Empirical modeling and interpretation of thermopower in AlPdMn quasicrystalline materials

The thermopower in AlPdMn quasicrystalline systems is explored. Thermopower in metals, semiconductors and metallic glasses are compared in relation to icosahedral AlPdMn quasicrystals. Due to atypical symmetry, transport in quasicrystalline materials is difficult to understand. Utilizing three free variables we propose an empirical fit to the temperature dependence of the experimental thermopower data. The physical significance of the fit parameters is discussed. These results are discussed in brief concerning the relation to the application of quasicrystals for use as thermoelectric materials.

[1]  T. M. Rice,et al.  Metal‐Insulator Transitions , 2003 .

[2]  E. Maciá May quasicrystals be good thermoelectric materials , 2000 .

[3]  T. Tritt,et al.  Thermal and electrical transport properties of the single-phase quasicrystalline material: Al70.8Pd20.9Mn8.3 , 1999 .

[4]  P. Lindqvist,et al.  Resistivity, hall effect and thermopower in AIPdMn and AlCuFe quasicrystals , 1996 .

[5]  Janot Conductivity in quasicrystals via hierarchically variable-range hopping. , 1996, Physical review. B, Condensed matter.

[6]  Ott,et al.  Low-temperature thermal conductivity of icosahedral Al70Mn9Pd21. , 1995, Physical review. B, Condensed matter.

[7]  Yun-ping,et al.  Universality in the resistivity-temperature relationship for decagonal quasicrystals. , 1994, Physical review. B, Condensed matter.

[8]  Yamamoto,et al.  Band structure effects of transport properties in icosahedral quasicrystals. , 1993, Physical review letters.

[9]  Wagner,et al.  Band-structure effects on the electronic properties of icosahedral alloys. , 1990, Physical review letters.

[10]  Y. Yokoyama,et al.  New icosahedral alloys with superlattice order in the Al–Pd–Mn system prepared by rapid solidification , 1990 .

[11]  B. Gallagher,et al.  The electron transport properties of metallic glasses , 1988 .

[12]  From,et al.  Thermoelectric power of Fe-Zr and Co-Zr metallic glasses. , 1986, Physical review. B, Condensed matter.

[13]  John W. Cahn,et al.  Metallic Phase with Long-Range Orientational Order and No Translational Symmetry , 1984 .