Hydraulic lime mortar in the ambit of stone restoration: evaluation of applicability

This study presents the results of the applicability of hydraulic lime mortars in the ambit of stone conserva- tion and restoration. Historical buildings, as well as sculptures or ornamental artworks exposed to environmental influences, composed by natural stone materials suffer severe alteration/degradation in the course of time. On this account, the physico- chemical properties of hydraulic lime mortars have been compared with those of two calcarenitic rocks (Barxeta and Bateig azul), found in historical Valencian monuments. A systematically analytical procedural method was established on a series of test specimens in order to prove compatibility/ replaceability of limestones. The specimens were subjected to standard accelerated physical-chemical ageing tests. Compressive and flexural strength tests have been performed on the mortars and the stone material in order to determine the physical degra- dation. Alteration by chemical attack was simulated by the exposure in a SO 2 pollutant chamber and salt crystallisation test. The experiments performed show that the applied mortars have on one hand similar physical resistance and on the other hand present higher chemical resistance properties, especially against salt crystallisation in comparison to the natural stones and therefore might be of special interest for replicas.

[1]  Erhard M. Winkler,et al.  Salt Burst by Hydration Pressures in Architectural Stone in Urban Atmosphere , 1970 .

[2]  P. Jacobs,et al.  The role of saline solution properties on porous limestone salt weathering by magnesium and sodium sulfates , 2007 .

[3]  J. Lanas,et al.  MECHANICAL PROPERTIES OF NATURAL HYDRAULIC LIME-BASED MORTARS , 2004 .

[4]  Carl W. Correns,et al.  Growth and dissolution of crystals under linear pressure , 1949 .

[5]  Eleni Aggelakopoulou,et al.  Strength development and lime reaction in mortars for repairing historic masonries , 2005 .

[6]  Nabajyoti Saikia,et al.  Cementitious properties of metakaolin–normal Portland cement mixture in the presence of petroleum effluent treatment plant sludge , 2002 .

[7]  G. Scherer Stress from crystallization of salt , 2004 .

[8]  Robert J. Flatt,et al.  Salt damage in porous materials: how high supersaturations are generated , 2002 .

[9]  M. Doménech-Carbó,et al.  SEM/EDX and vis spectrophotometry study of the stability of resin-bound mortars used for casting replicas and filling missing parts of historic stone fountains , 2003, Analytical and bioanalytical chemistry.

[10]  Peur F. Konn INFRARED ABSORPTION FREQUENCY TRENDS FOR ANHYDROUS NORMAL CARBONATES , 2007 .

[11]  Koenraad Van Balen,et al.  Modelling lime mortar carbonation , 1994 .

[12]  J. Lanas,et al.  Masonry repair lime-based mortars: factors affecting the mechanical behavior , 2003 .

[13]  S. Shoval Using FT-IR spectroscopy for study of calcareous ancient ceramics , 2003 .

[14]  I. Evans Salt crystallization and rock weathering: a review , 1970 .

[15]  S. Sahu,et al.  Mechanism of concrete deterioration due to salt crystallization , 2004 .

[16]  Rafael Fort,et al.  Thermodynamic modelling of changes induced by salt pressure crystallisation in porous media of stone , 1999 .

[17]  Commission 25-PEM Protection et érosion des monuments , 1980 .

[18]  X. Barberá Estudio y caracterización de morteros compuestos, para su aplicación en intervenciones de sellados, reposiciones y réplicas, de elementos pétreos escultórico-ornamentales , 2011 .

[19]  R. Flatt,et al.  Hydration and crystallization pressure of sodium sulfate: A critical review , 2002 .

[20]  J. I. Alvarez,et al.  Pore structure and mechanical properties of cement–lime mortars , 2007 .

[21]  E. Winkler,et al.  Crystallization Pressure of Salts in Stone and Concrete , 1972 .

[22]  S. Gunasekaran,et al.  Raman and infrared spectra of carbonates of calcite structure , 2006 .

[23]  George W. Scherer,et al.  Crystallization in pores , 1999 .

[24]  K. Van Balen,et al.  Carbonation reaction of lime, kinetics at ambient temperature , 2005 .

[25]  Rafael Fort,et al.  Natural cement as the precursor of Portland cement: Methodology for its identification , 2005 .

[26]  Ioannis Karatasios,et al.  Hydraulic Lime Mortars for the Restoration of Historic Masonry in Crete , 2005 .