Optical Methods Based on Ultraviolet, Visible, and Near-Infrared Spectra to Estimate Fat and Protein in Raw Milk: A Review

The present manuscript focuses on reviewing the optical techniques proposed to monitor milk quality in dairy farms to increase productivity and reduce costs. As is well known, the quality is linked to the fat and protein concentration; in addition, this issue is crucial to maintaining a healthy herd and preventing illnesses such as mastitis and ketosis. Usually, the quality of the milk is carried out with invasive methods employing chemical reagents that increase the time analysis. As a solution, several spectroscopy optical methods have been proposed, here, the benefits such as non-invasive measurement, online implementation, rapid estimation, and cost-effective execution. The most attractive optical methods to estimate fat and protein in cow’s milk are compared and discussed considering their performance. The analysis is divided considering the wavelength operation (ultraviolet, visible, and infrared). Moreover, the weaknesses and strengths of the methods are fully analyzed. Finally, we provide the trends and a recent technique based on spectroscopy in the visible wavelength.

[1]  Bandaru Ramakrishna,et al.  U-bent plastic optical fiber probes as refractive index based fat sensor for milk quality monitoring , 2019, Optical Fiber Technology.

[2]  J. D. Pettinati,et al.  Photometric Milk Fat Determination , 1959 .

[3]  L. Ragni,et al.  Spectral-sensitive Pulsed Photometry to predict the fat content of commercialized milk , 2016 .

[4]  E. Hartung,et al.  Accuracy of in-line milk composition analysis with diffuse reflectance near-infrared spectroscopy. , 2012, Journal of dairy science.

[5]  Yan Wang,et al.  Research on Rapid Detection Method of Protein and Fat in Raw Milk Based on Mid-infrared Spectrum , 2016, MUE 2016.

[6]  Rudolf W. Kessler,et al.  Quantitative determination of fat and total protein in milk based on visible light scatter , 2012 .

[7]  S. Nakai,et al.  Spectrophotometric determination of protein and fat in milk simultaneously. , 1970 .

[8]  Aditya Dave,et al.  Ultrasonic sensing system for detecting water adulteration in milk , 2016, 2016 IEEE Region 10 Conference (TENCON).

[9]  José Santa,et al.  Smart farming IoT platform based on edge and cloud computing , 2019, Biosystems Engineering.

[10]  R. Jenny,et al.  Fundamentals of Optics , 2001 .

[11]  A. Bogomolov,et al.  Scatter-based quantitative spectroscopic analysis of milk fat and total protein in the region 400-1100nm in the presence of fat globule size variability , 2013 .

[12]  J. D. S. Goulden,et al.  Analysis of milk by infra-red absorption , 1964, Journal of Dairy Research.

[13]  Robert D. O'Neill,et al.  Design and construction of a low cost single-supply embedded telemetry system for amperometric biosensor applications , 2007 .

[14]  Qi Xin,et al.  The rapid determination of fat and protein content in fresh raw milk using the laser light scattering technology , 2006 .

[15]  Zhaobing Tian,et al.  Single-Mode Fiber Refractive Index Sensor Based on Core-Offset Attenuators , 2008, IEEE Photonics Technology Letters.

[16]  Sergey Kucheryavskiy,et al.  Determination of fat and total protein content in milk using conventional digital imaging. , 2014, Talanta.

[17]  J. Lammertyn,et al.  Visible and near-infrared spectroscopic analysis of raw milk for cow health monitoring: reflectance or transmittance? , 2011, Journal of dairy science.

[18]  Motoyasu Natsuga,et al.  Near-infrared spectroscopic sensing system for online monitoring of milk quality during milking , 2007 .

[19]  Dean Calloway,et al.  Beer-Lambert Law , 1997 .

[20]  C. Tropea,et al.  Light Scattering from Small Particles , 2003 .

[21]  A. Kuaye An ultraviolet spectrophotometric method to determine milk protein content in alkaline medium , 1994 .

[22]  Fuminori Terada,et al.  Development of a New Measurement Unit (MilkSpec-1) for Rapid Determination of Fat, Lactose, and Protein in Raw Milk Using Near-Infrared Transmittance Spectroscopy , 2002 .

[23]  J. Markwell,et al.  Assays for Determination of Protein Concentration , 2007, Current protocols in protein science.

[24]  M Pinar Mengüç,et al.  Characterization of milk properties with a radiative transfer model. , 2002, Applied optics.

[25]  Q. Lüthi-Peng,et al.  Determination of protein and casein in milk by fourth derivative UV spectrophotometry , 1999 .

[26]  Motoyasu Natsuga,et al.  Near-infrared spectroscopic sensing system for on-line milk quality assessment in a milking robot , 2008 .

