3-Chloro-N-(3-methylphenyl)benzamide

In the molecular structure of the title compound, C14H12ClNO, the meta-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N—H bond. The two aromatic rings make a dihedral angle of 77.4 (1)°. In the crystal, the molecules are linked by N—H⋯O hydrogen bonds, forming C(4) chains propagating in [010].

[1]  J. S. Reid,et al.  The Analytical Calculation of Absorption in Multifaceted Crystals , 1995 .

[2]  B. Thimme Gowda,et al.  N‐(4‐Nitrophenyl)methanesulfonamide , 2007 .

[3]  Erdal Bedir,et al.  Two New Iridoid Glucosides from Verbascum salviifolium Boiss. , 2005 .

[4]  B. Thimme Gowda,et al.  3-Chloro-N-(3-chlorophenyl)benzamide , 2008, Acta crystallographica. Section E, Structure reports online.

[5]  良二 上田.  J. Appl. Cryst.の発刊に際して , 1970 .

[6]  G. Sheldrick.  A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[7]  Christopher Glidewell,et al.  A triclinic polymorph of benzanilide: disordered molecules form hydrogen-bonded chains. , 2003, Acta crystallographica. Section C, Crystal structure communications.

[8]  Jim Simpson,et al.  A monoclinic polymorph of N-(3-chlorophenyl)benzamide , 2010, Acta crystallographica. Section E, Structure reports online.

[9]  Owen Johnson,et al.  CIF applications. XV. enCIFer: a program for viewing, editing and visualizing CIFs , 2004 .