Dielectric behavior of three-phase percolative Ni–BaTiO3/polyvinylidene fluoride composites

A three-phase percolative composite with a ferroelectric phase (BaTiO3) and metallic inclusions (Ni) embedded into polyvinylidene fluoride matrix was prepared by using a simple blending and hot-molding technique. Effective medium approximations and percolation theory were employed in order to design and describe the dielectric behavior of such three-phase composites. Our experimental results showed that the static dielectric constant of such a three-phase composite can reach above 800 when the Ni concentration is close to its percolation threshold. Such composites have a potential to become capacitors and can be easily fabricated into various shapes due to its flexibility.

[1]  C. Choy,et al.  Pyroelectric and piezoelectric properties of lead titanate/polyvinylidene fluoride-trifluoroethylene 0-3 composites , 1998 .

[2]  C. Nan Physics of inhomogeneous inorganic materials , 1993 .

[3]  R. Gregorio,et al.  Dielectric behaviour of thin films of β-PVDF/PZT and β-PVDF/BaTiO3 composites , 1996, Journal of Materials Science.

[4]  D. K. Das-Gupta,et al.  Inorganic ceramic/polymer ferroelectric composite electrets , 1996 .

[5]  Haisheng Xu,et al.  High-dielectric-constant ceramic-powder polymer composites , 2000 .

[6]  J. Moya,et al.  Experimental evidence of a giant capacitance in insulator-conductor composites at the percolation threshold , 2000 .

[7]  D. A. G. Bruggeman Berechnung verschiedener physikalischer Konstanten von heterogenen Substanzen. I. Dielektrizitätskonstanten und Leitfähigkeiten der Mischkörper aus isotropen Substanzen , 1935 .

[8]  C. Nan Comment on “Effective dielectric function of a random medium” , 2001 .

[9]  Junjie Wu,et al.  Percolation exponents and thresholds obtained from the nearly ideal continuum percolation system graphite-boron nitride , 1997 .

[10]  Fátima Esteban-Betegón,et al.  New Percolative BaTiO3–Ni Composites with a High and Frequency-Independent Dielectric Constant (εr ≈ 80000) , 2001 .

[11]  D. Kuo,et al.  Dielectric behaviours of multi-doped BaTiO3/epoxy composites , 2001 .

[12]  C. Brosseau Generalized effective medium theory and dielectric relaxation in particle-filled polymeric resins , 2002 .