Advances on methane steam reforming to produce hydrogen through membrane reactors technology: A review

ABSTRACT Methane steam reforming is the most common industrial process used for almost the 50% of the world’s hydrogen production. Commonly, this reaction is performed in fixed bed reactors and several stages are needed for separating hydrogen with the desired purity. The membrane reactors represent a valid alternative to the fixed bed reactors, by combining the reforming reaction for producing hydrogen and its separation in only one stage. This article deals with the recent progress on methane steam reforming reaction, giving a short overview on catalysts utilization as well as on the fundamentals of membrane reactors, also summarizing the relevant advancements in this field.

[1]  P. Nielsen,et al.  Steam reforming of methane in a membrane reactor , 1995 .

[2]  Marcello De Falco,et al.  Pd-based Selective Membrane State-of-the-Art , 2011 .

[3]  H. Nakajima,et al.  Development of membrane reformer system for highly efficient hydrogen production from natural gas , 2009 .

[4]  Francesco Paolo Di Maio,et al.  Optimization of membrane area and catalyst distribution in a permeative-stage membrane reactor for methane steam reforming , 2008 .

[5]  Mohd Nasir Jamaluddin Abd Rahman,et al.  Development of a catalytic hollow fibre membrane micro-reactor for high purity H 2 production , 2011 .

[6]  P. Pfeifer,et al.  Ultra-compact microstructured methane steam reformer with integrated Palladium membrane for on-site production of pure hydrogen: Experimental demonstration , 2014 .

[7]  Jam Hans Kuipers,et al.  Modelling of packed bed membrane reactors for autothermal production of ultrapure hydrogen , 2006 .

[8]  M. Tańczyk,et al.  Mathematical simulation of WGS membrane reactor for gas from coal gasification , 2010 .

[9]  J. Requies,et al.  Biogas steam and oxidative reforming processes for synthesis gas and hydrogen production in conventional and microreactor reaction systems , 2012 .

[10]  G. Froment,et al.  Methane steam reforming: II. Diffusional limitations and reactor simulation , 1989 .

[11]  M. Šarić,et al.  Steam reforming of methane in a bench-scale membrane reactor at realistic working conditions , 2012 .

[12]  A. Basile,et al.  Membrane reactors for methane steam reforming (MSR) , 2015 .

[13]  Sushil Adhikari,et al.  Hydrogen Membrane Separation Techniques , 2006 .

[14]  J.A.M. Kuipers,et al.  Fluidised bed membrane reactor for ultrapure hydrogen production via methane steam reforming: Experimental demonstration and model validation , 2007 .

[15]  John R. Grace,et al.  Characteristics of Fluidized-Bed Membrane Reactors: Scale-up and Practical Issues , 1997 .

[16]  Marcello De Falco,et al.  Pd-based membrane steam reformers: A simulation study of reactor performance , 2008 .

[17]  R. Dittmeyer,et al.  Methane steam reforming operation and thermal stability of new porous metal supported tubular palladium composite membranes , 2013 .

[18]  A. M. Efstathiou,et al.  Hydrogen Production Technologies: Current State and Future Developments , 2013 .

[19]  Nikos G. Papayannakos,et al.  Membrane reactor modelling : A comparative study to evaluate the role of combined mass and heat dispersion in large-scale adiabatic membrane modules , 2005 .

[20]  Hengyong Xu,et al.  Efficient production of hydrogen from natural gas steam reforming in palladium membrane reactor , 2008 .

[21]  K. Sotowa,et al.  Methane steam reforming over Ce–ZrO2-supported noble metal catalysts at low temperature , 2004 .

[22]  P. Roy,et al.  Metal foam-supported Pd–Rh catalyst for steam methane reforming and its application to SOFC fuel processing , 2014 .

[23]  J. Múnera,et al.  Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review , 2015 .

[24]  Hiroyuki Suda,et al.  Experimental Study of Steam Reforming of Methane in a Thin (6 μM) Pd-Based Membrane Reactor , 2005 .

[25]  R. Keiski,et al.  Microreactors and membrane microreactors: fabrication and applications , 2013 .

[26]  Laurent Falk,et al.  Steam methane reforming reaction process intensification by using a millistructured reactor: Experimental setup and model validation for global kinetic reaction rate estimation , 2012 .

[27]  E. Hensen,et al.  The role of promoters for Ni catalysts in low temperature (membrane) steam methane reforming , 2011 .

[28]  Hsin-Fu Chang,et al.  Biogas reforming for hydrogen production over mesoporous Ni2xCe1−xO2 catalysts , 2012 .

