SEDIMENT AND NUTRIENT MODELING FOR TMDL DEVELOPMENT AND IMPLEMENTATION

At present, there are over 34,000 impaired waters and over 58,000 associated impairments officially listed in the U.S. Nutrients and sediment are two of the most common pollutants included in the list. States are required to identify and list those waters within their boundaries that are not meeting standards, to prioritize them, and to develop Total Maximum Daily Loads (TMDLs) for the pollutants of concern. Models are used to support development of TMDLs, typically to estimate source loading inputs, evaluate receiving water quality, and determine source load allocations so that receiving water quality standards are met. Numerous models are available today, and selection of the most suitable model for a specific TMDL project can be daunting. This article presents a critical review of models simulating sediment and nutrients in watersheds and receiving waters that have potential for use with TMDL development and implementation. The water quality models discussed, especially those with sediment and/or nutrient components, include loading models (GWLF and PLOAD), receiving water models (AQUATOX, BATHTUB, CE-QUAL-W2, QUAL2E, and QUAL2K), and watershed models having both loading and receiving components (AGNPS, AnnAGNPS, CASC2D/GSSHA, DWSM, HSPF, KINEROS2, LSPC, MIKE SHE, and SWAT). Additional models mentioned include another receiving water quality model (WASP), watershed models (ANSWERS storm event, ANSWERS continuous, PRMS storm event, SWMM, and WEPP), and BMP models (APEX, REMM, and VFSMOD). Model sources, structures, and procedures for simulating hydrology, sediment, and nutrients are briefly described for the reviewed models along with an assessment of their strengths, limitations, robustness, and potentials for using in sediment and/or nutrient TMDLs. Applications of AGNPS, APEX, BATHTUB, CE-QUAL-W2, GWLF, and SWAT in TMDL developments are presented. Applications of some of the other models (DWSM, GSSHA, and KINEROS2) relevant to TMDL studies are also presented. The models proved to be useful; however, they require a learning process. Simple models are easy to use but have limitations; comprehensive models are labor and data intensive but offer extensive analysis tools. Finally, recommendations are offered for advancing the sediment and nutrient modeling technologies as applied to TMDL development and implementation. Advances could be made towards: making the best use of existing models, enhancing the existing models, combining strengths of existing models, developing new models or supplemental components with physically based robust routines, numerous field applications, sensitivity analyses, full documentation, and rigorous education and training.

[1]  L. F. Huggins,et al.  ANSWERS: A Model for Watershed Planning , 1980 .

[2]  E. M. Thurman,et al.  Organic Geochemistry of Natural Waters , 1985, Developments in Biogeochemistry.

[3]  A. Saleh,et al.  EVALUATION OF SWAT AND HSPF WITHIN BASINS PROGRAM FOR THE UPPER NORTH BOSQUE RIVER WATERSHED IN CENTRAL TEXAS , 2004 .

[4]  William W Walker,et al.  Empirical Methods for Predicting Eutrophication in Impoundments. Report 4. Phase III. Applications Manual. , 1987 .

[5]  Georg Cadisch,et al.  Impact of land use on soluble organic nitrogen in soil , 2005 .

[6]  L. Kalin Evaluation of Sediment Transport Models and Comparative Application of Two Watershed Models , 2003 .

[7]  S. Chiu,et al.  Loading functions for assessment of water pollution from nonpoint sources. Final report , 1976 .

[8]  John R. Williams,et al.  Flood Routing With Variable Travel Time or Variable Storage Coefficients , 1969 .

[9]  Randy A. Dahlgren,et al.  Polyphenol control of nitrogen release from pine litter , 1995, Nature.

[10]  Peter B. Barraclough,et al.  Utilization of mineral nitrogen in the subsoil by winter wheat , 1989 .

[11]  Jimmy R. Williams SPNM, a model for predicting sediment, phosphorus, and nitrogen yields from agricultural basins. , 1980 .

[12]  Vijay P. Singh,et al.  Hydrological Simulation Program - Fortran (HSPF). , 1995 .

[13]  B. Mech.,et al.  River Width Adjustment. II: Modeling , 1998 .

[14]  Douglas A. Haith,et al.  G W LF GENERALIZED WATERSHED LOADING FUNCTIONS VERSION 2 . 0 USER ' S MANUAL December 15 , 1992 , 2001 .

