The Chemistry of 1,4,7‐Triazacyclononane and Related Tridentate Macrocyclic Compounds

[1]  D. Busch,et al.  Geometric and optical isomers of cobalt(III) complexes containing two moles of the cyclic tridentate ligand derived from o-aminobenzaldehyde , 1970 .

[2]  M. Nonoyama.  [(R)-2-Methyl-1,4,7-triazacyclononane] [1,1,1-tris(aminomethyl)ethane]-cobalt(III) and some Mono[(R)-2-methyl-1,4,7-triazacyclononane]-cobalt(III) Complexes , 1980 .

[3]  E. J. Billo.  Aqueous solution equilibria of five-coordinate complexes of 1,5-diazacyclooctane-N,N′diacetic acid , 1975 .

[4]  C. G. Young,et al.  Preparation and characterization of binuclear complexes of molybdenum(III) and molybdenum(V) via oxidative decarbonylation. Reactions of LMo(CO)3 (L = 1,5,9-triazacyclododecane) and crystal structure of anti-[L2Mo2O4](ClO4)2.2H2O , 1985 .

[5]  P. West,et al.  Kinetics and mechanism of the oxidation of benzenediols and ascorbic acid by bis(1,4,7-triazacyciononane)nickel(III) in aqueous perchlorate media , 1985 .

[6]  K. Wieghardt,et al.  Komplexe des Chroms mit 1,5,9-Triazacyclododecan: Darstellung, Magnetismus und Kristallstruktur von Tri-μ-hydroxo-bis[(1,5,9-triazacyclododecan)chrom(III)] tribromid Dihydrat; Kinetik und Mechanismus der Brückenspaltung mit Hydroxidionen , 1985 .

[7]  D. Hunkler,et al.  „cis‐Diaza‐bis‐σ‐homobenzole”︁ ([π2s + σ2s + σ2s]‐Cycloreversion) – 1,4‐Dihydro‐1,4‐diazocine („Aromatizität”︁) , 1980 .

[8]  J. Chatt,et al.  X-Ray determination of molecular structures of molybdenum(IV) oxo-complexes. The possibility of a new type of isomerism , 1971 .

[9]  S. Mason,et al.  The optical activity of cobalt(III) chelate diamine complexes , 1976 .

[10]  H. Prinzbach,et al.  “cis-Trioxa-tris-σ-homobenzol” Synthese und [σ2s + σ2s + σ2s]-Cycloreversion , 1979 .

[11]  H. Brittain,et al.  Optically Active Cis‐Unidentate‐Dicarbonato, Cis‐Cis‐Diunidentate‐Carbonato, and Unidentate Glycinato Cobalt(III) Complexes , 2007 .

[12]  K. Wieghardt,et al.  An unusual CuII-promoted desulphurisation of thiourea: synthesis and crystal structure of di-µ-hydrogencyanamido(1–)-bis[(N,N′,N″-trimethyl-1,4,7-triazacyclononane)copper(II)] di-perchlorate monohydrate , 1985 .

[13]  R. Hancock,et al.  Stability, electronic spectra, and structure of transition-metal ion complexes of a novel mixed-donor (nitrogen―sulphur) macrocycle, 1-thia-4,7-diazacyclononane , 1983 .

[14]  D. Busch,et al.  Chemical Foundations for the Understanding of Natural Macrocyclic Complexes , 1971 .

[15]  R. Hancock,et al.  Synthesis and metal complexing properties of the mixed-donor (NitrogenOxygen) macrocycle, 1-Oxa-4,7,11- triaza-cyclotridecane , 1983 .

[16]  L. Gray,et al.  Blue chloroammine complexes of ruthenium , 1972 .

[17]  K. Wieghardt,et al.  Neue μ‐Hydroxo‐Übergangsmetallkomplexe, III. Darstellung zweikerniger Komplexe des Rhodiums(III) mit einer μ‐Acetato‐ und μ‐Carbonato‐Brücke. Die Struktur des trans‐Diaqua‐di‐μ‐hydroxo‐bis[(1,4,7‐triazacyclononan)rhodium(III)]‐Kations , 1980 .

[18]  Horst Prinzbach,et al.  cis‐Triaza‐tris‐σ‐homobenzol (cis‐„Benzol‐triimin”︁) , 1973 .

[19]  W. Kläui,et al.  Die Michaelis‐Arbusov‐Reaktion als Zugang zu neuen Sauerstoff‐Tripodliganden des Typs [C5R5M{P(O)(OCH3)2}3]−. Ligandfeldspektroskopische und koordinationschemische Charakterisierung der Liganden , 1982 .

[20]  F. Einstein,et al.  A NOVEL MODE OF CARBONATE BINDING. STRUCTURE OF SPIN-PAIRED μ-CARBONATO-BIS(2,4,4,7-TETRAMETHYL-1,5,9-TRIAZACYCLODODEC-1-ENE)DICOPPER(II# ) PERCHLORATE , 1978 .

[21]  K. Wieghardt,et al.  Variable-temperature single-crystal electron spin resonance study and crystal structure of bis(1,4,7-triazacyclononane)copper(2+) tricyanocuprate(2-) dihydrate at 110 and 293 K. Static and dynamic Jahn-Teller distortions in the CuN6 polyhedron , 1986 .