[29]  J. Caro,et al.  Catalysis in Micro-structured Membrane Reactors with Nano-designed Membranes , 2008 .

[30]  Maohong Fan,et al.  The progress in water gas shift and steam reforming hydrogen production technologies – A review , 2014 .

[31]  K. Kato,et al.  Bubble assemblage model for fluidized bed catalytic reactors , 1969 .

[32]  G. Manzolini,et al.  H2 production by low pressure methane steam reforming in a Pd–Ag membrane reactor over a Ni-based catalyst: Experimental and modeling , 2010 .

[33]  Y. Matsumura,et al.  Steam reforming of methane over nickel catalysts at low reaction temperature , 2004 .

[34]  A. Singh,et al.  Steam reforming of methane and methanol in simulated macro & micro-scale membrane reactors: Selective separation of hydrogen for optimum conversion , 2014 .

[35]  Tatiana de Freitas Silva,et al.  Hydrogen production from oxidative reforming of methane on Ni/γ-Al2O3 catalysts: Effect of support promotion with La, La–Ce and La–Zr , 2014 .

[36]  W. Ueda,et al.  Quantitative Analysis of Coke Formation during Steam Reforming of Methane on a Nickel-Hydrotalcite Catalyst under Practical Operation Conditions , 2013 .

[37]  Thijs Peters,et al.  Experimental investigation of a microchannel membrane configuration with a 1.4 μm Pd/Ag23 wt.% membrane—Effects of flow and pressure , 2009 .

[38]  Stefan Heinrich,et al.  Membrane assisted fluidized bed reactors: Potentials and hurdles , 2007 .

[39]  Catalytic reforming of natural gas for hydrogen production in a pilot fluidized-bed membrane reactor , 2011 .

[40]  M. Labaki,et al.  Hydrogen production by methane steam reforming over Ru supported on Ni–Mg–Al mixed oxides prepared via hydrotalcite route , 2015 .

[41]  T. Boyd,et al.  Pure hydrogen generation in a fluidized-bed membrane reactor: Experimental findings , 2008 .

[42]  Riitta L. Keiski,et al.  Hydrogen production for PEM fuel cell by gas phase reforming of glycerol as byproduct of bio-diesel. The use of a Pd-Ag membrane reactor at middle reaction temperature , 2011 .

[43]  Enrico Drioli,et al.  Process Intensification for greenhouse gas separation from biogas: More efficient process schemes based on membrane-integrated systems , 2015 .

[44]  Yi Hua Ma,et al.  Modeling and performance assessment of Pd- and Pd/Au-based catalytic membrane reactors for hydrogen production , 2009 .

[45]  Jam Hans Kuipers,et al.  Experimental study of a membrane assisted fluidized bed reactor for H2 production by steam reforming of CH4 , 2006 .

[46]  G. Manzolini,et al.  CFD simulation of Pd-based membrane reformer when thermally coupled within a fuel cell micro-CHP system , 2010 .

[47]  A. Lemonidou,et al.  State-of-the-art catalysts for CH4 steam reforming at low temperature , 2014 .

[48]  Shin-Kun Ryi,et al.  A multi-membrane reformer for the direct production of hydrogen via a steam-reforming reaction of methane , 2012 .

[49]  John R. Grace,et al.  Modeling of fluidized bed membrane reactors for hydrogen production from steam methane reforming with Aspen Plus , 2009 .

[50]  K. Yoshikawa,et al.  Hydrogen generation from biogas reforming using a gliding arc plasma-catalyst reformer , 2009 .

[51]  M. Rahimpour,et al.  A novel slurry bubble column membrane reactor concept for Fischer–Tropsch synthesis in GTL technology , 2012 .

[52]  Yoshiaki Hideshima,et al.  Estimation of hydrogen output from a full-scale plant for production of hydrogen from biogas , 2010 .

[53]  Masayuki Haraguchi,et al.  Low temperature steam reforming of methane over metal catalyst supported on CexZr1―xO2 in an electric field , 2011 .

[54]  David Chadwick,et al.  Catalytic steam reforming of methane over Ce0.9Gd0.1O2−x , 2004 .

[55]  A. S. Al-Ubaid,et al.  Intrinsic kinetics of nickel/calcium aluminate catalyst for methane steam reforming , 2007 .

[56]  Wen-ching Yang Handbook of Fluidization and Fluid-Particle Systems , 2003 .

[57]  Carlos A. Grande,et al.  Steam methane reforming in a Ni/Al2O3 catalyst: Kinetics and diffusional limitations in extrudates , 2009 .

[58]  John R. Grace,et al.  The fluidized bed membrane reactor system: a pilot scale experimental study , 1994 .

