A Polythiophene Derivative with Superior Properties for Practical Application in Polymer Solar Cells

A polythiophene derivative called PDCBT, which has a backbone of thiophene units and just carboxylate functional groups to modulate its properties, exhibits properties superior to those of poly(3-hexylthiophene), the classic polythiophene derivative, when used as an electron donor in polymer solar cells (PSCs). The best device, based on PDCBT/PC71BM (1:1), develops a good power conversion efficiency of 7.2%.

[1]  John R. Tumbleston,et al.  Understanding the Morphology of PTB7:PCBM Blends in Organic Photovoltaics , 2014 .

[2]  Wei Ma,et al.  An Easy and Effective Method to Modulate Molecular Energy Level of the Polymer Based on Benzodithiophene for the Application in Polymer Solar Cells , 2014, Advanced materials.

[3]  Jianhui Hou,et al.  Synergistic Effect of Fluorination on Molecular Energy Level Modulation in Highly Efficient Photovoltaic Polymers , 2014, Advanced materials.

[4]  B. Rand,et al.  Isostructural, Deeper Highest Occupied Molecular Orbital Analogues of Poly(3-hexylthiophene) for High-Open Circuit Voltage Organic Solar Cells , 2013 .

[5]  Jianhui Hou,et al.  Efficient Polymer Solar Cells Based on Benzothiadiazole and Alkylphenyl Substituted Benzodithiophene with a Power Conversion Efficiency over 8% , 2013, Advanced materials.

[6]  M. Wienk,et al.  High-molecular-weight regular alternating diketopyrrolopyrrole-based terpolymers for efficient organic solar cells. , 2013, Angewandte Chemie.

[7]  John R. Tumbleston,et al.  Domain Purity, Miscibility, and Molecular Orientation at Donor/Acceptor Interfaces in High Performance Organic Solar Cells: Paths to Further Improvement , 2013 .

[8]  G. Wantz,et al.  Controlling the morphology and performance of bulk heterojunctions in solar cells. Lessons learned from the benchmark poly(3-hexylthiophene):[6,6]-phenyl-C61-butyric acid methyl ester system. , 2013, Chemical reviews.

[9]  Yongfang Li,et al.  Influence of D/A Ratio on Photovoltaic Performance of a Highly Efficient Polymer Solar Cell System , 2012, Advanced materials.

[10]  A. Jen,et al.  Improved Charge Transport and Absorption Coefficient in Indacenodithieno[3,2‐b]thiophene‐based Ladder‐Type Polymer Leading to Highly Efficient Polymer Solar Cells , 2012, Advanced materials.

[11]  Yongfang Li,et al.  Effect of Branched Side Chains on the Physicochemical and Photovoltaic Properties of Poly(3‐hexylthiophene) Isomers , 2012 .

[12]  M. Ratner,et al.  Bithiopheneimide-dithienosilole/dithienogermole copolymers for efficient solar cells: information from structure-property-device performance correlations and comparison to thieno[3,4-c]pyrrole-4,6-dione analogues. , 2012, Journal of the American Chemical Society.

[13]  Klaus Müllen,et al.  Design strategies for organic semiconductors beyond the molecular formula. , 2012, Nature chemistry.

[14]  Yongfang Li,et al.  Poly(thieno[3,2-b]thiophene-alt-bithiazole): A D–A Copolymer Donor Showing Improved Photovoltaic Performance with Indene-C60 Bisadduct Acceptor , 2012 .

[15]  F. Liu,et al.  Efficient Polymer Solar Cells Based on a Low Bandgap Semi‐crystalline DPP Polymer‐PCBM Blends , 2012, Advanced materials.

[16]  D. Seferos,et al.  Donor–Donor Block Copolymers for Ternary Organic Solar Cells , 2012 .

[17]  Bumjoon J. Kim,et al.  The effect of side-chain length on regioregular poly[3-(4-n-alkyl)phenylthiophene]/PCBM and ICBA polymer solar cells , 2012 .