[22]  J. Richman,et al.  NITROGEN ANALOGS OF CROWN ETHERS , 1974 .

[23]  A. Sherry,et al.  Nuclear magnetic resonance and potentiometric studies of the protonation scheme of a triaza triacetic macrocycle and its complexes with lanthanum and lutetium , 1985 .

[24]  A. Sargeson,et al.  MACROTRICYCLIC HEXAAMINE CAGE COMPLEXES OF COBALT(III): SYNTHESIS, CHARACTERIZATION AND PROPERTIES , 1983 .

[25]  T. Kaden,et al.  Metal Complexes with Macrocyclic Ligands, IV. Synthesis, Properties and Kinetics of Complexation with Three N‐methyl Substituted 1,4,8,11‐tetraazacyclotetradecanes , 1974 .

[26]  K. Wieghardt,et al.  Distortional Isomers of [LWOCl2]+ in the Solid State and in Solution; Crystal Structures of the Blue and Green Forms of [LWOCl2]PF6 , 1985 .

[27]  J. S. Alper,et al.  A crystal field study of a trigonally distorted complex: Bis (1,4,7-triazacyclononane) Ni(II) ion , 1980 .

[28]  T. Kaden.  Synthesis and metal complexes of aza-macrocycles with pendant arms having additional ligating groups , 1984 .

[29]  A. Sherry,et al.  Lanthanide-nota chelates as aqueous shift reagents: Interaction with cyclopropane carboxylic acid , 1985 .

[30]  K. Wieghardt,et al.  Electron-transfer barriers in cobalt(III) and cobalt(II) bis complexes of 1,4,7-triazacyclononane (tacn) and 1,4,7-trithiacyclononane (ttcn). Crystal structures of [CoII(tacn)2]I2.H2O and of [CoIII(ttcn)2](ClO4)3 , 1986 .

[31]  D. Busch,et al.  Stereospecific formation of chelate sandwich compounds derived from o-aminobenzaldehyde and 2-amino-5-chlorobenzaldehyde by a metal-ion-induced rearrangement , 1969 .

[32]  K. Wieghardt,et al.  Säure-Base-Eigenschaften des zyklischen Triamins N,N′,N″-Trimethyl-1,4,7-triazacyclononan: Die Kristallstruktur seiner monoprotonierten Form [C9H22N3]ClO4) / Acid-Base Properties of the Cyclic Triamine N,N′,N″-Trimethyl-1,4,7-triazacyclononane and Crystal Structure of its Monoprotonated Form [C9H22N , 1987 .

[33]  A. Vacca,et al.  Transition Metal Complexes of 3,3'-Diaminodipropylamine:Stability Constants , 1966 .

[34]  N. F. Curtis.  Macrocyclic coordination compounds formed by condensation of metal-amine complexes with aliphatic carbonyl compounds , 1968 .

[35]  F. Vögtle,et al.  Ligandstruktur und Komplexierung, VII. Einfache Synthese neuer Kronenätheramine , 1976 .

[36]  C. N. Reilley,et al.  Multinuclear nuclear magnetic resonance study of three aqueous lanthanide shift reagents: complexes with EDTA and axially symmetric macrocyclic polyamino polyacetate ligands , 1981 .

[37]  Edwin Weber,et al.  Host Guest Complex Chemistry / Macrocycles , 1985 .

[38]  P. R. Norman,et al.  Electron transfer reactions of nickel complexes of 1,4,7-triazacyclodecane , 1985 .

[39]  K. Wieghardt,et al.  Complexes of thallium(I) and -(III) containing 1,4,7-triazacyclononane (L) ligands. Kinetics and mechanism of the reduction of [L2TlIII]3+. Crystal structure of (N,N',N"-trimethyl-1,4,7-triazacyclononane)thallium(I) hexafluorophosphate , 1986 .

[40]  S. Fujinami,et al.  CD Spectra and Absolute Configurations of fac(a,b,c)-[Co(a)(b)(c)(1,4,7-Triazacyclononane)]n+ Complexes , 1983 .

[41]  J. Weiss,et al.  Preparation and characterization of binuclear (1,4,7-triazacyclononane)molybdenum(III) complexes. Crystal structures of [MoIII2(.mu.-OH)2Cl2(C6H15N3)2]I2 and [MoIII2(.mu.-OH)2(.mu.-O2CCH3)(C6H15N3)2]I3.H2O , 1984 .

[42]  G. Lawrance,et al.  Branched cyclononane macrocycles with pentaamine and tetraamine-thioether donors. Preparation and base hydrolysis of chlorocobalt(III) complexes , 1982 .

[43]  M. Nonoyama,et al.  Triammine(1,4,7-triazacycloalkane)cobalt(III) and [(R)-2-methyl-1,4,7-triazacyclononane] (1,4,7-triazacyclononane)cobalt(III) , 1983 .

[44]  S. Fujinami,et al.  Synthesis and Circular Dichroism Spectra of [Co(a)(gly)(1,4,7-triazacyclononane)]-type Complexes , 1980 .

[45]  K. Wieghardt,et al.  The electrochemistry of a dimeric and two monomeric cis-trioxomolybdenum(VI) complexes containing cyclic triamine ligands in protic and aprotic media: model compounds for the active site informate dehydrogenase , 1986 .

[46]  D. Busch.  Metal ion control of chemical reactions. , 1971, Science.