[59]  M.E.E. Abashar,et al.  Coupling of steam and dry reforming of methane in catalytic fluidized bed membrane reactors , 2004 .

[60]  J. Thöming,et al.  Interactions between reaction kinetics in ATR-reactors and transport mechanisms in functional ceramic membranes: A simulation approach , 2008 .

[61]  W. Bujalski,et al.  Nickel–silica core@shell catalyst for methane reforming , 2013 .

[62]  Karl O. Albrecht,et al.  Highly active and stable MgAl2O4-supported Rh and Ir catalysts for methane steam reforming: A combined experimental and theoretical study , 2014 .

[63]  Shane Ward,et al.  Evaluation of energy efficiency of various biogas production and utilization pathways , 2010 .

[64]  C. Gennequin,et al.  A highly reactive and stable Ru/Co6−xMgxAl2 catalyst for hydrogen production via methane steam reforming , 2014 .

[65]  Integrating chemical kinetics with CFD modeling for autothermal reforming of biogas , 2009 .

[66]  M. Laborde,et al.  Methane steam reforming and ethanol steam reforming using a Ni(II)-Al(III) catalyst prepared from lamellar double hydroxides , 2006 .

[67]  A. Monzón,et al.  Steam-methane reforming at low temperature on nickel-based catalysts , 2014 .

[68]  V. Palma,et al.  Monolithic catalysts for methane steam reforming intensification: Experimental and numerical investigations , 2014 .

[69]  K. Jun,et al.  Highly stable Ni catalyst supported on Ce–ZrO2 for oxy-steam reforming of methane , 2001 .

[70]  Olaf Deutschmann,et al.  Steam reforming of methane, ethane, propane, butane, and natural gas over a rhodium-based catalyst , 2009 .

[71]  D. King,et al.  Structure and reactivity investigations on supported bimetallic AuNi catalysts used for hydrocarbon steam reforming , 2006 .

[72]  G. Manzolini,et al.  Methane steam reforming in a Pd–Ag membrane reformer: An experimental study on reaction pressure influence at middle temperature , 2011 .

[73]  Mohammad Reza Ghasemi,et al.  Steam reforming of methane in a tapered membrane Assisted fluidized Bed reactor: Modeling and si , 2011 .

[74]  C. Rhodes,et al.  Promotion of Fe3O4/Cr2O3 high temperature water gas shift catalyst , 2002 .

[75]  N. Itoh,et al.  Steam reforming of biogas mixtures with a palladium membrane reactor system , 2010 .

[76]  Hao Yu,et al.  Reaction/separation coupled equilibrium modeling of steam methane reforming in fluidized bed membrane reactors , 2010 .

[77]  Tao Huang,et al.  Methane reforming reaction with carbon dioxide over SBA-15 supported NiMo bimetallic catalysts , 2011 .

[78]  H. Kwak,et al.  Preparation of supported Ni catalysts on various metal oxides with core/shell structures and their tests for the steam reforming of methane , 2011 .

[79]  N. Muradov,et al.  Thermocatalytic Conversion of Landfill Gas and Biogas to Alternative Transportation Fuels , 2008 .

[80]  Said S.E.H. Elnashaie,et al.  A fluidized bed membrane reactor for the steam reforming of methane , 1991 .

[81]  E. Assaf,et al.  Production of the hydrogen by methane steam reforming over nickel catalysts prepared from hydrotalcite precursors , 2005 .

[82]  Said S.E.H. Elnashaie,et al.  Bifurcation and its implications for a novel autothermal circulating fluidized bed membrane reformer for the efficient pure hydrogen production , 2005 .

[83]  P. Cobden,et al.  Low temperature catalytic methane-steam reforming over ceria-zirconia supported rhodium , 2010 .

[84]  John R. Grace,et al.  Experimental studies of pure hydrogen production in a commercialized fluidized-bed membrane reactor with SMR and ATR catalysts , 2007 .

[85]  V. Almăşan,et al.  Supported nickel catalysts for low temperature methane steam reforming: comparison between metal additives and support modification , 2012, Reaction Kinetics, Mechanisms and Catalysis.

[86]  Ejm Emiel Hensen,et al.  Influence of particle size on the activity and stability in steam methane reforming of supported Rh nanoparticles , 2011 .

[87]  Chun-Zhu Li,et al.  Hierarchically structured NiO/CeO2 nanocatalysts templated by eggshell membranes for methane steam reforming , 2014 .

[88]  Hsiaotao Bi,et al.  Application of the Generic Fluidized-Bed Reactor Model to the Fluidized-Bed Membrane Reactor Process for Steam Methane Reforming with Oxygen Input , 2003 .

