Sputtered–Anodized $\hbox{Ta}_{2}\hbox{O}_{5}$ as the Dielectric Layer for Electrowetting-on-Dielectric

Evaluating the anodized tantalum pentoxide (Ta<sub>2</sub>O<sub>5</sub>) that has been recently reported as a dielectric for low-voltage electrowetting-on-dielectric (EWOD) devices, we find a severe deterioration in performance if the working liquid is actuated with positive dc voltage. In an effort to reduce the limitation of this otherwise attractive dielectric material for EWOD, proposed herein is a Ta<sub>2</sub>O<sub>5</sub> layer prepared by anodizing a sputtered Ta<sub>2</sub>O<sub>5</sub> film. This sputtered-anodized Ta<sub>2</sub>O<sub>5</sub> allows the use of positive dc signals, while maintaining the low-voltage actuation for which the anodized Ta<sub>2</sub>O<sub>5</sub> was originally introduced. All the EWOD tests were performed with a conductive liquid droplet in an air environment.

[1]  Manjeet Dhindsa,et al.  Electrowetting without electrolysis on self-healing dielectrics. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[2]  Jason Heikenfeld,et al.  Reliable and Low-Voltage Electrowetting on Thin Parylene Films , 2011 .

[3]  Hong Liu,et al.  Dielectric materials for electrowetting-on-dielectric actuation , 2009 .

[4]  Y. Tzeng,et al.  Improved Oxide Properties by Anodization of Aluminum Films with Thin Sputtered Aluminum Oxide Overlays , 1988 .

[5]  H. Groult,et al.  Dielectric properties of anodic oxide films on tantalum , 1995 .

[6]  K. Sundaram,et al.  Wet etching of sputtered tantalum thin films in NaOH and KOH based solutions , 2007 .

[7]  Manjeet Dhindsa,et al.  Ion and liquid dependent dielectric failure in electrowetting systems. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[8]  L. Young Anodization Constants for Tantalum , 1977 .

[9]  S. Cho,et al.  Low voltage electrowetting-on-dielectric , 2002 .

[10]  Y. Tzeng,et al.  Charge trapping/generation and reliability for high‐performance tantalum oxide capacitors , 1989 .

[11]  W. Badawy,et al.  Stability of anodic tantalum oxide films in NaOH solutions , 1989 .

[12]  Bonhye Koo,et al.  Evaluation of anodic TA2O5 as the dielectric layer for EWOD devices , 2012, 2012 IEEE 25th International Conference on Micro Electro Mechanical Systems (MEMS).

[13]  J. Stevenson,et al.  Room-Temperature Fabrication of Anodic Tantalum Pentoxide for Low-Voltage Electrowetting on Dielectric (EWOD) , 2008, Journal of Microelectromechanical Systems.

[14]  D. Muth Ellipsometer Study of Anodic Oxides Formed on Sputtered Tantalum and Tantalum–Aluminum Alloy Films , 1969 .

[15]  R. Fair,et al.  Low Voltage Electrowetting-on-Dielectric Platform using Multi-Layer Insulators. , 2010, Sensors and actuators. B, Chemical.