A general model of proton exchange membrane fuel cell

In this study, a general model of proton exchange membrane fuel cell (PEMFC) was constructed, implemented and employed to simulate the fluid flow, heat transfer, species transport, electrochemical reaction, and current density distribution, especially focusing on liquid water effects on PEMFC performance. The model is a three-dimensional and unsteady one with detailed thermo-electrochemistry, multi-species, and two-phase interaction with explicit gas–liquid interface tracking by using the volume-of-fluid (VOF) method. The general model was implemented into the commercial computational fluid dynamics (CFD) software package FLUENT® v6.2, with its user-defined functions (UDFs). A complete PEMFC was considered, including membrane, gas diffusion layers (GDLs), catalyst layers, gas flow channels, and current collectors. The effects of liquid water on PEMFC with serpentine channels were investigated. The results showed that this general model of PEMFC can be a very useful tool for the optimization of practical engineering designs of PEMFC.

[1]  S. Dutta,et al.  Three-dimensional numerical simulation of straight channel PEM fuel cells , 2000 .

[2]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[3]  Loreto Daza,et al.  Optimisation of flow-field in polymer electrolyte membrane fuel cells using computational fluid dynamics techniques , 2000 .

[4]  Mark Pritzker,et al.  Pore network modeling of fibrous gas diffusion layers for polymer electrolyte membrane fuel cells , 2007 .

[5]  E. Passalacqua,et al.  Modeling of porous membranes for molten carbonate fuel cells , 1997 .

[6]  Ned Djilali,et al.  A 3D, Multiphase, Multicomponent Model of the Cathode and Anode of a PEM Fuel Cell , 2003 .

[7]  Chao-Yang Wang,et al.  Large-scale simulation of polymer electrolyte fuel cells by parallel computing , 2004 .

[8]  N. Djilali,et al.  Determination of transport parameters for multiphase flow in porous gas diffusion electrodes using a capillary network model , 2007 .

[9]  Werner Lehnert,et al.  Quasi–in situ neutron tomography on polymer electrolyte membrane fuel cell stacks , 2007 .

[10]  Trung Van Nguyen,et al.  Three-dimensional effects of liquid water flooding in the cathode of a PEM fuel cell , 2003 .

[11]  R. O’Hayre,et al.  Fuel Cell Fundamentals , 2005 .

[12]  T. Springer,et al.  Polymer Electrolyte Fuel Cell Model , 1991 .

[13]  Hongtan Liu,et al.  A two-phase flow and transport model for the cathode of PEM fuel cells , 2002 .

[14]  Joel H. Ferziger,et al.  Computational methods for fluid dynamics , 1996 .

[15]  Chaoyang Wang,et al.  Nonisothermal Modeling of Polymer Electrolyte Fuel Cells II. Parametric Study of Low-Humidity Operation , 2006 .

[16]  Biao Zhou,et al.  Water behavior in serpentine micro-channel for proton exchange membrane fuel cell cathode , 2005 .

[17]  Hyunchul Ju,et al.  Experimental Validation of a PEM Fuel Cell Model by Current Distribution Data , 2004 .

[18]  Chaoyang Wang,et al.  Visualization of Liquid Water Transport in a PEFC , 2004 .

[19]  Biao Zhou,et al.  Liquid water transport in straight micro-parallel-channels with manifolds for PEM fuel cell cathode , 2006 .

[20]  A. A. Kulikovsky,et al.  Numerical simulation of a new operational regime for a polymer electrolyte fuel cell , 2001 .

[21]  Suk Won Cha,et al.  The scaling behavior of flow patterns: a model investigation , 2004 .

[22]  P. Sui,et al.  Dynamic behaviour of liquid water emerging from a GDL pore into a PEMFC gas flow channel , 2007 .

[23]  Michael Vynnycky,et al.  On the modelling of two-phase flow in the cathode gas diffusion layer of a polymer electrolyte fuel cell , 2007, Appl. Math. Comput..

[24]  James Larminie,et al.  Fuel Cell Systems Explained , 2000 .

[25]  Chao-Yang Wang,et al.  Two-phase transport and the role of micro-porous layer in polymer electrolyte fuel cells , 2004 .

[26]  Biao Zhou,et al.  Innovative gas diffusion layers and their water removal characteristics in PEM fuel cell cathode , 2007 .

[27]  Chao-Yang Wang,et al.  A Nonisothermal, Two-Phase Model for Polymer Electrolyte Fuel Cells , 2006 .

[28]  Jin Hyun Nam,et al.  Effective diffusivity and water-saturation distribution in single- and two-layer PEMFC diffusion medium , 2003 .

[29]  Xuan Liu,et al.  Water flooding and two-phase flow in cathode channels of proton exchange membrane fuel cells , 2006 .

[30]  Jürgen Mergel,et al.  Interaction between the diffusion layer and the flow field of polymer electrolyte fuel cells—experiments and simulation studies , 2003 .

[31]  Chao-Yang Wang,et al.  Pore-network modeling of liquid water transport in gas diffusion layer of a polymer electrolyte fuel cell , 2007 .

[32]  Kirk W Feindel,et al.  In situ observations of water production and distribution in an operating H2/O2 PEM fuel cell assembly using 1H NMR microscopy. , 2004, Journal of the American Chemical Society.

[33]  Biao Zhou,et al.  Effects of electrode wettabilities on liquid water behaviours in PEM fuel cell cathode , 2008 .

[34]  C. Peskin Numerical analysis of blood flow in the heart , 1977 .

[35]  Biao Zhou,et al.  Liquid water transport in parallel serpentine channels with manifolds on cathode side of a PEM fuel cell stack , 2006 .

[36]  Chao-Yang Wang,et al.  Model of Two-Phase Flow and Flooding Dynamics in Polymer Electrolyte Fuel Cells , 2005 .

[37]  Chaoyang Wang,et al.  Probing Liquid Water Saturation in Diffusion Media of Polymer Electrolyte Fuel Cells , 2007 .

[38]  Jung S. Yi,et al.  Water management along the flow channels of PEM fuel cells , 2004 .

[39]  Frano Barbir,et al.  PEM Fuel Cells , 2006 .

[40]  Chao-Yang Wang,et al.  Ultra large-scale simulation of polymer electrolyte fuel cells , 2006 .

[41]  Chaoyang Wang,et al.  Two-Phase Modeling and Flooding Prediction of Polymer Electrolyte Fuel Cells , 2005 .

[42]  Feng-Yuan Zhang,et al.  Liquid Water Removal from a Polymer Electrolyte Fuel Cell , 2006 .

[43]  Chao-Yang Wang,et al.  Computational Fluid Dynamics Modeling of Proton Exchange Membrane Fuel Cells , 2000 .