Polymers at Interfaces and the Interactions in Colloidal Dispersions

Abstract Solutions of different polymers in the same solvent are incompatible as a rule and show phase separation when they are mixed. If incompatibility is also to be observed in systems where one of the polymer components is replaced by colloidal particles, sterically stabilized by a cover of polymer chains, will be discussed in this lecture. After a discussion of the applicability of statistical thermodynamical criteria for colloid stability we focus attention on the potential of average force between two particles, V(r), and the second virial coefficient, B2. First it is shown from general arguments that V(r) and B2 always decrease in magnitude upon addition of particles identical to the particle pair considered. The decrease is particularly large for high molecular weight polymers. Subsequently, the analysis is extended, with the help of simple models, to mixtures of polymer colloid and polymer. It is predicted that B2 should decrease and may become negative when the molecular weight and concentration of the polymer are sufficiently large. For high molecular weight polymer this is of the order of a per cent or less. More polymer is needed for low molecular weights. The destabilization is intimately connected with the expulsion of polymer from the interstitial spaces between approaching particles because of “volume restriction”- and “osmotic” effects. The predictions are in accordance with some experiments that were available. Finally the applicability of light scattering as an experimental tool in these stability problems is stressed. Results are also given of the incompatibility of two polymers in a single solvent in which one of the polymers is masked i.e. does not scatter light.

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