Development of New Reagents Containing Silicon and Related Metals and Application to Practical Organic Syntheses

Our research works in the last few decades are summarized. We have studied the synthetic use of organometallics, especially organosilicon compounds, and have developed a number of new reagents and ...

[1]  A. Hosomi,et al.  Stereoselective Synthesis of Substituted Cyclic Ethers and Amines by Acid-Catalyzed Cyclization of Vinylsilanes Bearing a Hydroxy or Amino Group , 2003 .

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[12]  A. Hosomi,et al.  Acid-Catalyzed Cyclization of Vinylsilanes Bearing a Hemiacetal Group , 2001 .

[13]  A. Hosomi,et al.  Synthetic Utility of Stannyl Enolates as Radical Alkylating Agents1 , 2001 .

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[16]  K. Ishihara,et al.  A High Yield Procedure for the Me3SiNTf2-Induced Carbon-Carbon Bond-Forming Reactions of Silyl Nucleophiles with Carbonyl Compounds: The Importance of Addition Order and Solvent Effects , 2001 .

[17]  M. Hojo,et al.  Allyl- and propargylchromium reagents generated by achromium(III) ate-type reagent as a reductant and theirreactions with electrophiles , 2001 .

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[41]  M. Hojo,et al.  A New and Mild System for the Generation of Nonstabilized Carbonyl Ylides: Synthetically Practical Use in Reactions with Electron-Deficient Dipolarophiles , 1997 .

[42]  Hajime Ito,et al.  Highly Stereoselective Intramolecular Addition of a Hydroxyl Group to Vinylsilanes via 1,2-Silyl Migration(1). , 1997, The Journal of organic chemistry.

[43]  Hajime Ito,et al.  Studies on Organosilicon Chemistry. Part 135. New Access to Cross- Coupling Reaction Between Arylsilanes or Heteroarylsilanes and Aryl Halides Mediated by a Copper(I) Salt. , 1997 .

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[50]  Hajime Ito,et al.  “Tailor-Made” carbonyl ylides: [3 + 2] cycloaddition of the parent and optionally substituted nonstabilized carbonyl ylides , 1996 .

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