Synthesis and photoluminescence studies on ZnO nanowires

ZnO nanowires were grown in gram quantities on graphite flakes (as collector) using the vapour transport and condensation approach. The yield, defined as the weight ratio of ZnO nanowires to the original graphite flakes, has been studied thoroughly by tuning the various growth parameters such as pressure and temperature inside the tube furnace, the amount of graphite powder in the original source, the source to collector ratio, etc. A yield as high as 200% has been achieved, equivalent to a 40% conversion of the ZnO powder in the original source. A study comparing the photoluminescence spectra of the ZnO nanowires grown on both graphite flakes and substrates with commercially available ZnO powder has been carried out.

[1]  Ning Wang,et al.  FORMATION OF ZNO NANOSTRUCTURES BY A SIMPLE WAY OF THERMAL EVAPORATION , 2002 .

[2]  Eicke R. Weber,et al.  Catalytic Growth of Zinc Oxide Nanowires by Vapor Transport , 2001 .

[3]  Dapeng Yu,et al.  Ultraviolet-emitting ZnO nanowires synthesized by a physical vapor deposition approach , 2001 .

[4]  A. J. Shuskus,et al.  R.f. sputtered epitaxial ZnO films on sapphire for integrated optics , 1976 .

[5]  Phaedon Avouris,et al.  Field-Effect Transistors Based on Single Semiconducting Oxide Nanobelts , 2003 .

[6]  Giorgio Sberveglieri,et al.  A novel method for the preparation of NH3 sensors based on ZnO-In thin films , 1995 .

[7]  Hironori Arakawa,et al.  Highly efficient photon-to-electron conversion with mercurochrome-sensitized nanoporous oxide semiconductor solar cells , 2000 .

[8]  Martin Moskovits,et al.  Detection of CO and O2 Using Tin Oxide Nanowire Sensors , 2003 .

[9]  N. Chubachi ZnO films for surface acoustooptic devices on nonpiezoelectric substrates , 1976, Proceedings of the IEEE.

[10]  Peidong Yang,et al.  Nanowire ultraviolet photodetectors and optical switches , 2002 .

[11]  C. Lieber,et al.  Nanowire Nanosensors for Highly Sensitive and Selective Detection of Biological and Chemical Species , 2001, Science.

[12]  Diane M. Steeves,et al.  Large-quantity free-standing ZnO nanowires , 2003 .

[13]  Yeshayahu Lifshitz,et al.  Oxide‐Assisted Growth of Semiconducting Nanowires , 2003 .

[14]  Xinsheng Peng,et al.  Catalytic growth of semiconducting zinc oxide nanowires and their photoluminescence properties , 2002 .

[15]  Hisami Yumoto,et al.  Application of ITO films to photocatalysis , 1999 .

[16]  K. Nashimoto,et al.  Metal Alkoxide Solution-Derived Epitaxial Lead Titanate-Based Thin-Film Optical Waveguides , 1995 .

[17]  Yiying Wu,et al.  Room-Temperature Ultraviolet Nanowire Nanolasers , 2001, Science.

[18]  A. Freeman,et al.  Chemical and Thin-Film Strategies for New Transparent Conducting Oxides , 2000 .

[19]  Jih-Jen Wu,et al.  LOW-TEMPERATURE GROWTH OF WELL-ALIGNED ZNO NANORODS BY CHEMICAL VAPOR DEPOSITION , 2002 .

[20]  David S. Ginley,et al.  Transparent Conducting Oxides , 2000 .

[21]  Toru Aoki,et al.  ZnO diode fabricated by excimer-laser doping , 2000 .

[22]  H. R. Chandrasekhar,et al.  Optical and structural properties of ZnO films deposited on GaAs by pulsed laser deposition , 2000 .

[23]  M. Kadota Surface Acoustic Wave Characteristics of a ZnO/Quartz Substrate Structure Having a Large Electromechanical Coupling Factor and a Small Temperature Coefficient , 1997 .

[24]  Mengyan Shen,et al.  High temperature excitonic stimulated emission from ZnO epitaxial layers , 1998 .

[25]  E. Suh,et al.  Low temperature growth and photoluminescence of well-aligned zinc oxide nanowires , 2002 .

[26]  P. Couturier Japan , 1988, The Lancet.

[27]  Atsushi Ashida,et al.  Electro-optic property of ZnO:X (X=Li,Mg) thin films , 2002 .

[28]  William L. Warren,et al.  Correlation between photoluminescence and oxygen vacancies in ZnO phosphors , 1996 .

[29]  G. Heiland,et al.  Homogeneous semiconducting gas sensors , 1981 .