[15]  Jeffrey G. Arnold,et al.  APPLICATION OF SWAT FOR THE UPPER NORTH BOSQUE RIVER WATERSHED , 2000 .

[16]  E M Laursen RIVER WIDTH ADJUSTMENT. II: MODELING. DISCUSSION AND CLOSURE , 2000 .

[17]  Juan J. Armesto,et al.  Patterns of Nutrient Loss from Unpolluted, Old‐Growth Temperate Forests: Evaluation of Biogeochemical Theory , 1995 .

[18]  Wesley W. Wallender,et al.  Evaluation of Modeling Tools For TMDL Development And Implementation , 2007 .

[19]  F. J. Stevenson,et al.  On the Presence of Fixed Ammonium in Rocks , 1959, Science.

[20]  Deva K. Borah,et al.  AGNPS-based Assessment of the Impact of BMPs on Nitrate-Nitrogen Discharging into an Illinois Water Supply Lake , 2002 .

[21]  V. G. Christensen,et al.  Water-Quality Study of the Cheney Reservoir Watershed, South-Central Kansas , 1997 .

[22]  G. R. Foster,et al.  Predicting soil erosion by water : a guide to conservation planning with the Revised Universal Soil Loss Equation (RUSLE) , 1997 .

[23]  Steven C. Chapra,et al.  QUAL2K: A Modeling Framework for Simulating River and Stream Water Quality , 2004 .

[24]  K. Mengel,et al.  Turnover of interlayer ammonium in loess-derived soil grown with winter wheat in the Shaanxi Province of China , 1990, Biology and Fertility of Soils.

[25]  Samar J. Bhuyan,et al.  An integrated approach for water quality assessment of a Kansas watershed , 2003, Environ. Model. Softw..

[26]  Kyle R. Mankin,et al.  DERIVING LAND COVER OF A LARGE AGRICULTURAL WATERSHED FROM MULTI-TEMPORAL LANDSAT SCENES , 2002 .

[27]  William G. Crumpton,et al.  Factors affecting nitrogen loss in experimental wetlands with different hydrologic loads , 1994 .

[28]  J. M. Kelly Carbon Flux to Surface Mineral Soil After Nitrogen and Phosphorus Fertilization , 1981 .

[29]  D. A. Woolhiser,et al.  KINEROS - a kinematic runoff and erosion model , 1995 .

[30]  Edward C. Krug,et al.  A Contribution to the Characterization of Illinois Reference/Background Conditions for Setting Nitrogen Criteria for Surface Waters in Illinois , 2000 .

[31]  R. Qualls,et al.  Comparison of the behavior of soluble organic and inorganic nutrients in forest soils , 2000 .

[32]  Deva K. Borah,et al.  WATERSHED-SCALE HYDROLOGIC AND NONPOINT-SOURCE POLLUTION MODELS: REVIEW OF APPLICATIONS , 2004 .

[33]  Edward C. Krug,et al.  Identification of factors that aid carbon sequestration in Illinois agricultural systems , 2003 .

[34]  J. J. Bond,et al.  Nitrification in Paleocene Shale , 1974, Science.

[35]  E. Krug,et al.  The need for comprehensive and consistent treatment of the nitrogen cycle in nitrogen cycling and mass balance studies: I. Terrestrial nitrogen cycle. , 2002, The Science of the total environment.

[36]  J. E. Parsons,et al.  Modeling hydrology and sediment transport in vegetative filter strips , 1999 .

[37]  V. Singh,et al.  Computer Models of Watershed Hydrology , 1995 .

[38]  Scott A. Sheeder,et al.  A Spatial Technique for Estimating Streambank Erosion Based On Watershed Characteristics , 2004 .

[39]  Chad R. Milligan,et al.  Occurrence of phosphorus, nitrate, and suspended solids in streams of the Cheney Reservoir Watershed, south-central Kansas, 1997-2000 , 2001 .

[40]  W. Green,et al.  Studies on Soil Phyics. , 1911, The Journal of Agricultural Science.

[41]  Douglas A. Haith,et al.  GENERALIZED WATERSHED LOADING FUNCTIONS FOR STREAM FLOW NUTRIENTS , 1987 .