[18]  Yongfang Li,et al.  High efficiency polymer solar cells based on poly(3-hexylthiophene)/indene-C70 bisadduct with solvent additive , 2012 .

[19]  T. P. Russell,et al.  Multi‐Length‐Scale Morphologies in PCPDTBT/PCBM Bulk‐Heterojunction Solar Cells , 2012 .

[20]  A. Facchetti,et al.  Bithiophene Imide and Benzodithiophene Copolymers for Efficient Inverted Polymer Solar Cells , 2012, Advanced materials.

[21]  A. Hexemer,et al.  Soft x-ray scattering facility at the Advanced Light Source with real-time data processing and analysis. , 2012, The Review of scientific instruments.

[22]  Yu‐Cheng Chiu,et al.  Biaxially Extended Quaterthiophene– and Octithiophene–Vinylene Conjugated Polymers for High Performance Field Effect Transistors and Photovoltaic Cells , 2012 .

[23]  Alberto Salleo,et al.  Controlled conjugated backbone twisting for an increased open-circuit voltage while having a high short-circuit current in poly(hexylthiophene) derivatives. , 2012, Journal of the American Chemical Society.

[24]  Yongfang Li,et al.  Side Chain Engineering of Polythiophene Derivatives with a Thienylene–Vinylene Conjugated Side Chain for Application in Polymer Solar Cells , 2012 .

[25]  Yongfang Li Molecular design of photovoltaic materials for polymer solar cells: toward suitable electronic energy levels and broad absorption. , 2012, Accounts of chemical research.

[26]  C. B. Nielsen,et al.  Design of semiconducting indacenodithiophene polymers for high performance transistors and solar cells. , 2012, Accounts of chemical research.

[27]  B. Collins,et al.  Fullerene-Dependent Miscibility in the Silole-Containing Copolymer PSBTBT-08 , 2011 .

[28]  J. Fréchet,et al.  Molecular design and ordering effects in π-functional materials for transistor and solar cell applications. , 2011, Journal of the American Chemical Society.

[29]  Yongfang Li,et al.  Downwards tuning the HOMO level of polythiophene by carboxylate substitution for high open-circuit-voltage polymer solar cells , 2011 .

[30]  Feng Xu,et al.  Replacing alkoxy groups with alkylthienyl groups: a feasible approach to improve the properties of photovoltaic polymers. , 2011, Angewandte Chemie.

[31]  Stelios A. Choulis,et al.  How the structural deviations on the backbone of conjugated polymers influence their optoelectronic properties and photovoltaic performance , 2011 .

[32]  Wei Chen,et al.  Hierarchical nanomorphologies promote exciton dissociation in polymer/fullerene bulk heterojunction solar cells. , 2011, Nano letters.

[33]  Wei Zhao,et al.  Defining the nanostructured morphology of triblock copolymers using resonant soft X-ray scattering. , 2011, Nano letters.

[34]  Mario Leclerc,et al.  Processable Low-Bandgap Polymers for Photovoltaic Applications† , 2011 .

[35]  Yongfang Li,et al.  6.5% Efficiency of Polymer Solar Cells Based on poly(3‐hexylthiophene) and Indene‐C60 Bisadduct by Device Optimization , 2010, Advanced materials.

[36]  Howard A. Padmore,et al.  A SAXS/WAXS/GISAXS Beamline with Multilayer Monochromator , 2010 .

[37]  J. Lüning,et al.  Nanomorphology of bulk heterojunction photovoltaic thin films probed with resonant soft X-ray scattering. , 2010, Nano letters.

[38]  Gang Li,et al.  For the Bright Future—Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4% , 2010, Advanced materials.

[39]  Jin Kon Kim,et al.  High‐Efficiency Organic Solar Cells Based on End‐Functional‐Group‐Modified Poly(3‐hexylthiophene) , 2010, Advanced materials.