[47]  J. Lehn.  Cryptates: macropolycyclic inclusion complexes , 1977 .

[48]  L. J. Zompa.  Metal complexes of cyclic triamines. 2. Stability and electronic spectra of nickel(II), copper(II), and zinc(II) complexes containing nine- through twelve-membered cyclic triamine ligands , 1978 .

[49]  R. Hancock,et al.  Crystallographic and Thermodynamic Study of Metal Ion Size Selectivity in the Ligand 1,4,7-Triazacyclononane- N, N',N"-triacetate , 1985 .

[50]  Hiroyuki Koyama,et al.  Syntheses of Some Medium Sized Cyclic Triamines and Their Cobalt(III) Complexes , 1972 .

[51]  J. Lehn.  Dinuclear cryptates: dimetallic macropolycyclic inclusion complexes: concepts - design - prospects , 1980 .

[52]  Stephen J. Lippard,et al.  (.mu.-Oxo)bis(.mu.-acetato)bis(tri-1-pyrazolylborato)diiron(III), [(HBpz3)FeO(CH3CO2)2Fe(HBpz3)]: model for the binuclear iron center of hemerythrin , 1983 .

[53]  M. Nonoyama.  Five coordinate nickel(II) isothiocyanato and chloro complexes of triazacycloalkanes , 1976 .

[54]  R. M. Wing,et al.  Evidence for Piper's model of optical activity. The structure and absolute configuration of (+)5461-bis(tribenzo[b,f,j][1,5,9]triazacycloduodecine)cobalt(III) iodide , 1970 .

[55]  A. Martin,et al.  Synthesis of selectively protected tri- and hexaamine macrocycles , 1982 .

[56]  H. Schugar,et al.  Molecular structure of dichloro(1,4,7-triazacyclononane)copper(II), a macrocyclic triamine complex with an unusually small formation constant , 1980 .

[57]  R. Hancock,et al.  Synthesis and metal binding properties of the novel ligand N,N′N″-tris(2-hydroxyethyl)-1,4,7-triazacyclononane , 1983 .

[58]  K. Wieghardt,et al.  Macrocyclic complexes of lead(II): crystal structures of LPb(ClO4)2 and LPb(NO3)2 (L = 1,4,7-triazacyclononane) , 1986 .

[59]  S. Fujinami,et al.  PREPARATION OF A NOVEL AMMINEBROMOCYANO[1,4,7-TRIAZACYCLONONANE]COBALT(III) COMPLEX , 1979 .

[60]  D. Busch,et al.  Reactions of Coordinated Ligands. XI. The Formation and Properties of a Tridentate Macrocyclic Ligand Derived from o-Aminobenzaldehyde , 1965 .

[61]  K. Wieghardt,et al.  Exchange coupling in tris(.mu.-hydroxo)bis[(1,4,7-trimethyl-1,4,7-triazacyclononane)chromium(III)] triperchlorate trihydrate , 1983 .

[62]  M. Kodama,et al.  Equilibria of complex formation between several bivalent metal ions and macrocyclic tri- and penta-amines , 1978 .

[63]  P. Schaber,et al.  Preparation and crystal and molecular structure of dibromo(1,4,7-triazacyclononane)copper(II) , 1979 .

[64]  S. Larsen,et al.  Synthesis and reactivity of hydroxo-bridged binuclear ethylenediamine complexes of iridium(III) and the x-ray crystal structure of [aquabis(ethylenediamine)iridium(III)](.mu.-hydroxo)hydroxobis(ethylenediamine)iridium(III) dithionate perchlorate hydrate , 1986 .

[65]  L. Sieker,et al.  Restrained least-squares refinement of Themiste dyscritum methydroxohemerythrin at 2.0 Å resolution , 1982 .

[66]  M. Nonoyama,et al.  Cobalt(III), nickel(II), and copper(II) complexes of 1-thia (or oxa)4,7-diazacyclononane and related mixed-ligand cobalt(III) complexes , 1984 .

[67]  H. Stetter,et al.  Komplexbildung mit Tetraazacycloalkan-N,N′,N″,N‴-tetraessigsäuren in Abhängigkeit von der Ringgröße† , 1976 .

[68]  J. Bradshaw,et al.  Macrocyclic sulfide syntheses: A review , 1974 .

[69]  K. Wieghardt,et al.  Redox potentials of bis(1,4,7-triazacyclononane complexes of some first transition series metals(II,III). Preparation of bis(1,4,7-triazacyclononane)nickel(III) perchlorate , 1983 .

[70]  J. Sanders-Loehr,et al.  Structure of the binuclear iron complex in metazidohaemerythrin from Themiste dyscritum at 2.2. Å resolution , 1981, Nature.

[71]  K. Wieghardt,et al.  Komplexchemie des Gallium(III) mit makrozyklischen Liganden Darstellung und Kristallstruktur von Di‐μ‐hydroxo‐μ‐acetato‐bis[(1,4,7‐triazacyclononan)gallium(III)]triiodid · Monohydrat , 1986 .

[72]  J. Weiss,et al.  Preparation and crystal structure of bis(1,4,7-trithiacyclononane)iron(II) bis(hexafluorophosphate) containing an octahedral, low-spin FeIIS6 core. Electrochemistry of [M([9]aneS3)2]2+ complexes (M=Fe, Co, Ni) , 1985 .

