Correlations of values of average energy transfer from highly excited polyatomic molecules with heats of vaporization and boiling temperatures

Correlations of the average energy transfered in a highly excited polyatomic molecule-bath gas binary collision with the heat of vaporization and boiling point of the bath gas are presented. It is shown that a unique correlation exists between the logarithms of the average energy transferred in a collision and the values of the two quantities reported above. Examples are given for excited toluene, azulene, and substituted cycloheptatriene collisions with mono- and polyatomic bath gases