Hybridized plasmon modes and near-field enhancement of metallic nanoparticle-dimer on a mirror

For the attractive plasmonic structure consisting of metal nanoparticles (NPs) on a mirror, the coexistence of near-field NP-NP and NP-mirror couplings is numerically studied at normal incidence. By mapping their 3D surface charge distributions directly, we have demonstrated two different kinds of mirror-induced bonding dipole plasmon modes and confirmed the bonding hybridizations of the mirror and the NP-dimer which may offer a much stronger near-field enhancement than that of the isolated NP dimers over a broad wavelength range. Further, it is revealed that the huge near-field enhancement of these two modes exhibit different dependence on the NP-NP and NP-mirror hot spots, while both of their near-field resonance wavelengths can be tuned to the blue exponentially by increasing the NP-NP gaps or the NP-mirror separation. Our results here benifit significantly the fundamental understanding and practical applications of metallic NPs on a mirror in plasmonics.

[1]  Yiping Zhao,et al.  Enhanced surface-enhanced Raman scattering performance by folding silver nanorods , 2012 .

[2]  J. M. Taboada,et al.  MLFMA-MoM for Solving the Scattering of Densely Packed Plasmonic Nanoparticle Assemblies , 2015, IEEE Photonics Journal.

[3]  George C Schatz,et al.  Structure-activity relationships in gold nanoparticle dimers and trimers for surface-enhanced Raman spectroscopy. , 2010, Journal of the American Chemical Society.

[4]  De‐Yin Wu,et al.  Extraordinary enhancement of Raman scattering from pyridine on single crystal Au and Pt electrodes by shell-isolated Au nanoparticles. , 2011, Journal of the American Chemical Society.

[5]  De‐Yin Wu,et al.  Nanostructure-based plasmon-enhanced Raman spectroscopy for surface analysis of materials , 2016 .

[6]  W. Choy,et al.  Highly Intensified Surface Enhanced Raman Scattering by Using Monolayer Graphene as the Nanospacer of Metal Film–Metal Nanoparticle Coupling System , 2014 .

[7]  G. Schatz,et al.  Fundamental behavior of electric field enhancements in the gaps between closely spaced nanostructures. , 2010, 1008.2490.

[8]  David R. Smith,et al.  Probing dynamically tunable localized surface plasmon resonances of film-coupled nanoparticles by evanescent wave excitation. , 2012, Nano letters.

[9]  Thomas Härtling,et al.  Surface-enhanced infrared spectroscopy using nanometer-sized gaps. , 2014, ACS nano.

[10]  Lingyan Meng,et al.  Probing the location of hot spots by surface-enhanced Raman spectroscopy: toward uniform substrates. , 2014, ACS nano.

[11]  Jian-Feng Li,et al.  In Situ Monitoring of Electrooxidation Processes at Gold Single Crystal Surfaces Using Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy. , 2015, Journal of the American Chemical Society.

[12]  Francesco De Angelis,et al.  3D Nanostar Dimers with a Sub‐10‐nm Gap for Single‐/Few‐Molecule Surface‐Enhanced Raman Scattering , 2014, Advanced materials.

[13]  Mengjing Hou,et al.  Near-field mapping of three-dimensional surface charge poles for hybridized plasmon modes , 2015 .

[14]  A. Zayats,et al.  Nonlinear plasmonics , 2012, Nature Photonics.

[15]  David R. Smith,et al.  Distance-dependent plasmon resonant coupling between a gold nanoparticle and gold film. , 2008, Nano letters.

[16]  Per Ola Andersson,et al.  Dimer-on-mirror SERS substrates with attogram sensitivity fabricated by colloidal lithography. , 2015, Nanoscale.

[17]  Luke P. Lee,et al.  Comparison of near- and far-field measures for plasmon resonance of metallic nanoparticles. , 2009, Optics letters.

[18]  Fadi Issam Baida,et al.  Coupling between surface plasmon modes on metal films , 2004 .

[19]  D. L. Jeanmaire,et al.  Surface raman spectroelectrochemistry: Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode , 1977 .

[20]  R. Frontiera,et al.  SERS: Materials, applications, and the future , 2012 .

[21]  Strong plasmon coupling between two gold nanospheres on a gold slab , 2011, 1107.5939.

