Investigation of oil and emulsion stability of locally prepared metalworking fluids

Purpose – No one particular fluid has cooling and lubrication properties suitable for every metalworking application. The purpose of this paper is first, to investigate the effect of anionic and nonionic mixed emulsifier system in stabilization of cutting fluid formulations and second, to study the interaction synergism of the fulfill additives of metalworking fluids to achieve low scar diameters, high stability, anti rusting and corrosion properties.Design/methodology/approach – A lot of set mixtures in this work were formulated to get the demand needed for soluble oil metalworking fluids. It was based on a blend of emulsifier package (anionic‐non ionic), and in order to reach acceptable manufacturing conditions, coupling agent, stabilizer, biocide, base oil and anti‐rust additives were added to the formulation. Different percentages of these components were incorporated to optimize the stability of the emulsifier system. Standard tests were carried out to evaluate the performance of oil‐in‐water (O/W) e...

[1]  Z. Derriche,et al.  Simultaneous elimination of dissolved and dispersed pollutants from cutting oil wastes using two aqueous phase extraction methods. , 2009, Journal of hazardous materials.

[2]  M. Sakamoto,et al.  Characteristic properties of cutting fluid additives made from the derivatives of some polymeric nonionic surface-active agents , 1998 .

[3]  T. Yamane,et al.  High-yield enzymatic glycerolysis of fats and oils , 1991 .

[4]  M. A. El Baradie,et al.  Cutting fluids: Part I. Characterisation , 1996 .

[5]  M. A. El Baradie,et al.  Cutting fluids: Part II. Recycling and clean machining , 1996 .

[7]  Ch. Srinivasa Rao,et al.  Influence of emulsifier content on properties and durability of cutting fluids , 2007 .

[8]  A. Al-sabagh,et al.  Surface activity and light scattering investigation for some novel aromatic polyester amine surfactants , 2004 .

[9]  W. A. Taber,et al.  Reassessment of fungal dry weight as a measure of carbon source utilization by Pisolithus tinctorius , 1988 .

[10]  A. Omar.  Micellization and adsorption of anionic/nonionic polymeric surfactants for metal work fluid at different interfaces , 2004 .

[11]  Ahmed M. Al-Sabagh,et al.  Effect of Binary Surfactant Mixtures on the Stability of Asphalt Emulsions , 1997 .

[12]  Ken Sutherland.  Machinery and processing: Managing cutting fluids used in metal working , 2008 .

[13]  Junyan Liu,et al.  Research on experiments and action mechanism with water vapor as coolant and lubricant in Green cutting , 2005 .

[14]  Mirko Soković,et al.  Ecological aspects of the cutting fluids and its influence on quantifiable parameters of the cutting processes , 2001 .

[15]  C. Bregni,et al.  Some considerations about the hydrophilic-lipophilic balance system. , 2008, International journal of pharmaceutics.

[16]  P. Luckham,et al.  Stabilisation of emulsions by using a combination of an oil soluble ionic surfactant and water soluble polyelectrolytes. I: Emulsion stabilisation and Interfacial tension measurements , 2009 .

[17]  H. Bataller,et al.  Cutting fluid emulsions produced by dilution of a cutting fluid concentrate containing a cationic/nonionic surfactant mixture , 2004 .

[18]  P. Bruheim,et al.  Effects of Surfactant Mixtures, Including Corexit 9527, on Bacterial Oxidation of Acetate and Alkanes in Crude Oil , 1999, Applied and Environmental Microbiology.

[19]  I. Norton,et al.  Mixed-emulsifier stabilised emulsions: Investigation of the effect of monoolein and hydrophilic silica particle mixtures on the stability against coalescence. , 2009, Journal of colloid and interface science.

[20]  Steven J Skerlos,et al.  Structural aspects of surfactant selection for the design of vegetable oil semi-synthetic metalworking fluids. , 2006, Environmental science & technology.

[21]  G. Jiang,et al.  Effect of cationic and anionic surfactants on the sorption and desorption of perfluorooctane sulfonate (PFOS) on natural sediments. , 2009, Environmental pollution.

[22]  Peter C. Raynor,et al.  Emulsions containing vegetable oils for cutting fluid application , 2004 .

[23]  Ángel Cambiella,et al.  Interfacial properties of oil-in-water emulsions designed to be used as metalworking fluids , 2007 .

[24]  Yanli Sun,et al.  Effects of mixed surfactants on the volatilization of naphthalene from aqueous solutions. , 2007, Journal of hazardous materials.

[25]  Y. Sugimoto,et al.  Characteristic properties of cutting fluid additives derived from the reaction products of hydroxyl fatty acids with some acid anhydrides , 1998 .

[26]  M. J. Rosen.  Surfactants and Interfacial Phenomena , 1978 .

[27]  B. Kovacevich,et al.  Sequence and molecular characterization of a DNA region encoding the dibenzothiophene desulfurization operon of Rhodococcus sp. strain IGTS8 , 1995, Applied and environmental microbiology.

[28]  M. Blaszkewicz,et al.  Assessing the genotoxicity of industrial cutting fluids under conditions of use. , 2004, Toxicology letters.

[29]  N. M. Nasser,et al.  Investigation Factors Affecting Cutting Oil Formulations Prepared by Emulsifiers Based on Linear Alkyl Benzene and Oleic Acid‐Maleic Anhydride Esters , 2008 .

[30]  Steven J Skerlos,et al.  Design of hard water stable emulsifier systems for petroleum- and bio-based semi-synthetic metalworking fluids. , 2003, Environmental science & technology.

[31]  Ángel Cambiella,et al.  Formulation of emulsifiable cutting fluids and extreme pressure behaviour , 2007 .

[32]  T. Dąbroś,et al.  Breaking Water-in-Bitumen Emulsions using Polyoxyalkylated DETA Demulsifier , 2008 .

[33]  T. Fujita,et al.  Characteristic properties of cutting fluid additives derived from the adducts of diamines and acid chlorides , 1993 .

[34]  P. M. Krugli︠a︡kov.  Hydrophile-Lipophile Balance of Surfactants and Solid Particles: Physicochemical Aspects and Applications , 2000 .