[89]  J. Kuipers,et al.  Experimental study on the effects of gas permeation through flat membranes on the hydrodynamics in membrane-assisted fluidized beds , 2011 .

[90]  Matteo Maestri,et al.  Steam and dry reforming of methane on Rh : Microkinetic analysis and hierarchy of kinetic models , 2008 .

[91]  N. Pradhan,et al.  Production of hydrogen by steam reforming of ethanol over alumina supported nano-NiO/SiO2 catalyst , 2013 .

[92]  Suthida Authayanun,et al.  Enhancement of Hydrogen Production for Steam Reforming of Biogas in Fluidized Bed Membrane Reactor , 2014 .

[93]  H. Alves,et al.  Overview of hydrogen production technologies from biogas and the applications in fuel cells , 2013 .

[94]  Kang Li,et al.  Catalytic hollow fibre membrane micro-reactor: High purity H2 production by WGS reaction , 2011 .

[95]  Marcello De Falco,et al.  Membrane Reactors for Hydrogen Production Processes , 2011 .

[96]  M. Balat,et al.  Political, economic and environmental impacts of biomass-based hydrogen , 2009 .

[97]  Tong Zhang,et al.  New synthesis strategies for Ni/Al2O3-Sil-1 core-shell catalysts for steam reforming of methane , 2014 .

[98]  Shigeyuki Uemiya,et al.  Steam reforming of methane in membrane reactors: comparison of electroless-plating and CVD membranes and catalyst packing modes , 2000 .

[99]  W. Bujalski,et al.  Characterization and activity test of commercial Ni/Al2O3, Cu/ZnO/Al2O3 and prepared Ni–Cu/Al2O3 catalysts for hydrogen production from methane and methanol fuels , 2013 .

[100]  John R. Grace,et al.  Comparison of fluidized bed flow regimes for steam methane reforming in membrane reactors: A simulation study , 2009 .

[101]  G. Froment,et al.  Methane steam reforming, methanation and water‐gas shift: I. Intrinsic kinetics , 1989 .

[102]  Johannes Schmitz,et al.  Steam reforming of natural gas with intergrated hydrogen separation for hydrogen production , 1987 .

[103]  Y. Zhan,et al.  Superior catalytic behavior of trace Pt-doped Ni/Mg(Al)O in methane reforming under daily start-up and shut-down operation , 2008 .

[104]  David T. Wickham,et al.  Catalytic steam reforming of methane using Rh supported on Sr-substituted hexaaluminate , 2009 .

[105]  J. Nørskov,et al.  First principles calculations and experimental insight into methane steam reforming over transition metal catalysts , 2008 .

[106]  E. Assaf,et al.  Ni catalysts with Mo promoter for methane steam reforming , 2009 .

[107]  Xiaolai Wang,et al.  Catalytic performances of NiO–CeO2 for the reforming of methane with CO2 and O2 , 2006 .

[108]  X. Verykios,et al.  Kinetic study of the catalytic reforming of methane with carbon dioxide to synthesis gas over Ni/La2O3 catalyst , 2001 .

[109]  N. Muradov,et al.  From hydrocarbon to hydrogen–carbon to hydrogen economy , 2005 .

[110]  M. Centeno,et al.  Supported nickel catalysts with a controlled molecular architecture for the catalytic reformation of methane , 2010 .

[111]  Mayuresh V. Kothare,et al.  Towards a palladium micro-membrane for the water gas shift reaction: microfabrication approach and hydrogen purification results , 2003 .

[112]  Takuma Mori,et al.  Autothermal reforming of biogas over a monolithic catalyst , 2010 .

[113]  Shigetaka Wada,et al.  Effect of CaO–ZrO2 addition to Ni supported on γ-Al2O3 by sequential impregnation in steam methane reforming , 2010 .

[114]  Yu-Ming Lin,et al.  Effect of incipient removal of hydrogen through palladium membrane on the conversion of methane steam reforming: Experimental and modeling , 2003 .

[115]  Iduvirges Lourdes Muller,et al.  Performance of a PEMFC system integrated with a biogas chemical looping reforming processor: A theoretical analysis and comparison with other fuel processors (steam reforming, partial oxidation and auto-thermal reforming) , 2012 .

[116]  Bernard P. A. Grandjean,et al.  Methane steam reforming in asymmetric Pd- and Pd-Ag/porous SS membrane reactors , 1994 .

[117]  José Mansur Assaf,et al.  Reforming of a model biogas on Ni and Rh–Ni catalysts: Effect of adding La , 2012 .