[22]  David R. Smith,et al.  Controlled-reflectance surfaces with film-coupled colloidal nanoantennas , 2012, Nature.

[23]  G. Schatz,et al.  Electromagnetic fields around silver nanoparticles and dimers. , 2004, The Journal of chemical physics.

[24]  P. K. Aravind,et al.  A new geometry for field enhancement in surface-enhanced spectroscopy , 1982 .

[25]  Emil Prodan,et al.  Quantum description of the plasmon resonances of a nanoparticle dimer. , 2009, Nano letters.

[26]  Mengjing Hou,et al.  Nanogap effects on near- and far-field plasmonic behaviors of metallic nanoparticle dimers. , 2015, Physical chemistry chemical physics : PCCP.

[27]  De‐Yin Wu,et al.  In-situ electrochemical shell-isolated Ag nanoparticles-enhanced Raman spectroscopy study of adenine adsorption on smooth Ag electrodes , 2016 .

[28]  Prashant K. Jain,et al.  On the Universal Scaling Behavior of the Distance Decay of Plasmon Coupling in Metal Nanoparticle Pairs: A Plasmon Ruler Equation , 2007 .

[29]  K. S. Shin,et al.  Raman Scattering of 4-Aminobenzenethiol Sandwiched between Au Nanoparticles and a Macroscopically Smooth Au Substrate: Effect of Size of Au Nanoparticles , 2009 .

[30]  M. Majewski,et al.  Optical properties of metallic films for vertical-cavity optoelectronic devices. , 1998, Applied optics.

[31]  B. Wei,et al.  An all-copper plasmonic sandwich system obtained through directly depositing copper NPs on a CVD grown graphene/copper film and its application in SERS. , 2015, Nanoscale.

[32]  Mengjing Hou,et al.  Gradual plasmon evolution and huge infrared near-field enhancement of metallic bridged nanoparticle dimers. , 2016, Physical chemistry chemical physics : PCCP.

[33]  F Javier García de Abajo,et al.  Surface plasmon dependence on the electron density profile at metal surfaces. , 2014, ACS nano.

[34]  David R. Smith,et al.  Film-coupled nanoparticles by atomic layer deposition: Comparison with organic spacing layers , 2014 .

[35]  张忠平,et al.  Graphene oxide embedded sandwich nanostructures for enhanced Raman readout and their applications in pesticide monitoring , 2013 .

[36]  K. Crozier,et al.  Experimental study of the interaction between localized and propagating surface plasmons. , 2009, Optics letters.

[37]  J. M. Taboada,et al.  Comparison of surface integral equation formulations for electromagnetic analysis of plasmonic nanoscatterers. , 2012, Optics express.

[38]  Denis Boudreau,et al.  Label-free biosensing based on multilayer fluorescent nanocomposites and a cationic polymeric transducer. , 2011, ACS nano.

[39]  M. Stockman Nanoplasmonics: past, present, and glimpse into future. , 2011, Optics express.

[40]  Ullrich Steiner,et al.  Single molecule SERS and detection of biomolecules with a single gold nanoparticle on a mirror junction. , 2013, The Analyst.

[41]  April S. Brown,et al.  UV Plasmonic Behavior of Various Metal Nanoparticles in the Near- and Far-Field Regimes: Geometry and Substrate Effects , 2013 .

[42]  E. Palik Handbook of Optical Constants of Solids , 1997 .

[43]  N. Halas,et al.  Tailoring plasmonic substrates for surface enhanced spectroscopies. , 2008, Chemical Society reviews.

[44]  R. Dasari,et al.  Single Molecule Detection Using Surface-Enhanced Raman Scattering (SERS) , 1997 .

[45]  Z. Tian,et al.  A theoretical and experimental approach to shell-isolated nanoparticle-enhanced Raman spectroscopy of single-crystal electrodes , 2015 .

[46]  S. Gray,et al.  Plasmonic amplifiers: engineering giant light enhancements by tuning resonances in multiscale plasmonic nanostructures. , 2013, Small.

[47]  J. Aizpurua,et al.  Controlling subnanometer gaps in plasmonic dimers using graphene. , 2013, Nano letters.

[48]  W. Wen,et al.  Plasmon-driven surface catalysis in hybridized plasmonic gap modes , 2014, Scientific Reports.