[73]  S. Fujinami,et al.  Preparation and circular dichroism spectrum of a (triazacyclononane)(tribenzo(b,f,j)(1,5,9)triazacyclododecene)cobalt(III) complex. , 1981 .

[74]  Mariko Takahashi,et al.  The Preparation of Trivalent Metal Chelates with Some N3O3-Type Ligands , 1977 .

[75]  T. N. Margulis,et al.  THE CRYSTAL AND MOLECULAR STRUCTURE OF BIS(1,4,7-TRIAZACYCLODECANE)NICKEL(II) DIPERCHLORATE, (NI((10)ANEN3)2))(CLO4)2 , 1980 .

[76]  G. Schwarzenbach,et al.  Die Kinetik der Spaltung dinuklearer Tri‐μ‐hydroxo‐kobalt(III)‐Komplexe N3Co(Oh)3CoN33+ (triole) mit Säure , 1974 .

[77]  D. Sellmann,et al.  Übergangsmetallkomplexe mit schwefelliganden: X. Substitutions- und redox-reaktionen von molybdän(0)-carbonyl-komplexen mit den mehrzähnigen thioetherthiol-liganden 1,2-methylthiobenzolthiol, 1,4,7-trithiaheptan, 23,8,9-dibenzo-1,4,7,10-tetrathiadecan sowie 1,2-benzoldithiol☆ , 1985 .

[78]  H. K. Frensdorff,et al.  Macrocyclic polyethers and their complexes. , 1972, Angewandte Chemie.

[79]  M. Nonoyama.  Bis[(R)-2-methyl-1,4,7-triazacyclononane] cobalt(III), nickel(II), and copper(II) complexes , 1978 .

[80]  R. Hancock,et al.  Crystal structure of the Ni(ClO4)2 complex of the mixed donor macrocycle, 9-ane N2O: Resolution of disorder by force-field calculation , 1984 .

[81]  Reinhard Schwesinger,et al.  cis-Trioxa-tris-σ-homobenzol (cis-„Benzol-trioxid”)† , 1972 .

[82]  F. Cotton,et al.  The Crystal and Molecular Structure of Trioxo (diethylenetriamine)molybdenum(VI) , 1964 .

[83]  T. Meade,et al.  Inclusion Complexes of Molecular Transition Metal Hosts , 2007 .

[84]  K. Wieghardt,et al.  Synthese eines vierkernigen Mangan(IV)‐Clusters mit Adamantan‐Skelett: [C6H15N3)4Mn4O6]4+ , 2006 .

[85]  R. E. Terry,et al.  A calorimetric titration study of uni-and bivalent metal ion interaction with several thia derivatives of 9-crown-3, 12-crown-4, 15-crown-5, 18-crown-6, 24-crown-8, and with several oxathiapentadecanes in water or water-methanol solvents at 25 °C , 1978 .

[86]  K. Wieghardt,et al.  Charakterisierung von Distorsionsisomeren der Anionen Pentacyano‐oxo‐molybdat(IV) sowie Tetracyano‐oxo‐aqua‐molybdat(IV) im festen Zustand. Kristallstrukturen von [(C6H5)4P]3[MoO(CN)5] · 7 H2O(grün), [(C6H5)4As]2 [MoO(OH2)(CN)4] · 4 H2O (blau) und [(C6H5)4P]2[MoO(OH2)(CN)4] · 4 H2O (grün) , 1983 .

[87]  K. Wieghardt,et al.  [L2Fe 2II(μ‐OH)(μ‐CH3CO2)2](ClO4)·H2O, a Model Compound for the Diiron Centers in Deoxyhemerythrin , 1985 .

[88]  A. Drake,et al.  Single-crystal, vacuum-ultraviolet, and lon-association circular-dichroism spectra of the bis[(2R)-2-methyl-1,4,7-triazacyclononane]cobalt(III) lon , 1979 .

[89]  D. Sellmann,et al.  A Facile Route to 1,4,7‐Trithiacyclononane , 1984 .

[90]  G. Huttner,et al.  Hydrolysis Products of the Monomeric Amine Complex (C6H15N3)FeCl3: The Structure of the Octameric Iron(III) Cation of {[(C6H15N3)6Fe8(μ3‐O)2(μ2‐OH)12]Br7(H2O)}Br·8H2O , 1984 .

[91]  K. Wieghardt,et al.  Coordination chemistry of the bimacrocyclic, potentially binucleating ligand 1,2-bis(1,4,7-triaza-1-cyclononyl)ethane (dtne). Electrochemistry of its first transition series metal(II,III) complexes. Characterization of the new hemerythrin model complex [Fe2(dtne)(.mu.-O)(.mu.-CH3CO2)2]Br2.H2O , 1985 .

[92]  G. Dismukes,et al.  Intermediates of a polynuclear manganese center involved in photosynthetic oxidation of water. , 1981, Proceedings of the National Academy of Sciences of the United States of America.

[93]  進 高本,et al.  分光光度法による銅(II)およびニッケル(II)-トリアミンキレートの安定度定数測定 , 1975 .

[94]  H. Maeda,et al.  Synthesis of monoaza crown ethers from N,N-di(oligo(oxyalkylene))amines and oligoethylene glycol di(p-toluenesulfonates) or corresponding dichlorides. , 1983 .

