A One‐Dimensional Manganese(II) Coordination Polymer Derived from Zerovalent Manganese and 1‐Hydroxybenzotriazole − Synthesis, Characterization, Crystal Structure and Magnetic Properties

The reaction of zerovalent manganese with 1-hydroxybenzotriazole, btaOH, and NH4SCN in DMF in the presence of dioxygen allows isolation of the one-dimensional coordination polymer [Mn3(btaO)2(NCS)4(DMF)8]n (3). X-ray diffraction analysis reveals that the chain is best described as [Mn2(btaO)2(NCS)2(DMF)6] dimers linked by Mn(NCS)2

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