Low operating temperature toluene sensor based on novel α-Fe2O3/SnO2 heterostructure nanowire arrays

In this work, we reported a novel toluene sensor based on α-Fe2O3/SnO2 heterostructure nanowires arrays, which were synthesized via combining an ultrasonic spray pyrolysis (for the SnO2 nanowires arrays) method and the subsequent hydrothermal strategy (for the α-Fe2O3 nanorod branches). Various techniques were employed for the characterization of the structure and morphology of the as-obtained products. The results revealed that α-Fe2O3 nanorod branches grew on SnO2 nanowire arrays with an average length of about 800 nm. As a proof-of-concept demonstration of the function, such novel heterostructure nanowires arrays were used as the sensing material for gas sensors. As expected, the heterostructure composites exhibited good sensing performances for toluene, superior to a single component (SnO2 nanowires arrays). For example, the response of the α-Fe2O3/SnO2 composites was up to 5 times higher than that of the primary SnO2 nanowire arrays at 90 °C.

[1]  Jiajun Chen,et al.  Growth of monoclinic WO3nanowire array for highly sensitive NO2 detection , 2009 .

[2]  Thorsten Wagner,et al.  Ordered Mesoporous In2O3: Synthesis by Structure Replication and Application as a Methane Gas Sensor , 2009 .

[3]  S. Agarwala,et al.  Probing the morphology-device relation of Fe₂O₃ nanostructures towards photovoltaic and sensing applications. , 2012, Nanoscale.

[4]  N. D. Cuong,et al.  Synthesis, characterization, and comparative gas-sensing properties of Fe2O3 prepared from Fe3O4 and Fe3O4-chitosan , 2012 .

[5]  Duk-Dong Lee,et al.  Fabrication and characteristics of SnO2 gas sensor array for volatile organic compounds recognition , 2002 .

[6]  Xiaohong Sun,et al.  Nanocasting synthesis of In2O3 with appropriate mesostructured ordering and enhanced gas-sensing property. , 2014, ACS applied materials & interfaces.

[7]  Makoto Egashira,et al.  High H2 sensing performance of anodically oxidized TiO2 film contacted with Pd , 2002 .

[8]  Chan Woong Na,et al.  Selective detection of NO2 and C2H5OH using a Co3O4-decorated ZnO nanowire network sensor. , 2011, Chemical communications.

[9]  Anurat Wisitsoraat,et al.  Flame-Spray-Made Undoped Zinc Oxide Films for Gas Sensing Applications , 2010, Sensors.

[10]  Adisorn Tuantranont,et al.  Ultra-rapid VOCs sensors based on sparked-In2O3 sensing films , 2014 .

[11]  G. Lu,et al.  Design of Au@ZnO yolk-shell nanospheres with enhanced gas sensing properties. , 2014, ACS applied materials & interfaces.

[12]  Yigal Komem,et al.  The effect of grain size on the sensitivity of nanocrystalline metal-oxide gas sensors , 2004 .

[13]  N. Yamazoe,et al.  Oxide Semiconductor Gas Sensors , 2003 .

[14]  W. Wlodarski,et al.  Nanorod based Schottky contact gas sensors in reversed bias condition , 2010, Nanotechnology.

[15]  Xueling Gao,et al.  Fabrication of porous α-Fe2O3 nanoshuttles and their application for toluene sensors , 2014 .

[16]  A. Gurlo,et al.  Nanosensors: towards morphological control of gas sensing activity. SnO2, In2O3, ZnO and WO3 case studies. , 2011, Nanoscale.

[17]  N. Yamazoe,et al.  Cu-doped α-Fe2O3 hierarchical microcubes: Synthesis and gas sensing properties , 2014 .

[18]  A. Gurlo,et al.  Hybrid organotin and tin oxide-based thin films processed from alkynylorganotins: synthesis, characterization, and gas sensing properties. , 2014, ACS applied materials & interfaces.