[118]  E. Iglesia,et al.  Isotopic and kinetic assessment of the mechanism of reactions of CH4 with CO2 or H2O to form synthesis gas and carbon on nickel catalysts , 2004 .

[119]  Said S.E.H. Elnashaie,et al.  Novel circulating fast fluidized-bed membrane reformer for efficient production of hydrogen from steam reforming of methane , 2003 .

[120]  A. Salladini,et al.  Experimental tests on steam reforming of natural gas in a reformer and membrane modules (RMM) plant , 2011 .

[121]  Simira Papadopoulou,et al.  Enhancement of pure hydrogen production through the use of a membrane reactor , 2014 .

[122]  Xinli Zhu,et al.  Carbon formation and steam reforming of methane on silica supported nickel catalysts , 2012 .

[123]  José Luz Silveira,et al.  Hydrogen production by biogas steam reforming: A technical, economic and ecological analysis , 2013 .

[124]  D. Simakov,et al.  Model‐based optimization of hydrogen generation by methane steam reforming in autothermal packed‐bed membrane reformer , 2011 .

[125]  Kang Li,et al.  Novel catalytic membrane micro-reactors for CO2 capture via pre-combustion decarbonization route , 2012 .

[126]  M. Temkin The Kinetics of Some Industrial Heterogeneous Catalytic Reactions , 1980 .

[127]  Adélio Mendes,et al.  The water‐gas shift reaction: from conventional catalytic systems to Pd‐based membrane reactors—a review , 2010 .

[128]  Aydin K. Sunol,et al.  Modeling and simulation of methane steam reforming in a thermally coupled membrane reactor , 2007 .

[129]  Michael Patrascu,et al.  Design concepts of a scaled-down autothermal membrane reformer for on board hydrogen production , 2015 .

[130]  John R. Grace,et al.  The fluidized-bed membrane reactor for steam methane reforming: model verification and parametric study , 1997 .

[131]  Miroslaw L. Wyszynski,et al.  Biogas upgrade to syn-gas (H 2CO) via dry and oxidative reforming , 2011 .

[132]  Suttichai Assabumrungrat,et al.  Methane steam reforming over Ni/Ce-ZrO2 catalyst : Influences of Ce-ZrO2 support on reactivity, resistance toward carbon formation, and intrinsic reaction kinetics , 2005 .

[133]  Takafumi Yoshida,et al.  Optimising H2 production from model biogas via combined steam reforming and CO shift reactions , 2005 .

[134]  Enrico Drioli,et al.  Medium/high temperature water gas shift reaction in a Pd–Ag membrane reactor: an experimental investigation , 2012 .

[135]  M. Sheintuch,et al.  On-site pure hydrogen production by methane steam reforming in high flux membrane reactor: Experimental validation, model predictions and membrane inhibition , 2015 .

[136]  Kang Li,et al.  A novel catalytic membrane microreactor for COx free H2 production , 2010 .

[137]  A. Basile,et al.  Model biogas steam reforming in a thin Pd-supported membrane reactor to generate clean hydrogen for fuel cells , 2015 .

[138]  Antonio Galvagno,et al.  Biogas as hydrogen source for fuel cell applications , 2013 .

[139]  Shigeyuki Uemiya,et al.  Separation of hydrogen through palladium thin film supported on a porous glass tube , 1991 .

[140]  S. Oyama,et al.  The boundary between simple and complex descriptions of membrane reactors: The transition between 1-D and 2-D analysis , 2009 .

[141]  Pablo Marín,et al.  Modelling of hydrogen perm-selective membrane reactors for catalytic methane steam reforming , 2012 .

[142]  S. Ivanova,et al.  Effect of gold on a NiLaO3 perovskite catalyst for methane steam reforming , 2014 .

[143]  De Chen,et al.  Effect of supports and Ni crystal size on carbon formation and sintering during steam methane reforming , 2006 .

[144]  K. Alhumaizi,et al.  Modeling of a Fluidized Bed Membrane Reactor for the Steam Reforming of Methane: Advantages of Oxygen Addition for Favorable Hydrogen Production , 2005 .

[145]  R. J. Smith,et al.  CFD analysis of water gas shift membrane reactor , 2011 .

[146]  M. Ertan Taskin,et al.  3D CFD simulations of steam reforming with resolved intraparticle reaction and gradients , 2007 .

[147]  Mark Saeys,et al.  Effect of boron on the stability of Ni catalysts during steam methane reforming , 2009 .

[148]  John R. Grace,et al.  In-situ CO2 capture in a pilot-scale fluidized-bed membrane reformer for ultra-pure hydrogen production , 2011 .