论文信息 - Comment on “Equilibrium constants and rate constants for adsorbates: Two-dimensional (2D) ideal gas, 2D ideal lattice gas, and ideal hindered translator models”

Comment on “Equilibrium constants and rate constants for adsorbates: Two-dimensional (2D) ideal gas, 2D ideal lattice gas, and ideal hindered translator models”

The paper by Campbell et al. was recently brought to my attention. This comment is written to provide greater clarity to the community to prevent misconceptions regarding the entropies being discussed in that work and to clarify the differences between the adsorbate standard states suggested by Campbell and by Savara.

A. Savara

[1] C. Campbell,et al. Equilibrium Constants and Rate Constants for Adsorbates: Two-Dimensional (2D) Ideal Gas, 2D Ideal Lattice Gas, and Ideal Hindered Translator Models , 2016 .

[2] A. Savara. Standard States for Adsorption on Solid Surfaces: 2D Gases, Surface Liquids, and Langmuir Adsorbates , 2013 .

[3] E. Weitz,et al. Adsorption Entropies and Enthalpies and Their Implications for Adsorbate Dynamics , 2009 .

[4] J. Cox. Notation for states and processes, significance of the word standard in chemical thermodynamics, and remarks on commonly tabulated forms of thermodynamic functions , 1982 .