[19]  Peng Sun,et al.  Growth of SnO2 nanowire arrays by ultrasonic spray pyrolysis and their gas sensing performance , 2014 .

[20]  Barrier-controlled carrier transport in microcrystalline semiconducting materials: Description within a unified model , 2002, cond-mat/0204427.

[21]  Ivan P. Parkin,et al.  A microstructural model of semiconducting gas sensor response: The effects of sintering temperature on the response of chromium titanate (CTO) to carbon monoxide , 2006 .

[22]  Pelagia-Irene Gouma,et al.  Ferroelectric WO3 Nanoparticles for Acetone Selective Detection , 2008 .

[23]  N. Yamazoe,et al.  Surface chemistry of neat tin oxide sensor for response to hydrogen gas in air , 2016 .

[24]  Buxing Han,et al.  A Highly Efficient Chemical Sensor Material for H2S: α‐Fe2O3 Nanotubes Fabricated Using Carbon Nanotube Templates , 2005 .

[25]  Xiaoming Sun,et al.  Highly sensitive WO3 hollow-sphere gas sensors. , 2004, Inorganic chemistry.

[26]  Hao Gong,et al.  Nano-crystalline Cu-doped ZnO thin film gas sensor for CO , 2006 .

[27]  G. Lu,et al.  Gas sensing with hollow α-Fe2O3 urchin-like spheres prepared via template-free hydrothermal synthesis , 2012 .

[28]  Eduard Llobet,et al.  Au nanoparticle-functionalised WO3 nanoneedles and their application in high sensitivity gas sensor devices. , 2011, Chemical communications.

[29]  Adisorn Tuantranont,et al.  Effects of cobalt doping on nitric oxide, acetone and ethanol sensing performances of FSP-made SnO2 nanoparticles , 2015 .

[30]  Xuejun Zheng,et al.  Synthesis and toluene sensing properties of SnO2 nanofibers , 2009 .

[31]  S. Phanichphant,et al.  Semiconducting metal oxides as sensors for environmentally hazardous gases , 2011 .

[32]  Adisorn Tuantranont,et al.  Electrolytically exfoliated graphene-loaded flame-made Ni-doped SnO2 composite film for acetone sensing. , 2015, ACS applied materials & interfaces.

[33]  N. Bârsan,et al.  Conduction Model of Metal Oxide Gas Sensors , 2001 .

[34]  Jianhui Zhu,et al.  Facile synthesis of α-Fe2O3@SnO2 core–shell heterostructure nanotubes for high performance gas sensors , 2015 .

[35]  Jiaqiang Xu,et al.  Hydrothermal synthesis of hierarchical SnO2 microspheres for gas sensing and lithium-ion batteries applications: Fluoride-mediated formation of solid and hollow structures , 2012 .

[36]  Yuehuan Li,et al.  One-pot synthesis of La-doped SnO2 layered nanoarrays with an enhanced gas-sensing performance toward acetone , 2016 .

[37]  Jing Wang,et al.  Hollow hierarchical SnO2-ZnO composite nanofibers with heterostructure based on electrospinning method for detecting methanol , 2014 .

[38]  A. Gurlo,et al.  Nanoscaled tin dioxide films processed from organotin-based hybrid materials: an organometallic route toward metal oxide gas sensors. , 2012, Nanoscale.

[39]  Peng Sun,et al.  Hierarchical Assembly of α-Fe₂O₃ Nanosheets on SnO2₂Hollow Nanospheres with Enhanced Ethanol Sensing Properties. , 2015, ACS applied materials & interfaces.

[40]  Sheikh A. Akbar,et al.  Gas Sensors Based on One Dimensional Nanostructured Metal-Oxides: A Review , 2012, Sensors.

[41]  G. Lu,et al.  Porous SnO2 hierarchical nanosheets: hydrothermal preparation, growth mechanism, and gas sensing properties , 2011 .