[95]  R. Robson.  Complexes of binucleating ligands I. Two novel binuclear cupric complexes , 1970 .

[96]  G. Schwarzenbach,et al.  Metallkomplexe mit Polyaminen IV: Mit Diäthylentriamin = „den” , 1950 .

[97]  K. Wieghardt,et al.  Zweikerniger, gemischtvalenter MoVI/V-Komplex; Kristallstruktur von [(C9H21N3)2Mo2VI O5](Br3)2 , 1984 .

[98]  S. Lippard,et al.  A new synthetic approach to the ferritin core uncovers the soluble iron(III) oxo-hydroxo aggregate [Fe11O6(OH)6(O2CPh)15] , 1986, Nature.

[99]  K. Muir,et al.  Molybdenum(IV) oxo-complexes. Part II. Crystal and molecular structure of dichlorotris(diethylphenylphosphine)oxomolybdenum(IV), cis-mer-[MoOCl2(PEt2Ph)3] , 1972 .

[100]  R. Hancock,et al.  Optimum ligand hole sizes for stabilizing nickel (III). Structure of the nickel (III) complex of 1,4,7-triazacyclononane-N,N',N''-triacetate , 1983 .

[101]  D. Sellmann,et al.  Einfacher Weg zu 1,4,7-Trithiacyclononan , 1984 .

[102]  A. Simon,et al.  Herstellung, Magnetismus und Kristallstrukturen der Tautomere [LCu(μ2‐OH)2CuL](CIO4)2 (blau) und [LCu(μ2‐OH2)(μ2‐O)CuL](CIO4)2 (grün): μ‐Aqua‐μ‐oxo‐ vs. Di‐μ‐hydroxo‐Verknüpfung , 1985 .

[103]  R. M. Izatt,et al.  Maerocyelic polyether sulfide syntheses. The preparation of thia-crown-3,4, and 5 compounds , 1973 .

[104]  Ian D. Williams,et al.  Electronic and vibrational spectroscopic analysis of the (.mu.-oxo)bis(.mu.-carboxylato)diiron(III) core: a study of [Fe2O(O2CCH3)2(TACN)2]2+ , 1985 .

[105]  健生 有島,et al.  1,4,7トリアザシクロノナンおよび直鎖状トリアミンの2価金属キレートの安定度定数 , 1973 .

[106]  R. Hancock,et al.  Macrocyclic effect in transition metal ion complexes of a mixed (nitrogen, oxygen) donor macrocycle , 1982 .

[107]  J. Desreux.  Nuclear magnetic resonance spectroscopy of lanthanide complexes with a tetraacetic tetraaza macrocycle. Unusual conformation properties , 1980 .

[108]  S. Trofimenko.  Polypyrazolylborates, a new class of ligands , 1971 .

[109]  D. VanDerveer,et al.  X-ray structure of Mer-Trichloro[N-(3-aminopropyl)-1,3-diaminopropane]cobalt(III) , 1980 .

[110]  N. Sutin.  Nuclear, electronic, and frequency factors in electron transfer reactions , 1982 .

[111]  E. Doomes,et al.  COPPER(II) COMPLEXES OF BIS-2,6-(METHYLTHIOMETHYL) PYRIDINE AND THE DITHIA(2,6)PYRIDINOPHANES , 1976 .

[112]  D. A. House,et al.  1025. Transition-metal complexes with aliphatic Schiff bases. Part VII. Compounds formed by the reaction of copper(II) and nickel(II) dipropylenetriamine complexes with acetone , 1965 .

[113]  E. Fleischer,et al.  The Structure of a Self-Condensation Product ofo-Aminobenzaldehyde in the Presence of Nickel Ions , 1965 .

[114]  M. Viggiano,et al.  New class of .sigma.-bonded aliphatic aza-macrocyclic complexes of transition metals: synthesis and x-ray crystal structures of nitrogen-bridged [(TiN4C12H24)2] and the oxo-bridged species [(N4C12H25)TiOTi(N4C12H25)] , 1983 .

[115]  S. Lincoln,et al.  Isomers of the bis(1,4,7-triazacyclodecane)cobalt(III) ion, and the occurrence of higher cyclic and non-cyclic amines in the Richman—Atkins synthesis for cyclic amines , 1980 .

[116]  Karl Wieghardt,et al.  [{(C6H15N3)Fe}2(μ‐O)(μ‐CH3CO2)2]2+ a Dinuclear Iron, (III)Complex with a Metazidohemerythrin‐Type Structure , 1983 .

[117]  J. Halpern.  Mechanisms of coenzyme B12-dependent rearrangements. , 1985, Science.

[118]  B. Mannervik,et al.  The Oligomerization of Ethylene Oxide to Macrocyclic Ethers, Including 1,4,7-Trioxacyclononane. , 1974 .

[119]  J. P. Smith,et al.  State of manganese in the photosynthetic apparatus. 1. Extended x-ray absorption fine structure studies on chloroplasts and di-.mu.-oxo-bridged dimanganese model compounds , 1981 .

[120]  W. Marzluff.  Polyamine Complexes of Molybdenum Trioxide , 1964 .

[121]  Jean-Marie Lehn,et al.  Cryptates: inclusion complexes of macropolycyclic receptor molecules , 1978 .

