Pyrolysis for recycling waste composites

Abstract: Pyrolysis is a suitable process for recycling polymer composites because the thermal decomposition products of the polymer matrix evaporate, and thus the reinforcement materials can be recovered and reused. The products of pyrolysis carried out at an appropriate temperature are monomers and other valuable chemicals. This chapter describes the pyrolysis reactions and products of frequently used thermoplastics and thermosets in polymer composites. Published results on pyrolysis of various polymer composites are discussed in order to understand the requirements of successful plastic composite recycling by pyrolysis. The environmental concern related to pyrolysis of flame retardants containing polymer composites is also touched upon and some methods are referred to for decreasing or eliminating toxic and harmful compounds from the pyrolysis products of halogenated flame retardants.

[1]  E. Jakab,et al.  Thermal Decomposition of Polymer Mixtures Containing Poly(vinyl chloride) , 2002 .

[2]  C. Snape,et al.  The flammability of urethane-modified polyisocyanurates and its relationship to thermal degradation chemistry , 2001 .

[3]  D. Wiles,et al.  The thermal degradation of poly(aryl—ether—ether—ketone) (PEEK) as monitored by pyrolysis—GC/MS and TG/MS☆ , 1990 .

[4]  H. Hatori,et al.  The mechanism of polyimide pyrolysis in the early stage , 1996 .

[5]  Robert P. Lattimer,et al.  Low-temperature pyrolysis products from a polyether-based urethane , 2002 .

[6]  A. Torres,et al.  Recycling by pyrolysis of thermoset composites: characteristics of the liquid and gaseous fuels obtained , 2000 .

[7]  M. Blazsó,et al.  Sequence of phenolic units in phenol—formaldehyde polycondensates studied by pyrolysis—gas chromatography / mass spectrometry , 1991 .

[8]  C. Wesdemiotis,et al.  MALDI-MS analysis of pyrolysis products from a segmented polyurethane , 1998 .

[9]  Paul T. Williams,et al.  Analysis of products from the pyrolysis of plastics recovered from the commercial scale recycling of waste electrical and electronic equipment , 2007 .

[10]  R. Allred,et al.  Tertiary Recycling of Automotive Plastics and Composites , 2000 .

[11]  S. Guerra,et al.  Poly(ethylene-co-1,4-cyclohexylenedimethylene terephthalate) copolyesters obtained by ring opening polymerization , 2009 .

[12]  C. J. Tsai,et al.  Mechanism and kinetic modelling of PEEK pyrolysis by TG/MS , 1999 .

[13]  E. Mészáros,et al.  Thermal decomposition of flame retarded polycarbonates , 2007 .

[14]  José A. Caballero,et al.  Pyrolysis study of polyurethane , 2001 .

[15]  J. Hetper,et al.  Pyrolysis-gas chromatography-mass spectrometry of cured phenolic resins. , 2003, Journal of chromatography. A.

[16]  K. Chrissafis,et al.  Nanocomposites of isotactic polypropylene with carbon nanoparticles exhibiting enhanced stiffness, thermal stability and gas barrier properties , 2008 .

[17]  M. Blazsó,et al.  Pyrolysis and debromination of flame retarded polymers of electronic scrap studied by analytical pyrolysis , 2002 .

[18]  W. Kaminsky,et al.  Catalytical and thermal pyrolysis of polyolefins , 2007 .

[19]  A. I. Balabanovich Poly(butylene terephthalate) fire retarded by bisphenol A bis(diphenyl phosphate) , 2004 .

[20]  P. N. Tutunjian,et al.  Thermal stability of poly(trimethylene terephthalate) , 2005 .

[21]  Chris D. Rudd,et al.  A fluidised-bed process for the recovery of glass fibres from scrap thermoset composites , 2000 .

[22]  S. Hsiao,et al.  Thermal degradation behaviour of aromatic poly(ester–imide) investigated by pyrolysis–GC/MS , 2007 .

[23]  W. Kaminsky,et al.  Pyrolysis of polyolefins with steam to yield olefins , 1996 .

[24]  M. Blazsó,et al.  Conversion of the volatile thermal decomposition products of polyamide-6,6 and ABS over Y zeolites , 2008 .

[25]  Paul T. Williams,et al.  Recycling of fibre-reinforced polymeric waste by pyrolysis: thermo-gravimetric and bench-scale investigations , 2003 .

[26]  P. Haines,et al.  Pyrolysis–gas-chromatographic study of a series of polyester thermosets , 2000 .

[27]  J. Scheirs Overview of Commercial Pyrolysis Processes for Waste Plastics , 2006 .

[28]  Chris D. Rudd,et al.  Microwave heating as a means for carbon fibre recovery from polymer composites: a technical feasibility study , 2004 .

[29]  Rafael Font,et al.  Pyrolysis and combustion of electronic wastes , 2009 .

[30]  G. Montaudo,et al.  Primary thermal degradation processes of poly(ether‐sulfone) and poly(phenylene oxide) investigated by direct pyrolysis‐mass spectrometry , 1994 .

[31]  R. E. Allred,et al.  Recycling Process for Carbon/Epoxy Composites , 2002 .

[32]  B. Schartel,et al.  Mechanical, thermal, and fire behavior of bisphenol a polycarbonate/multiwall carbon nanotube nanocomposites , 2008 .

[33]  Paul T. Williams,et al.  Characterisation of products from the recycling of glass fibre reinforced polyester waste by pyrolysis , 2003 .

[34]  Stephen Pickering,et al.  Recycling technologies for thermoset composite materials—current status , 2006 .

[35]  G. Cicala,et al.  Thermal decomposition products of copoly(arylene ether sulfone)s characterized by direct pyrolysis mass spectrometry , 2007 .

[36]  Kaminsky,et al.  New Pathways in Plastics Recycling. , 2000, Angewandte Chemie.

[37]  H. Ohtani,et al.  Characterization of polyurethanes by high-resolution pyrolysis-capillary gas chromatography , 1987 .

[38]  T. Horikawa,et al.  Preparation and characterization of the carbonized material of phenol–formaldehyde resin with addition of various organic substances , 2003 .

[39]  Bernhard Schartel,et al.  Flame Retardancy Mechanisms of Aluminium Phosphinate in Combination with Melamine Cyanurate in Glass-Fibre-Reinforced Poly(1,4-butylene terephthalate) , 2008 .

[40]  S. Ali,et al.  Polymer waste recycling over used catalysts , 2002 .

[41]  M. Blazsó In situ modification of pyrolysis products of macromolecules in an analytical pyrolyser , 2005 .

[42]  Christian Roy,et al.  The vacuum pyrolysis of used tires , 1995 .

[43]  G. Montaudo,et al.  Primary thermal degradation processes occurring in poly(phenylenesulfide) investigated by direct pyrolysis–mass spectrometry , 1994 .

[44]  Chris D. Rudd,et al.  Soft ionisation analysis of evolved gas for oxidative decomposition of an epoxy resin/carbon fibre composite , 2007 .

[45]  Mária Omastová,et al.  Thermal decomposition of polyolefin/carbon black composites , 2005 .

[46]  M. Blazsó Composition of Liquid Fuels Derived from the Pyrolysis of Plastics , 2006 .

[47]  M. Abdel-Goad,et al.  Fire behaviour of polyamide 6/multiwall carbon nanotube nanocomposites , 2005 .

[48]  H. Seifert,et al.  Detoxification of brominated pyrolysis oils , 2003 .