Asymmetric Pt/Au coated catalytic micromotors fabricated by dynamic shadowing growth

Asymmetric Pt/Au coated catalytic micromotors are fabricated by a dynamic shadowing growth method, and the exposed Au surface area A is changed systematically. The average moving speed u is found to follow the scaling relationship u∝A3/2, which agrees with the self-electrophoresis mechanism. Motion behaviors of micromotors with similar sizes and morphologies operating under a non-self-electrophoresis mechanism are compared with the Pt/Au micromotors, and in general, the self-electrophoresis mechanism gives higher activity for motors with similar sizes and morphologies.

[1]  Ramin Golestanian,et al.  Self-motile colloidal particles: from directed propulsion to random walk. , 2007, Physical review letters.

[2]  G. Whitesides,et al.  Autonomous Movement and Self‐Assembly , 2002 .

[3]  T. Mallouk,et al.  Bipolar electrochemical mechanism for the propulsion of catalytic nanomotors in hydrogen peroxide solutions. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[4]  Walter F Paxton,et al.  Motility of catalytic nanoparticles through self-generated forces. , 2005, Chemistry.

[5]  J. Brady,et al.  Osmotic propulsion: the osmotic motor. , 2008, Physical review letters.

[6]  Kalayil Manian Manesh,et al.  Thermal modulation of nanomotor movement. , 2009, Small.

[7]  Kalayil Manian Manesh,et al.  Ultrafast catalytic alloy nanomotors. , 2008, Angewandte Chemie.

[8]  Geoffrey A Ozin,et al.  Nanolocomotion - catalytic nanomotors and nanorotors. , 2010, Small.

[9]  Joseph Wang,et al.  Motion control at the nanoscale. , 2010, Small.

[10]  N. Kovtyukhova Toward Understanding of the Propulsion Mechanism of Rod-Shaped Nanoparticles That Catalyze Gas-Generating Reactions , 2008 .

[11]  Ramin Golestanian,et al.  Propulsion of a molecular machine by asymmetric distribution of reaction products. , 2005, Physical review letters.

[12]  Chad A Mirkin,et al.  Rational design and synthesis of catalytically driven nanorotors. , 2007, Journal of the American Chemical Society.

[13]  J. Gibbs,et al.  Design and characterization of rotational multicomponent catalytic nanomotors. , 2009, Small.

[14]  Yang Wang,et al.  Dynamic interactions between fast microscale rotors. , 2009, Journal of the American Chemical Society.

[15]  Jonathan D Posner,et al.  Rapid fabrication of bimetallic spherical motors. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[16]  D. Jia,et al.  The time, size, viscosity, and temperature dependence of the Brownian motion of polystyrene microspheres , 2007 .

[17]  Ayusman Sen,et al.  Biomimetic behavior of synthetic particles: from microscopic randomness to macroscopic control. , 2010, Physical chemistry chemical physics : PCCP.

[18]  Yiping Zhao,et al.  Designing catalytic nanomotors by dynamic shadowing growth. , 2007, Nano letters.

[19]  J. Posner,et al.  Locomotion of electrocatalytic nanomotors due to reaction induced charge autoelectrophoresis. , 2010, Physical review. E, Statistical, nonlinear, and soft matter physics.

[20]  John G. Gibbs,et al.  Autonomously motile catalytic nanomotors by bubble propulsion , 2009 .