The conversion of anaerobic digestion waste into biofuels via a novel Thermo-Catalytic Reforming process.

Producing energy from biomass and other organic waste residues is essential for sustainable development. Fraunhofer UMSICHT has developed a novel reactor which introduces the Thermo-Catalytic Reforming (TCR®) process. The TCR® is a process which can convert any type of biomass and organic feedstocks into a variety of energy products (char, bio-oil and permanent gases). The aim of this work was to demonstrate this technology using digestate as the feedstock and to quantify the results from the post reforming step. The temperature of a post reformer was varied to achieve optimised fuel products. The hydrogen rich permanent gases produced were maximised at a post reforming temperature of 1023 K. The highly de-oxygenated liquid bio-oil produced contained a calorific value of 35.2 MJ/kg, with significantly improved fuel physical properties, low viscosity and acid number. Overall digestate showed a high potential as feedstock in the Thermo-Catalytic Reforming to produce pyrolysis fuel products of superior quality.

[1]  C. Paquot 2.605 – Determination of Ash Content , 1979 .

[2]  Jinsong Zhou,et al.  Research on biomass fast pyrolysis for liquid fuel , 2004 .

[3]  Andreas Hornung,et al.  Steam gasification of rapeseed, wood, sewage sludge and miscanthus biochars for the production of a hydrogen-rich syngas , 2014 .

[4]  S. Channiwala,et al.  A UNIFIED CORRELATION FOR ESTIMATING HHV OF SOLID, LIQUID AND GASEOUS FUELS , 2002 .

[5]  P. Vale,et al.  Characteristics of the upper phase of bio-oil obtained from co-pyrolysis of sewage sludge with wood, rapeseed and straw , 2012 .

[6]  J. Solar,et al.  Avoiding tar formation in biocoke production from waste biomass , 2015 .

[7]  J. Solar,et al.  Upgrading of pyrolysis vapours from biomass carbonization , 2013 .

[8]  E. Schwab,et al.  Bundesforschungsanstalt für Forst- und Holzwirtschaft, Hamburg , 2007, Holz als Roh- und Werkstoff.

[9]  Shaomin Liu,et al.  Hydrogen production via catalytic pyrolysis of biomass in a two-stage fixed bed reactor system , 2014 .

[10]  Anthony V. Bridgwater,et al.  A comparative study of straw, perennial grasses and hardwoods in terms of fast pyrolysis products , 2013 .

[11]  S. Nielsen Determination of Moisture Content , 2010 .

[12]  J. Brammer,et al.  The intermediate pyrolysis and catalytic steam reforming of brewers spent grain , 2013 .

[13]  K. Sumathy,et al.  AN OVERVIEW OF HYDROGEN PRODUCTION FROM BIOMASS , 2006 .

[14]  A. Morán,et al.  An evaluation of stability by thermogravimetric analysis of digestate obtained from different biowastes. , 2007, Journal of hazardous materials.

[15]  Yang Yang,et al.  The intermediate pyrolysis of de-inking sludge to produce a sustainable liquid fuel , 2013 .

[16]  Yang Yang,et al.  Experimental investigation of performance, emission and combustion characteristics of an indirect injection multi-cylinder CI engine fuelled by blends of de-inking sludge pyrolysis oil with biodiesel , 2013 .

[17]  Andreas Apfelbacher,et al.  Intermediate pyrolysis: A sustainable biomass-to-energy concept - Biothermal valorisation of biomass (BtVB) process , 2011 .

[18]  Douglas C. Elliott,et al.  Catalytic hydroprocessing of biomass fast pyrolysis bio‐oil to produce hydrocarbon products , 2009 .

[19]  M. Balat,et al.  Hydrogen-Rich Gas Production from Biomass via Pyrolysis and Gasification Processes and Effects of Catalyst on Hydrogen Yield , 2008 .

[20]  Milan Martinov,et al.  Applicability of biogas digestate as solid fuel , 2010 .

[21]  T. Hamieh,et al.  Accelerated decantation of biodiesel–glycerol mixtures: Optimization of a critical stage in biodiesel biorefinery , 2014 .

[22]  Andreas Apfelbacher,et al.  Production and characterization of a new quality pyrolysis oil, char and syngas from digestate – Introducing the thermo-catalytic reforming process , 2015 .

[23]  Z. Qi,et al.  Review of biomass pyrolysis oil properties and upgrading research , 2007 .

[24]  Meisam Tabatabaei,et al.  Acceleration of biodiesel-glycerol decantation through NaCl-assisted gravitational settling: a strategy to economize biodiesel production. , 2013, Bioresource technology.

[25]  A. Demirbas,et al.  Yields of hydrogen-rich gaseous products via pyrolysis from selected biomass samples , 2001 .

[26]  L. Berliner,et al.  EPR: Instrumental Methods , 2004, Biological Magnetic Resonance.