Multidisciplinary approaches to metallic bipolar plate design with bypass flow fields through deformable gas diffusion media of polymer electrolyte fuel cells

In this study, multidisciplinary approaches to optimizing serpentine gas flow channels stamped on sheet metal with various design parameters (i.e., channel-to-rib width ratio, draft angle, inner fillet radius, and channel depth) are implemented to identify the fluid–structure interaction characteristics of locally deformed gas diffusion media (GDM) and the rate of entropy generation for bypass flow through the porous GDM. First, static structural analysis is conducted to demonstrate the GDM deformation by stack compression and its mechanical effects on fluidic properties of GDM experimentally and numerically. The GDM-channel model results agree with the experimental results within a maximum error of less than 10%. Emphasis is placed on understanding how the reactant gas flow through GDM effectively transports the oxygen gas to catalyst layers. Next, parametric studies are conducted to identify the dominant design effects on the fluidic performance over the entire computational domain. Subsequently, a design optimization method is applied to obtain the most favorable flow channel designs with trapezoidal cross-sections. In the optimized serpentine channel design, the maximized oxygen transport ratio is predicted to be 0.718 at the interface between the GDM and catalyst layers under the constraint of total pressure drop.

[1]  Brant A. Peppley,et al.  Modeling the Influence of GDL and flow-field plate parameters on the reaction distribution in the PEMFC cathode catalyst layer , 2005 .

[2]  Nilanjan Chakraborty,et al.  A Direct Numerical Simulation-Based Analysis of Entropy Generation in Turbulent Premixed Flames , 2013, Entropy.

[3]  M. Muthukumar,et al.  Experimental investigation on uniform and zigzag positioned porous inserts on the rib surface of cathode flow channel for performance enhancement in PEMFC , 2015 .

[4]  Todd A. Jankowski,et al.  Minimizing entropy generation in internal flows by adjusting the shape of the cross-section , 2009 .

[5]  A. Bejan Entropy Generation Minimization: The Method of Thermodynamic Optimization of Finite-Size Systems and Finite-Time Processes , 1995 .

[6]  Qinghui Hu,et al.  Cr2O3/C composite coatings on stainless steel 304 as bipolar plate for proton exchange membrane fuel cell , 2014 .

[7]  Alexandra M.F.R. Pinto,et al.  Numerical simulations of two-phase flow in an anode gas channel of a proton exchange membrane fuel cell , 2015 .

[8]  Aziz Khan,et al.  Conical nano-structure arrays of Platinum cathode catalyst for enhanced cell performance in PEMFC (proton exchange membrane fuel cell) , 2015 .

[9]  C. Hochenauer,et al.  Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels , 2012 .

[10]  Shahram Karimi,et al.  A Review of Metallic Bipolar Plates for Proton Exchange Membrane Fuel Cells: Materials and Fabrication Methods , 2012 .

[11]  P. J. Sebastian,et al.  Numerical evaluation of a PEM fuel cell with conventional flow fields adapted to tubular plates , 2014 .

[12]  Don W. Green,et al.  Perry's Chemical Engineers' Handbook , 2007 .

[13]  Ramana G. Reddy,et al.  Effect of channel dimensions and shape in the flow-field distributor on the performance of polymer electrolyte membrane fuel cells , 2003 .

[14]  Adriano Sciacovelli,et al.  Entropy generation analysis in a monolithic-type solid oxide fuel cell (SOFC) , 2009 .

[15]  Jun Ni,et al.  Fabrication of Metallic Bipolar Plates for Proton Exchange Membrane Fuel Cell by Flexible Forming Process-Numerical Simulations and Experiments , 2010 .

[16]  M. Fowler,et al.  In-plane and through-plane gas permeability of carbon fiber electrode backing layers , 2006 .

[17]  Entropy production analysis of swirling diffusion combustion processes , 2010 .