[27]  Yanbo Cao,et al.  Portable analyzer for rapid analysis of total protein, fat and lactose contents in raw milk measured by non-dispersive short-wave near-infrared spectrometry , 2013, Chemical Research in Chinese Universities.

[28]  J. Lammertyn,et al.  Visible and near-infrared bulk optical properties of raw milk. , 2015, Journal of dairy science.

[29]  Doreen Eichel,et al.  Basic Principles Of Spectroscopy , 2016 .

[30]  Byeong Ha Lee,et al.  Interferometric Fiber Optic Sensors , 2012, Sensors.

[31]  M. De Marchi,et al.  Short communication: Selecting the most informative mid-infrared spectra wavenumbers to improve the accuracy of prediction models for detailed milk protein content. , 2016, Journal of dairy science.

[32]  N. Corral,et al.  COMPARISON OF PRINCIPAL COMPONENT REGRESSION (PCR) AND PARTIAL LEAST SQUARE (PLS) METHODS IN PREDICTION OF RAW MILK COMPOSITION BY VIS-NIR SPECTROMETRY. APPLICATION TO DEVELOPMENT OF ON-LINE SENSORS FOR FAT, PROTEIN AND LACTOSE CONTENTS , 2009 .

[33]  Michael Ngadi,et al.  Applications of spectroscopic techniques for fat and fatty acids analysis of dairy foods , 2017 .

[34]  M. Laporte,et al.  Quantitation of Proteins in Milk and Milk Products , 2003 .

[35]  P. F. Fox,et al.  Dairy Chemistry and Biochemistry , 1998 .

[36]  W. Hübner,et al.  Infrared Spectroscopy in Aqueous Solution: Difficulties and Accuracy of Water Subtraction , 1997 .

[37]  John N. Lygouras,et al.  Design and evaluation of a hardware/software FPGA-based system for fast image processing , 2008, Microprocess. Microsystems.

[38]  CongDuc Pham,et al.  Precision Livestock Farming Technologies , 2018, 2018 Global Internet of Things Summit (GIoTS).

[39]  M. Meurens,et al.  Performance comparison of UV and FT-Raman spectroscopy in the determination of conjugated linoleic acids in cow milk fat. , 2008, Journal of agricultural and food chemistry.

[40]  Henry F. Taylor,et al.  Fiber-optic Fabry-Perot temperature sensor using a low-coherence light source , 1991 .

[41]  Y. Etzion,et al.  Determination of protein concentration in raw milk by mid-infrared fourier transform infrared/attenuated total reflectance spectroscopy. , 2004, Journal of dairy science.

[42]  Milk | Physical and Physico-Chemical Properties of Milk , 2011 .

[43]  M. Pinar Mengüç,et al.  EFFECT OF FAT AND CASEIN PARTICLES IN MILK ON THE SCATTERING OF ELLIPTICALLY POLARIZED LIGHT , 2005 .

[44]  Ke Yan,et al.  A Monitoring System for Vegetable Greenhouses based on a Wireless Sensor Network , 2010, Sensors.

[45]  Alwin Kienle,et al.  Broadband Optical Properties of Milk , 2017, Applied spectroscopy.

[46]  H. J. Luinge,et al.  Determination of the fat, protein and lactose content of milk using Fourier transform infrared spectrometry , 1993 .

[47]  Yong Zhao,et al.  A Mach-Zehnder interferometer-based High Sensitivity Temperature sensor for human body monitoring , 2018, Optical Fiber Technology.

[48]  Werner Mäntele,et al.  UV-VIS absorption spectroscopy: Lambert-Beer reloaded. , 2017, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[49]  J. Zoueu,et al.  Quantitative measurements of turbid liquids via structured laser illumination planar imaging where absorption spectrophotometry fails. , 2017, Applied optics.

[50]  Kun Qian,et al.  A rapid method for measuring fat content in milk based on W-type optical fibre sensor system , 2016 .

[51]  Y. Ozaki,et al.  Short-wave near-infrared spectroscopy of biological fluids. 1. Quantitative analysis of fat, protein, and lactose in raw milk by partial least-squares regression and band assignment. , 2001, Analytical chemistry.

[52]  J. D. Filoteo-Razo,et al.  Generation of supercontinuum light in micro-structured fiber and polarization study at different wavelengths , 2016, Optical Engineering + Applications.

[53]  D. Forcato,et al.  Milk fat content measurement by a simple UV spectrophotometric method: an alternative screening method. , 2005, Journal of dairy science.

[54]  Daniel Jauregui-Vazquez,et al.  A New Method for Total Fat Detection in Raw Milk Based on Dual Low-Coherence Interferometer , 2019, Sensors.