Self-replication in a Diels–Alder reaction

The Diels–Alder reaction between ene 1 and diene 2 at 23 and 40 °C shows sigmoidal characteristics for the formation of product 3 and a response to added 3 that indicates that it is an efficient catalyst for the reaction.

[1]  Julius Rebek,et al.  Kinetic studies and modeling of a self-replicating system , 1991 .

[2]  G. Kiedrowski,et al.  Sequence Dependence of Template‐Directed Syntheses of Hexadeoxynucleotide Derivatives with 3′–5′ Pyrophosphate Linkage , 1989 .

[3]  Günter von Kiedrowski,et al.  Self-replication by condensation of 3-aminobenzamidines and 2-formylphenoxyacetic acids , 1992 .

[4]  S. Boxer,et al.  Electroabsorption (stark effect) spectroscopy of mono- and biruthenium charge-transfer complexes : measurements of changes in dipole moments and other electrooptic properties , 1991 .

[5]  L. Orgel.  Unnatural selection in chemical systems. , 1995, Accounts of chemical research.

[6]  G. Bridger,et al.  A bisubstrate reaction template , 1989 .

[7]  Chen Zhao,et al.  Bisubstrate reaction templates. Examination of the consequences of identical versus different binding sites , 1990 .

[8]  David N. Reinhoudt,et al.  Kinetic analysis of the Rebek self-replicating system: is there a controversy? , 1996 .

[9]  E. Wintner,et al.  Template Effects in New Self-Replicating Molecules† , 1994 .

[10]  J. Sanders,et al.  Free‐Energy Profile for a Host‐Accelerated Diels–Alder Reaction: The Sources of exo Selectivity , 1995 .

[11]  Julius Rebek,et al.  Self-replicating system , 1990 .

[12]  J. Rebek,et al.  Reciprocal template effects in a replication cycle , 1994 .

[13]  S. Hoffmann.  Artificial Replication Systems , 1992 .

[14]  Günter von Kiedrowski,et al.  A Self‐Replicating Hexadeoxynucleotide , 1986 .

[15]  M. Matzen,et al.  Parabolic Growth of a Self‐Replicating Hexadeoxynucleotide Bearing a 3'‐5'‐Phosphoamidate Linkage , 1991 .