论文信息 - (2,2′-Bipyridine)tetracarbonylmolybdenum(0)

(2,2′-Bipyridine)tetracarbonylmolybdenum(0)

In the title compound, [Mo(C10H8N2)(CO)4], the Mo atom adopts a distorted cis-MoN2C4 octahedral geometry. The crystal packing is consolidated by π–π contacts and C—H⋯O interactions.

[1] Gene-Hsiang Lee,et al. Two noncentrosymmetric complexes: [W(CO)4(bipy)] and [W(CO)4(phen)](bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline) obtained through solvothermal synthesis and their optical properties , 2005 .

[2] G. Hogarth,et al. Organometallic chemistry in a conventional microwave oven: the facile synthesis of group 6 carbonyl complexes , 2004 .

[3] D. B. Green,et al. Microwave-Assisted Synthesis of Group 6 (Cr, Mo, W) Zerovalent Organometallic Carbonyl Compounds , 2000 .

[4] G. G. Stokes. "J." , 1890, The New Yale Book of Quotations.

[5] H. Flack,et al. On enantiomorph‐polarity estimation , 1983 .

(2,2′-Bipyridine)tetra­carbonyl­molybdenum(0)

(2,2′-Bipyridine)tetracarbonylmolybdenum(0)