[42]  Leonard P. Gianessi,et al.  Nonpoint-source pollution: Are cropland controls the answer? , 1986 .

[43]  Charles Dickens,et al.  American notes and Pictures from Italy , 1903 .

[44]  R. W. Hann,et al.  Optimal Operation of Large Agricultural Watersheds with Water Quality Restraints , 1978 .

[45]  J. L. Gaunt,et al.  Soluble organic nitrogen in agricultural soils , 2000, Biology and Fertility of Soils.

[46]  Anonymous Physics and hydraulics of the Mississippi River , 1862, American Journal of Science and Arts.

[47]  Larry M. Pope Significant Findings of Water-Quality Studies and Implications for Cheney Reservoir Watershed, South-Central Kansas, 1996-2001 , 2002 .

[48]  L. M. Hauck,et al.  The use of an integrated modeling approach for TMDL development in the lake Waco/Bosque river watershed. , 2000 .

[49]  Vijay P. Singh,et al.  DWSM - a Dynamic Watershed Simulation Model. , 2002 .

[50]  D. K. Borah,et al.  WATERSHED-SCALE HYDROLOGIC AND NONPOINT-SOURCE POLLUTION MODELS: REVIEW OF MATHEMATICAL BASES , 2003 .

[51]  J. Arnold,et al.  VALIDATION OF THE SWAT MODEL ON A LARGE RWER BASIN WITH POINT AND NONPOINT SOURCES 1 , 2001 .

[52]  T. A. Dillaha,et al.  ANSWERS: a nonpoint source pollution model for water, sediment and nutrient losses. , 2002 .

[53]  George Vellidis,et al.  Mathematical Simulation Tools for Developing Dissolved Oxygen TMDLs , 2007 .

[54]  W. H. Wischmeier,et al.  Predicting rainfall erosion losses : a guide to conservation planning , 1978 .

[55]  Jimmy R. Williams Sediment Routing for Agricultural Watersheds , 1975 .

[56]  William O. George,et al.  Nitrate in the ground water of Texas , 1951 .

[57]  M. J. HALL,et al.  Hydrology for Engineers , 1969, Nature.

[58]  Charles Lyell,et al.  A Second Visit To The United States Of North America , 2010 .

[59]  T. R. Ellsworth,et al.  Need for a Soil‐Based Approach in Managing Nitrogen Fertilizers for Profitable Corn Production , 2006 .

[60]  J. K. Koelliker,et al.  Applicability of AGNPS model for water quality planning , 1989 .

[61]  Samar J. Bhuyan,et al.  ASSESSMENT OF RUNOFF AND SEDIMENT YIELD USING REMOTE SENSING, GIS, AND AGNPS , 2002 .

[62]  C. A. Jones,et al.  A survey of the variability in tissue nitrogen and phosphorus concentrations in maize and grain sorghum , 1983 .

[63]  Darrell J. Bosch,et al.  ECONOMIC MODELS FOR TMDL ASSESSMENT AND IMPLEMENTATION , 2006 .

[64]  Jeffrey G. Arnold,et al.  DEVELOPMENT AND APPLICATION OF SWAT TO LANDSCAPES WITH TILES AND POTHOLES , 2005 .

[65]  R. Mccready,et al.  Distribution, source and evolution of nitrate in a glacial till of southern Alberta, Canada , 1984 .

[66]  J. J. Schoenau,et al.  Organic matter leaching as a component of carbon, Nitrogen, Phosphorus, and Sulfur Cycles in a forest, grassland, and Gleyed soil , 1987 .

[67]  W. D. Rosenthal,et al.  HYDROLOGIC MODELINGS/GIS AS AN AID IN LOCATING MONITORING SITES , 1999 .

[68]  Scott A. Wells,et al.  CE-QUAL-W2: A Two-dimensional, Laterally Averaged, Hydrodynamic and Water Quality Model, Version 3.5 , 2006 .

[69]  Indrajeet Chaubey,et al.  Uncertainty in TMDL Models , 2006 .

[70]  Lars J. Tranvik,et al.  Bioavailability of wetland‐derived DON to freshwater and marine bacterioplankton , 1999 .

[71]  Paul J Worsfold,et al.  Seawater induced release and transformation of organic and inorganic phosphorus from river sediments. , 2004, Water research.