[18]  Olli Himanen,et al.  Inhomogeneous compression of PEMFC gas diffusion layer: Part II. Modeling the effect , 2007 .

[19]  Abdul-Ghani Olabi,et al.  Design of experiment study of the parameters that affect performance of three flow plate configurations of a proton exchange membrane fuel cell , 2010 .

[20]  Alfredo Iranzo,et al.  Investigation of the liquid water distributions in a 50 cm2 PEM fuel cell: Effects of reactants relative humidity, current density, and cathode stoichiometry , 2015 .

[21]  Z. Ren,et al.  Stacks with TiN/titanium as the bipolar plate for PEMFCs , 2012 .

[22]  K. Lum,et al.  Optimization of assembly clamping pressure on performance of proton-exchange membrane fuel cells , 2010 .

[23]  A. Olabi,et al.  Representative model and flow characteristics of open pore cellular foam and potential use in proton exchange membrane fuel cells , 2015 .

[24]  Bernhard A. Schrefler,et al.  The Finite Element Method in the Deformation and Consolidation of Porous Media , 1987 .

[25]  Chongdu Cho,et al.  Effect of gas-diffusion electrode material heterogeneity on the structural integrity of polymer elec , 2010 .

[26]  T. Shudo,et al.  Experimental and numerical modeling study of the electrical resistance of gas diffusion layer-less polymer electrolyte membrane fuel cells , 2015 .

[27]  Qinghui Hu,et al.  Effect of flow-field dimensions on the formability of Fe–Ni–Cr alloy as bipolar plate for PEM (proton exchange membrane) fuel cell , 2015 .

[28]  B. Benicewicz,et al.  Synthesis of Poly (2,2′‐(1,4‐phenylene) 5,5′‐bibenzimidazole) (para‐PBI) and Phosphoric Acid Doped Membrane for Fuel Cells , 2009 .

[29]  M. Al-Nimr,et al.  Using the multiple regression analysis with respect to ANOVA and 3D mapping to model the actual performance of PEM (proton exchange membrane) fuel cell at various operating conditions , 2015 .

[30]  G. Fedder,et al.  Micro-electro-mechanical systems (MEMS)-based micro-scale direct methanol fuel cell development , 2006 .

[31]  Yiwu Weng,et al.  Effect of operating parameters on a hybrid system of intermediate-temperature solid oxide fuel cell and gas turbine , 2015 .

[32]  R. Pitchumani,et al.  MEASUREMENT AND PREDICTION OF ELECTRICAL CONTACT RESISTANCE BETWEEN GAS DIFFUSION LAYERS AND BIPOLAR PLATE FOR APPLICATIONS TO PEM FUEL CELLS , 2004 .

[33]  Félix Barreras,et al.  Optimal design and operational tests of a high-temperature PEM fuel cell for a combined heat and power unit , 2014 .

[34]  Sukkee Um,et al.  An engineering approach to optimal metallic bipolar plate designs reflecting gas diffusion layer compression effects , 2012 .

[35]  Hyung Jin Sung,et al.  Effects of channel geometrical configuration and shoulder width on PEMFC performance at high current density , 2006 .

[36]  R. Chouikh,et al.  A numerical investigation of reactant transport in a PEM fuel cell with partially blocked gas channels , 2014 .

[37]  Chin-Hsiang Cheng,et al.  Effects of porosity gradient in gas diffusion layers on performance of proton exchange membrane fuel cells , 2010 .

[38]  Jae Wan Park,et al.  Alloy Selection and Die Design for Stamped Proton Exchange Membrane Fuel Cell (PEMFC) Bipolar Plates , 2014 .

[39]  Xinmin Lai,et al.  Study on shape error effect of metallic bipolar plate on the GDL contact pressure distribution in proton exchange membrane fuel cell , 2013 .

[40]  T. Berning,et al.  Polymer electrolyte fuel cells based on phosphoric acid doped polybenzimidazole (PBI) membranes , 2007 .