[40]  S. Jenekhe,et al.  Enhanced Performance of Bulk Heterojunction Solar Cells Using Block Copoly(3-alkylthiophene)s , 2010 .

[41]  Yongfang Li,et al.  Indene-C(60) bisadduct: a new acceptor for high-performance polymer solar cells. , 2010, Journal of the American Chemical Society.

[42]  Srinivas Sista,et al.  An Easy and Effective Method To Modulate Molecular Energy Level of Poly(3-alkylthiophene) for High-Voc Polymer Solar Cells , 2009 .

[43]  S. Jenekhe,et al.  Regioregular Poly(3-pentylthiophene): Synthesis, Self-Assembly of Nanowires, High-Mobility Field-Effect Transistors, and Efficient Photovoltaic Cells , 2009 .

[44]  Chain‐Shu Hsu,et al.  Synthesis of conjugated polymers for organic solar cell applications. , 2009, Chemical reviews.

[45]  Yong Cao,et al.  Development of novel conjugated donor polymers for high-efficiency bulk-heterojunction photovoltaic devices. , 2009, Accounts of chemical research.

[46]  K. Wei,et al.  Intramolecular Donor–Acceptor Regioregular Poly(hexylphenanthrenyl‐imidazole thiophene) Exhibits Enhanced Hole Mobility for Heterojunction Solar Cell Applications , 2009 .

[47]  K. Müllen,et al.  Tailoring structure-property relationships in dithienosilole-benzothiadiazole donor-acceptor copolymers. , 2009, Journal of the American Chemical Society.

[48]  Nelson E. Coates,et al.  Bulk heterojunction solar cells with internal quantum efficiency approaching 100 , 2009 .

[49]  C. Ting,et al.  Two-dimensional regioregular polythiophenes with conjugated side chains for use in organic solar cells , 2009 .

[50]  Shijun Jia,et al.  Polymer–Fullerene Bulk‐Heterojunction Solar Cells , 2009, Advanced materials.

[51]  Kazuhito Hashimoto,et al.  Morphological Stabilization of Polymer Photovoltaic Cells by Using Cross-Linkable Poly(3-(5-hexenyl)thiophene) , 2009 .

[52]  S. Jenekhe,et al.  Bulk Heterojunction Solar Cells from Poly(3-butylthiophene)/Fullerene Blends: In Situ Self-Assembly of Nanowires, Morphology, Charge Transport, and Photovoltaic Properties , 2008 .

[53]  Samson A Jenekhe,et al.  Highly efficient solar cells based on poly(3-butylthiophene) nanowires. , 2008, Journal of the American Chemical Society.

[54]  N. S. Sariciftci,et al.  Conjugated polymer-based organic solar cells. , 2007, Chemical reviews.

[55]  Zhan'ao Tan,et al.  Synthesis, Hole Mobility, and Photovoltaic Properties of Cross-Linked Polythiophenes with Vinylene-Terthiophene-Vinylene as Conjugated Bridge , 2007 .

[56]  J. Fréchet,et al.  Enhancing the thermal stability of polythiophene:fullerene solar cells by decreasing effective polymer regioregularity. , 2006, Journal of the American Chemical Society.

[57]  Zhan'ao Tan,et al.  Synthesis and photovoltaic properties of two-dimensional conjugated polythiophenes with bi(thienylenevinylene) side chains. , 2006, Journal of the American Chemical Society.

[58]  Donal D. C. Bradley,et al.  A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells , 2006 .

[59]  Yang Yang,et al.  High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends , 2005 .

[60]  Xiong Gong,et al.  Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology , 2005 .

[61]  Yongfang Li,et al.  Synthesis and electroluminescence of novel copolymers containing crown ether spacers , 2003 .

[62]  Yong Cao,et al.  Electrochemical properties of luminescent polymers and polymer light-emitting electrochemical cells , 1999 .

[63]  J. Fréchet,et al.  Polymer-fullerene composite solar cells. , 2008, Angewandte Chemie.