[122]  V. Goedken,et al.  New macrocyclic complexes of titanium(IV): synthesis, reactivity, and X-ray crystal structure of the trigonal prismatic Ti(C22H22N4)Cl2, and synthesis and reactivity of its peroxo, disulphido, and pyrocatecholato derivatives , 1982 .

[123]  R. Hancock,et al.  Origin of macrocyclic enthalpy , 1980 .

[124]  L. A. Ochrymowycz,et al.  Synthesis of the torsionally strained monocyclic polythiaether 1,4,7-trithiacyclononane , 1977 .

[125]  N. Sutin.  Theory of electron transfer reactions: insights and hindsights , 2007 .

[126]  F. Anet,et al.  Conformation of 1,4,7-trioxacyclononane , 1974 .

[127]  K. Wieghardt,et al.  Syntheses of Monomeric, Dimeric, and Trimeric Complexes of Tungsten(VI), (V), (IV), and (III) with the 1,4,7‐Triazacyclononane (L) Ligand. Crystal Structures of Dimeric [W2L2(μ2OH)2Br2]Br2 · 2H2O and of Trimeric [W3L3(μ30)(μ2‐0)3][ZnBr4]2 , 1985 .

[128]  K. Wieghardt,et al.  New triply hydroxo-bridged complexes of chromium(III), cobalt(III), and rhodium(III): crystal structure of tris(.mu.-hydroxo)bis[(1,4,7-trimethyl-1,4,7-triazacyclononane)chromium(III)] triiodide trihydrate , 1982 .

[129]  E. Vogel,et al.  syn‐Benzoltrioxid – cis, cis, cis‐1,4,7‐Trioxacyclononatrien‐Valenzisomerisierung und anti‐Benzoltrioxid , 1972 .

[130]  H. Kuzuhara,et al.  Bifunctionalization of α,ω-sulphonamides via kinetically controlled reaction of α,ω-bis(N-nitrososulphonamides) , 1985 .

[131]  T. Kaden,et al.  Metal complexes with macrocyclic ligands. XIII. The complexation of Cu2+ with triazacycloalkanes , 1979 .

[132]  A. Shimizu,et al.  Preparation of Bis- and Tris(diamine)chromium(III) Complexes via Dimethyl Sulfoxide and Dimethylformamide Complexes. The Novel Series of cis-Bis(trimethylene-diamine)- and cis-Bis[(-)trans-1,2-cyclohexane-Diamine]chromium(III) Complexes. , 1970 .

[133]  D. Busch,et al.  The Coordination Template Effect in o-Aminobenzaldehyde-Metal Ion Systems and Formation of a Novel Chelate Sandwich Compound1 , 1966 .

[134]  K. Wieghardt,et al.  Neue μ‐Hydroxo‐Übergangsmetallkomplexe, I. Darstellung und Struktur des trans‐Diaqua‐di‐μ‐hydroxo‐bis[(1,4,7‐triazacyclononan)cobalt(III)]‐Kations; Kinetik und Mechanismus seiner Bildung , 1979 .

[135]  W. Setzer,et al.  CRYSTAL AND MOLECULAR STRUCTURE OF 1,4,7-TRITHIACYCLONONANE , 1980 .

[136]  E. Solomon,et al.  MCD-EPR studies of deoxy[FeII,FEII]hemerythrin: probes of endogenous bridging ligands and exogenous ligand binding , 1984 .

[137]  W. Setzer,et al.  Conformational analysis of mesocyclic polythioethers : Gas phase conformational analysis of five mesocyclic polythioethers using photoelectron spectroscopy , 1981 .

[138]  L. J. Zompa,et al.  Metal complexes of cyclic triamines. 1. Complexes of 1,4,7-triazacyclononane ([9]aneN3) with nickel(II), copper(II), and zinc(II) , 1976 .

[139]  K. Wieghardt,et al.  Synthesis of a Tetranuclear Manganese(IV) Cluster with Adamantane Skeleton: [(C6H15N3)4Mn4O6]4+ , 1983 .

[140]  Jean-Marie Lehn,et al.  Cryptates: the chemistry of macropolycyclic inclusion complexes , 1978 .

[141]  K. Wieghardt,et al.  Magnetic exchange interactions in some novel .mu.-azido-bridged copper(II) dimers. Crystal structures of [L2Cu2(.mu.-N3)(N3)2](ClO4).cntdot.H2O, LCu(N3)2, [L2Cu2(.mu.-N3)2(ClO4)2], and L'Cu(N3)2 (L = N,N',N"-trimethyl-1,4,7-triazacyclononane and L' = 1,4,7-triazacyclononane) , 1986 .

[142]  M. Nonoyama.  Synthesis of copper(II) and nickel(II) triazacycloalkane complexes , 1976 .

[143]  K. Wieghardt,et al.  Crystallographic study of the low-spin iron(II) and iron(III) bis complexes of 1,4,7-triazacyclononane , 1985 .

[144]  S. Fujinami,et al.  Crystal structure of (−)589‐ammineglycinato(1,4,7‐triazacyclononane)cobalt(III) diiodide 0.84‐hydrate , 1980 .

[145]  H. Gampp,et al.  Unusual redox and chemical properties of a sterically constrained N3CuII center. Preparation, structure, and solution studies of (nitrato)(1,4,7-triazacyclododecane)copper(II) nitrate , 1984 .