[49]  Martin Moskovits,et al.  Plasmonic properties of gold nanoparticles separated from a gold mirror by an ultrathin oxide. , 2012, Nano letters.

[50]  S. Maier,et al.  Use of a gold reflecting-layer in optical antenna substrates for increase of photoluminescence enhancement. , 2013, Optics express.

[51]  P. Nordlander,et al.  A Hybridization Model for the Plasmon Response of Complex Nanostructures , 2003, Science.

[52]  Steven R. Emory,et al.  Probing Single Molecules and Single Nanoparticles by Surface-Enhanced Raman Scattering , 1997, Science.

[53]  R. T. Hill,et al.  Probing the Ultimate Limits of Plasmonic Enhancement , 2012, Science.

[54]  G. Park,et al.  Terahertz field enhancement by a metallic nano slit operating beyond the skin-depth limit , 2009 .

[55]  R. Blaikie,et al.  Probing Plasmonic Gap Resonances between Gold Nanorods and a Metallic Surface , 2015 .

[56]  A. Dhawan,et al.  Full-wave electromagentic analysis of a plasmonic nanoparticle separated from a plasmonic film by a thin spacer layer. , 2014, Optics express.

[57]  Peter Nordlander,et al.  Substrates matter: influence of an adjacent dielectric on an individual plasmonic nanoparticle. , 2009, Nano letters.

[58]  Mengjing Hou,et al.  Silver Nanorods Wrapped with Ultrathin Al2O3 Layers Exhibiting Excellent SERS Sensitivity and Outstanding SERS Stability , 2015, Scientific Reports.

[59]  Ibrahim Abdulhalim,et al.  Ultrahigh Enhancement of Electromagnetic Fields by Exciting Localized with Extended Surface Plasmons , 2015, 1507.00311.

[60]  M. El-Sayed,et al.  On the use of plasmonic nanoparticle pairs as a plasmon ruler: the dependence of the near-field dipole plasmon coupling on nanoparticle size and shape. , 2009, The journal of physical chemistry. A.

[61]  Mohsen Rahmani,et al.  University of Birmingham Third-harmonic-upconversion enhancement from a single semiconductor nanoparticle coupled to a plasmonic antenna , 2016 .

[62]  Emil Prodan,et al.  Plasmon Hybridization in Nanoparticle Dimers , 2004 .

[63]  Jian-Feng Li,et al.  Electrochemical shell-isolated nanoparticle-enhanced Raman spectroscopy: correlating structural information and adsorption processes of pyridine at the Au(hkl) single crystal/solution interface. , 2015, Journal of the American Chemical Society.

[64]  Mark D. Huntington,et al.  Hetero-oligomer nanoparticle arrays for plasmon-enhanced hydrogen sensing. , 2014, ACS nano.

[65]  Zhilin Yang,et al.  How To Light Special Hot Spots in Multiparticle-Film Configurations. , 2016, ACS nano.

[66]  In-Yong Park,et al.  High-harmonic generation by resonant plasmon field enhancement , 2008, Nature.

[67]  Yingzhou Huang,et al.  Electromagnetic field redistribution in hybridized plasmonic particle-film system , 2013 .

[68]  R. G. Freeman,et al.  Structure enhancement factor relationships in single gold nanoantennas by surface-enhanced Raman excitation spectroscopy. , 2013, Journal of the American Chemical Society.

[69]  Bhavya Sharma,et al.  Single nanoparticle plasmonics. , 2013, Physical chemistry chemical physics : PCCP.

[70]  P. Kik,et al.  Gap-Plasmon Enhanced Gold Nanoparticle Photoluminescence , 2014 .

[71]  Naomi J Halas,et al.  Nanoshell-enabled photothermal cancer therapy: impending clinical impact. , 2008, Accounts of chemical research.

[72]  E. Coronado,et al.  The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment , 2003 .

[73]  J. Pendry,et al.  Collective Theory for Surface Enhanced Raman Scattering. , 1996, Physical review letters.

[74]  Louise Poissant Part I , 1996, Leonardo.

[75]  Zhong Lin Wang,et al.  Shell-isolated nanoparticle-enhanced Raman spectroscopy , 2010, Nature.