Multiwafer production of epitaxy ready 4" GaSb substrates: requirements for epitaxially growth infrared detectors

In this paper we describe the crystal growth and surface characterisation of ultra-flat 4" GaSb substrates suitable for the epitaxial deposition of advanced infrared detectors. Results will be presented on the production of single crystal 4" GaSb ingots grown by a modified version of the liquid encapsulated Czochralski (LEC) technique , supported by the analysis of bulk material quality by dislocation Etch Pit Density (EPD) and X-Ray topography (XRT) assessments. This study will also describe how various techniques were used to characterize the quality of the bare substrate. Surface oxide properties of the GaSb substrates will be characterized by spectroscopic ellipsometry (SE). Bow, Warp and Total Thickness Variation (TTV) data will be presented for 4" wafers processed on a multiwafer-type polishing platform. This study will conclude with a 'blueprint' for the manufacture of large diameter GaSb substrates, this defining the requirements for the production use of GaSb within a commercial epitaxial wafer foundry.

[1]  Frank Rutz,et al.  InAs/GaSb superlattices for advanced infrared focal plane arrays , 2009 .

[2]  Corey L. Bungay,et al.  Overview of variable-angle spectroscopic ellipsometry (VASE): I. Basic theory and typical applications , 1999, Optics + Photonics.

[3]  Yajun Wei,et al.  Very high quantum efficiency in type-II InAs/GaSb superlattice photodiode with cutoff of 12 μm , 2007 .

[4]  Xing Gu,et al.  Epitaxy ready 4" GaSb substrates: requirements for MBE grown type-II superlattice infrared detectors , 2010, Defense + Commercial Sensing.

[5]  Manijeh Razeghi,et al.  High performance long wavelength infrared mega-pixel focal plane array based on type-II superlattices , 2010 .

[6]  P. Norton HgCdTe Infrared Detectors , 2002 .

[7]  Meimei Z. Tidrow Type II strained layer superlattice: A potential future IR solution , 2009 .

[8]  Roberto Fornari,et al.  Bulk Crystal Growth of Semiconductors: An Overview , 2011 .

[9]  P. Rudolph,et al.  Present State and Future Tasks of III-V Bulk Crystal Growth , 2007, 2007 IEEE 19th International Conference on Indium Phosphide & Related Materials.

[10]  Antoni Rogalski,et al.  Optical detectors for focal plane arrays , 2004 .

[11]  D. V. Eddolls,et al.  Infrared Detector Materials , 1982 .

[12]  Dmitri Lubyshev,et al.  MBE growth of Sb-based type-II strained layer superlattice structures on multiwafer production reactors , 2010, Defense + Commercial Sensing.

[13]  Klavs F. Jensen,et al.  In-situ Reflectance Monitoring of GaSb Substrate Oxide Desorption , 2000 .

[14]  Peter Capper,et al.  Bulk crystal growth of electronic, optical & optoelectronic materials , 2005 .

[15]  Klaus-Werner Benz,et al.  White beam X-ray topography at the synchrotron light source ANKA, Research Centre Karlsruhe , 2003 .

[16]  Partha S. Dutta,et al.  The physics and technology of gallium antimonide: An emerging optoelectronic material , 1997 .

[17]  Mark J. Furlong,et al.  Antimonide based infrared materials: Developments in InSb and GaSb substrate technologies , 2010, 2010 22nd International Conference on Indium Phosphide and Related Materials (IPRM).