[146]  O. P. Anderson,et al.  Structural and electronic properties of tetranuclear iron(III) pyridylamine complexes containing cofacial pairs of µ-oxo-bis(µ-acetato)iron(III) moieties. Models for met hemerythrins , 1986 .

[147]  M. Nonoyama.  5- and 6-coordinate cobalt(II) isothiocyanato complexes with cyclic triamines , 1977 .

[148]  K. Wieghardt,et al.  Macrocyclic complexes of indium(III): novel .mu.-hydroxo- and .mu.-oxo-bridged complexes. Crystal structures of [L4In4(.mu.-OH)6](S2O6)3.4H2O and [L2In2(CH3CO2)4(.mu.-O)].2NaClO4 (L = 1,4,7-triazacyclononane) , 1986 .

[149]  A. Merz.  2,3,11,12‐Tetraphenyl‐1,4,7,10,13,16‐hexaoxa‐2,11‐cyclooctadecadien. Ein neuer Kronenether aus Benzoin , 1977 .

[150]  H. Kuzuhara,et al.  Synthesis and characterization of macrocyclic polyaza(2,5)pyridinophanes possessing vitamin B6 functionality. , 1986 .

[151]  F. Cotton,et al.  A Molecular Orbital Treatment of the Bonding in Certain Metal Atom Clusters , 1964 .

[152]  S. Fujinami,et al.  Circular Dichroism Spectra of fac(D)-[Co(a)(BC)(DDD)n+ Type Complexes with 1,4,7-Triazacyclononane, (2R)-2-Methyl-1,4,7-triazacyclononane, and 1,5,9-Triazacyclododecane , 1982 .

[153]  G. H. Searle,et al.  Improved Richman-Atkins syntheses of cyclic polyamines particularly 1,4,7-triazacyclononane (tacn) and 1,4,7-triazacyclodecane (tacd), with the aid of cation-exchange in purification and isolation , 1984 .

[154]  K. Wieghardt,et al.  Preparation and crystal structure of tetrameric [Ti4(C6H15N3)4(μ-O)6]Br4·4H2O containing an adamantane Ti4O6 Core , 1985 .

[155]  D. Busch,et al.  Octahedral nickel(II) complexes of some cyclic polyfunctional thioethers , 1970 .

[156]  R. Mattes,et al.  Mehrkernige Oxofluoroanionen des Wolframs(V) und Wolframs(IV) Die Kristallstrukturen von K3H[W2O4F6] und (NH4)5[W3O4F9] · NH4F · H2O , 1977 .

[157]  K. Wieghardt,et al.  Reactivity of the [Fe2(μ2‐O)(μ‐acetato)2] Unit in Methemerythrin Model Compounds towards N 3⊖ and NCS⊖ , 1985 .

[158]  K. Wieghardt,et al.  Synthesis and crystal structure of bis(.mu.-hydroxo)bis[oxo(1,4,7-triazacyclononane)vanadium(IV)] dibromide, a .mu.-hydroxo-bridged cation with antiferromagnetically coupled vanadium(IV) centers , 1984 .

[159]  R. M. Izatt,et al.  Ion Binding by Synthetic Macrocyclic Compounds , 1971, Science.

[160]  K. Raymond,et al.  Ferric ion sequestering agents. 1. Hexadentate O-bonding N,N',N"-tris(2,3-dihydroxybenzoyl) derivatives of 1,5,9-triazacyclotridecane and 1,3,5-triaminomethylbenzene , 1979 .

[161]  K. Wieghardt,et al.  Kinetics and mechanism of the oxidation of bis(.mu.-hydroxo)bis[aqua(1,4,7-triazacyclononane)molybdenum(III)](4+) by perchlorate. Acid-base-catalyzed trans .fwdarw. cis isomerization of bis(.mu.-oxo)-trans-dioxobis[(1,4,7-triazacyclononane)molybdenum(V)](2+) , 1984 .

[162]  Jean-Marie Lehn,et al.  Design of organic complexing agents Strategies towards properties , 1973 .

[163]  D. Busch,et al.  Chromatographic resolution of the antipodes of a helical complex of nickel(II) , 1967 .

[164]  E. Weiss,et al.  (PhC≡CLi)4(tmhda)2, eine polymere Organolithiumverbindung mit kubischen Li4C4‐Struktureinheiten , 1983 .

[165]  D. Rice,et al.  Ferritin: design and formation of an iron-storage molecule. , 1984, Philosophical transactions of the Royal Society of London. Series B, Biological sciences.

[166]  Dieter Hunkler,et al.  „cis‐Triaza‐tris‐σ‐homobenzole”︁ („cis‐Benzoltriimine”︁) Synthesen und [σ2s + σ2s + σ2s]‐Cycloreversionen zu 4,7‐Dihydro‐1H‐1,4,7‐triazoninen , 1980 .

[167]  E. Kimura.  Macrocyclic polyamines as biological cation and anion complexones — An application to calculi dissolution , 1985 .

[168]  K. Wieghardt,et al.  Neue μ‐Hydroxo‐Übergangsmetallkomplexe, II. Darstellung mehrkerniger Komplexe des Chroms(III) mit dreizähnigen Amin‐Liganden. Struktur des μ[cis‐Dihydroxo(O,O′)‐hydroxo(l,4,7‐triazacyclononan)chrom(III)]‐di‐μ‐hydroxobis[(1,4,7‐triazacyclononan)chrom(III)]‐Kations , 1979 .

