants

Thermal desalination systems are typically integrated with power plants to exploit the excess heat resulting from the power-generation units. Using seawater in cooling the power plant and the desalination system is a common practice in many parts of the world where there is a shortage of freshwater. Biofouling is one of the major problems associated with the usage of seawater in cooling systems. Because of the dynamic variation in the power and water demands as well as the changes in the characteristics of seawater and the process, there is a need to develop an optimal policy for scheduling biocide usage and cleaning maintenance of the heat exchangers. The objective of this article is to introduce a systematic procedure for the optimization of scheduling the dosing of biocide and dechlorination chemicals as well as cleaning maintenance for a power production/thermal desalination plant. A multi-period optimization formulation is developed and solved to determine: the optimal levels of dosing and dechlorination chemicals; the timing of maintenance to clean the heat-exchange surfaces; and the dynamic dependence of the biofilm growth on the applied doses, the seawater-biocide chemistry, the process conditions, and seawater characteristics for each time period. The technical, economic, and environmental considerations of the system are accounted for. A case study is solved to elucidate the applicability of the developed optimization approach.

[1]  Ramasamy Venkatesan,et al.  Biofilm control for plate heat exchangers using surface seawater from the open ocean for the OTEC power plant , 2004 .

[2]  K. Cooksey,et al.  Biofilms and microbial fouling , 1983 .

[3]  M. Turakhia,et al.  Fouling of Heat Exchanger Surface: Measurement and Diagnosis , 1984 .

[4]  D. Sales,et al.  Model for fouling deposition on power plant steam condensers cooled with seawater: Effect of water velocity and tube material , 2007 .

[5]  Garth P. McCormick,et al.  Computability of global solutions to factorable nonconvex programs: Part I — Convex underestimating problems , 1976, Math. Program..

[6]  M. H. Lietzke,et al.  Kinetic model for predicting the concentrations of active halogen species in chlorinated saline cooling waters , 1979 .

[7]  Ming-Hui Chen,et al.  A Model to Predict Total Chlorine Residue in the Cooling Seawater of a Power Plant Using Iodine Colorimetric Method , 2008, International journal of molecular sciences.

[8]  Sabah A. Abdul-Wahab,et al.  Levels of heavy metals in subtidal sediments in the vicinity of thermal power/desalination plants: a case study. , 2009 .

[9]  W. G. Characklis,et al.  Dynamics of biofilm processes: methods , 1982 .

[10]  R. P. Morgan,et al.  Destruction of phytoplankton in the cooling water supply of a steam electric station , 1969 .

[11]  P. M. Williams,et al.  Chlorine reactions with seawater constituents and the inhibition of photosynthesis of natural marine phytoplankton , 1976 .

[12]  Mahmoud M. El-Halwagi,et al.  Process integration techniques for optimizing seawater cooling systems and biocide discharge , 2006 .

[13]  J. Meier Water Chlorination — Chemistry, Environmental Impact and Health Effects: Jolley, R. L., Bull, R. J., Katz, S., Roberts, M. H. and Jacobs, V. A. Vol.5, 1575 pp. Chelsea, MI: Lewis Publishers, Inc. (1985) , 1986 .

[14]  M. Lijesen The real-time price elasticity of electricity , 2007 .

[15]  H. Jenner,et al.  Cooling water management in European power stations Biology and control of fouling , 1998 .

[16]  James E. Falk,et al.  Jointly Constrained Biconvex Programming , 1983, Math. Oper. Res..

[17]  W. G. Characklis,et al.  Oxidation and Destruction of Microbial Films , 1980 .

[18]  M. El‐Halwagi,et al.  Convex Hull Discretization Approach to the Global Optimization of Pooling Problems , 2009 .

[19]  T. E. Cloete,et al.  The chemical control of biofouling in industrial water systems , 2004, Biodegradation.

[20]  K. Wasewar,et al.  Recovery of propionic acid from an aqueous stream by reactive extraction: effect of diluents , 2009 .

[21]  W. G. Characklis,et al.  Processes governing primary biofilm formation , 1982, Biotechnology and bioengineering.