Preparation and properties of high purity Mg-Y biomaterials.

An effective zone solidification method has been found to prepare high purity Mg-Y biomaterials. The corrosion and mechanical properties of the purified middle region are improved remarkably compared with common casting method. The average gain size and secondary dendrite space decrease from the top layer to the bottom layer of the ingot. The oxides, defects and precipitates are mainly enriched in the top layer of the ingot under the impulsion of high thermal gradient. These results are in agreement with that simulated by finite elemental method using FLOW-3D software. It is confirmed that the mode of scallop symmetric solidification attributes to the purifying process. This zone solidification method not only contributes to high purity Mg-based biomaterials, but also provides a new approach to prepare high performance Mg alloys.

[1]  J. Wood,et al.  Variability of skin thickness in an AM60B magnesium alloy die-casting , 2006 .

[2]  Frank Witte,et al.  Degradable biomaterials based on magnesium corrosion , 2008 .

[3]  Elizabeth A. Holm,et al.  Three-dimensional simulation of grain growth in a thermal gradient with non-uniform grain boundary mobility , 2008 .

[4]  Frank Witte,et al.  In vitro and in vivo corrosion measurements of magnesium alloys. , 2006, Biomaterials.

[5]  A. K. Dahle,et al.  The role of solute in grain refinement of magnesium , 2000 .

[6]  E. Watson,et al.  Diffusion in solid-Earth systems , 2007 .

[7]  E. F. Emley Principles of magnesium technology , 1966 .

[8]  Felix Beckmann,et al.  Microtomography of magnesium implants in bone and their degradation , 2006, SPIE Optics + Photonics.

[9]  M. Liu,et al.  Influence of pH and chloride ion concentration on the corrosion of Mg alloy ZE41 , 2008 .

[10]  C. R. Howlett,et al.  Mechanisms of magnesium-stimulated adhesion of osteoblastic cells to commonly used orthopaedic implants. , 2002, Journal of biomedical materials research.

[11]  Yufeng Zheng,et al.  The development of binary Mg-Ca alloys for use as biodegradable materials within bone. , 2008, Biomaterials.

[12]  E. Mcbride,et al.  ABSORBABLE METAL IN BONE SURGERY: A FURTHER REPORT ON THE USE OF MAGNESIUM ALLOYS , 1938 .

[13]  Yang Song,et al.  Research on an Mg-Zn alloy as a degradable biomaterial. , 2010, Acta biomaterialia.

[14]  B. Chalmers,et al.  A PRISMATIC SUBSTRUCTURE FORMED DURING SOLIDIFICATION OF METALS , 1953 .

[15]  P. Uggowitzer,et al.  Corrosion behaviour of an Mg–Y–RE alloy used in biomedical applications studied by electrochemical techniques , 2008 .

[16]  G. Song,et al.  Corrosion mechanisms of magnesium alloys , 1999 .

[17]  Q. Peng,et al.  Microstructure and Strengthening Mechanism of Die-Cast Mg-Gd Based Alloys , 2008 .

[18]  F. Wittea,et al.  In vivo corrosion of four magnesium alloys and the associated bone response , 2004 .

[19]  Alexis M Pietak,et al.  Magnesium and its alloys as orthopedic biomaterials: a review. , 2006, Biomaterials.

[20]  A Haverich,et al.  Left main coronary artery fistula exiting into the right atrium , 2003, Heart.