[72]  Renjie Xia,et al.  Storm event flow and sediment simulations in agricultural watersheds using DWSM , 2004 .

[73]  F. J. Stevenson Cycles of soil : carbon, nitrogem, phosphorus, sulfur, micronutrients , 1986 .

[74]  M. H. Timperley,et al.  Organic Nitrogen Compounds in Atmospheric Precipitation: Their Chemistry and Availability to Phytoplankton , 1985 .

[75]  W. Green Studies in soil physics : I. The flow of air and water through soils , 1911 .

[76]  Vijay P. Singh,et al.  The Precipitation-Runoff Modeling System - PRMS. , 1995 .

[77]  C. Green,et al.  Release of fixed ammonium during nitrification in soils , 1994 .

[78]  Kyle R. Mankin,et al.  WATERSHED–SCALE AMC SELECTION FOR HYDROLOGIC MODELING , 2003 .

[79]  Gene Yagow Using GWLF for Development of “Reference Watershed Approach” TMDLs , 2004 .

[80]  D. J. Hatch,et al.  Distribution of nitrogen pools in the soil profile of undisturbed and reseeded grasslands , 2000, Biology and Fertility of Soils.

[81]  G. W. Thomas,et al.  Nitrate-Nitrogen and Phosphorus Contents of Streams Draining Small Agricultural Watersheds in Kentucky 1 , 1974 .

[82]  Vijay P. Singh,et al.  CASC2D: a two-dimensional, physically-based, Hortonian hydrologic model. , 2002 .

[83]  S. J. Smith Soluble organic nitrogen losses associated with recovery of mineralized nitrogen , 1987 .

[84]  Yakov A. Pachepsky,et al.  Modeling bacteria fate and transport in watersheds to support TMDLs , 2006 .

[85]  D. K. Borah,et al.  Runoff Simulation Model for Small Watersheds , 1989 .

[86]  F. J. Stevenson,et al.  Solubilization of soil organic matter by liquid anhydrous ammonia , 1987 .

[87]  Ali Saleh Application of SWAT and APEX Models Using SWAP (SWAT/APEX Program) for Upper North Bosque River Watershed in Texas , 2004 .

[88]  Klaus Kaiser,et al.  Dissolved organic phosphorus and sulphur as influenced by sorptive interactions with mineral subsoil horizons , 2001 .

[89]  Bruce N Wilson,et al.  Use of Biological Indicators in TMDL Assessment and Implementation , 2006 .

[90]  R. E. Dickinson,et al.  Storm-Water Management Model, Version 4. Part a: user's manual , 1988 .

[91]  K. Mengel,et al.  RELEASE OF NONEXCHANGEABLE (FIXED) SOIL AMMONIUM UNDER FIELD CONDITIONS DURING THE GROWING SEASON , 1981 .

[92]  David C. Goodrich,et al.  KINEROS: A kinematic runoff and erosion model documentation and user manual , 1986 .

[93]  Adina Paytan,et al.  Rapid biologically mediated oxygen isotope exchange between water and phosphate , 2002 .

[94]  H. B. Jr. Tukey,et al.  Leaching of Metabolites from Above-Ground Plant Parts and Its Implications , 1966 .

[95]  D. Jenkinson Cycles of Soil: Carbon, Nitrogen, Phosphorus, Sulfur, Micronutrients , 1987 .

[96]  K. D. Ritchey,et al.  Chemical Composition of Leachate of Dairy Manure Mixed with Fluidized Bed Combustion Residue , 1999 .

[97]  G. W. Thomas,et al.  Nitrate-Nitrogen and Phosphate-Phosphorus in Seven Kentucky Streams Draining Small Agricultural Watersheds: Eighteen Years Later , 1992 .

[98]  Á. Zsolnay,et al.  Water extractable organic matter in arable soils : effects of drought and long-term fertilization , 1994 .

[99]  G. R. Foster,et al.  Estimating Sediment Transport Capacity in Watershed Modeling , 1981 .

[100]  Deva K. Borah,et al.  Storm Event and Continuous Modeling of an Illinois Watershed to Evaluate Surface Water Supplies , 2005 .

[101]  D. Keeney,et al.  Nitrate and Ammonium Contents of Wisconsin Limestones , 1971, Nature.