[169]  R. Hancock,et al.  Molecular mechanics and crystallographic study of hole sizes in nitrogen-donor tetraaza macrocycles , 1984 .

[170]  Y. Tsai,et al.  Reactions of LM(CO)3 complexes (M=Cr, Mo, W; L= 1,4,7-triazacyclononane) with bromine, iodine, and nitric acid. Syntheses of air-stable hydridocarbonyl and hydridonitrosyl complexes. Crystal structure of [LMo(CO)3Br](ClO4)•H2O , 1984 .

[171]  L. Sieker,et al.  Active site structures of deoxyhemerythrin and oxyhemerythrin. , 1985, Proceedings of the National Academy of Sciences of the United States of America.

[172]  P. R. Norman,et al.  Kinetic Aspects of Redox Reactions of Nickel(III) Complexes , 1985 .

[173]  K. Wieghardt,et al.  Syntheses, properties, and electrochemistry of transition-metal complexes of the macrocycle 1,4,7-tris(2-pyridylmethyl)-1,4,7-triazacyclononane (L). Crystal structures of [NiL](ClO4)2, [MnL](ClO4)2, and [PdL](PF6)2 containing a distorted-square-base-pyramidal PdIIN5 core , 1986 .

[174]  W. Kläui.  [(C5H5)CO{P(0)(0C2H5)2}3]-: Eine einfache Synthese eines metallorganischen Tripodliganden und seine Reaktivität gegenüber den Kationen der III. Hauptgruppe / [(C5H5)CO{P(0)(0C2H5)2}3]-: A Convenient Synthesis of an Organometallic Tripod Ligand and its Reactivity towards the Main Group III Cations , 1979 .

[175]  K. Wieghardt,et al.  The Cation Di‐μ‐oxo‐trans‐dioxobis[(1,4,7‐triazacyclononane)molybdenum(V)](Mo—Mo) and its Acid‐Catalyzed cis‐Isomerization , 1983 .

[176]  K. Wieghardt,et al.  Distorsionsisomere vom [LWOCl2]+ im festen Zustand und in Lösung; Kristallstrukturen der blauen und der der grünen Form von [LWOCl2]PF6 , 1985 .

[177]  H. Prinzbach,et al.  Chemie des cis‐Triaza‐tris‐σ‐homobenzols. 3σ→3π‐Isomerisierung zum 1,4,7‐Triaza‐2,5,8‐cyclononatrien‐Gerüst , 1975 .

[178]  L. Fabbrizzi,et al.  Cyclic effects with medium ring triamines. Enthalpy and entropy contributions to the solution stability of copper(II) and zinc(II) complexes with 1,4,7-triazacyclononane , 1977 .

[179]  K. Wieghardt,et al.  Spontaneous self assembly of the {M2(µ-O)(µ-MeCO2)2}2+ core. Synthesis, structure, and properties of the binuclear vanadium(III) complex , 1986 .

[180]  F. Cotton.  Metal Atom Clusters in Oxide Systems , 1964 .

[181]  K. Wieghardt,et al.  1,4,7-Triazacyclononane-N,N',N''-triacetate (TCTA), a new hexadentate ligand for divalent and trivalent metal ions. Crystal structures of [CrIII(TCTA)], [FeIII(TCTA)], and Na[CuII(TCTA)].bul.2NaBr.bul.8H2O , 1982 .

[182]  J. Almog,et al.  Condensation of tetraaldehydes with pyrrole. Direct synthesis of capped porphyrins , 1975 .

[183]  K. Wieghardt,et al.  Preparation, Magnetism, and Crystal Structures of the Tautomers [LCu(μ2-OH)2CuL](ClO4)2 (Blue) and [LCu(μ2-OH2)(μ2-O)CuL](ClOμ4)μ2 (Green): μ-Aqua-μ-oxo vs. Di-μ-hydroxo Linkage , 1985 .

[184]  W. Kläui,et al.  Zur reaktivität von cobaltocen und nickelocen gegenüber sekundären phosphinchalkogeniden: Ein weg zu mehrzähnigen sauerstoff- und schwefel-liganden , 1983 .

[185]  G. H. Searle,et al.  Isomers of the bis(1,4,7-triazacyclodecane)cobalt(III) and (1,4,7,11,14,17−, hexaazacycloeicosane)cobalt(III) ions: Preparations, characterizations and isomerization , 1981 .

[186]  K. Wieghardt,et al.  Syntheses of [LRe(CO)3]+ and [LRe(NO)(CO)2]2+ and their oxidative decarbonylation product [LReO3]+. Crystal structure of [LReO3]Cl (L = 1,4,7-triazacyclononane) , 1986 .

[187]  A. Ozarowski,et al.  Anisotropic exchange interactions in the copper(II) and vanadium(IV) dimers [(L')Cu(.mu.-OH)2Cu(L')](ClO4)2 and [(L)VO(.mu.-OH)2VO(L)]Br2 with 1,4,7-triazacyclononane (L) and its N,N',N"-trimethyl derivative (L'): a single-crystal EPR study , 1986 .