Diiridium(II)-Komplexe durch lichtunterstützte oxidative Additionsreaktionen: Struktur eines stabilen zweikernigen Iodo(iodmethyl)iridium(II)-Komplexes†

La reaction de Ir(ηCl)(cod) 2 avec le pyridine-2 thiolate dans le diethyl ether donne le complexe Ir 2 (η-C 5 H 4 NS)(cod) 2 . L'acceleration de la synthese par la lumiere suggere un mecanisme radicalaire, mais la formation de complexes halogeno dans la synthese avec CH 2 I 2 le contredit

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