Nanoremediation and International Environmental Restoration Markets

Nanoscale zero-valent iron (nZVI) is the most commonly used nanoremediation material. While there has been a reasonable level of application of nZVI technologies for in situ remediation in the United States, its utilization across Europe has been much more limited. There has been significant uncertainty about the balance between deployment risks and benefits for nanoparticles (NPs), which has affected the regulatory position in several countries. Some member states of the European Union (EU) take a strong precautionary view of the risks from the deployment of NPs into the subsurface, preventing the adoption of the technology. This article provides a risk–benefit assessment for nZVI based on published information and describes the steps that will be taken by a major European research project (NanoRem), as part of its work to provide a basis for better informed decision making in European environmental restoration markets. A key part of this process is dialogue between practitioners and researchers. NanoRem therefore has an active process of communication with different stakeholder networks (regulators, service providers, and site owners). NanoRem hopes to stimulate a consensus on appropriate use of nanoremediation and thereby stimulate effective technology transfer to the European remediation market. ©2015 The Authors

[1]  Harald Burmeier NATO/CCMS pilot study : evaluation of demonstrated and emerging technologies for the treatment of contaminated land and groundwater -- phase III : special session on treatment walls and rermeable[i.e. permeable] reactive barriers , 1998 .

[2]  D. Elliott,et al.  Field assessment of nanoscale bimetallic particles for groundwater treatment. , 2001, Environmental science & technology.

[3]  Paul G Tratnyek,et al.  Characterization and properties of metallic iron nanoparticles: spectroscopy, electrochemistry, and kinetics. , 2005, Environmental science & technology.

[4]  E. Rubin,et al.  Noncombustion technologies for remediation of persistent organic pollutants in stockpiles and soil , 2006 .

[5]  Richard L. Johnson,et al.  Nanotechnologies for environmental cleanup , 2006 .

[6]  Florin Gheorghiu,et al.  Nanotechnology and groundwater remediation: A step forward in technology understanding , 2006 .

[7]  G. Lowry,et al.  Effect of particle age (Fe0 content) and solution pH on NZVI reactivity: H2 evolution and TCE dechlorination. , 2006, Environmental science & technology.

[8]  Mark R Wiesner,et al.  In vitro interactions between DMSA-coated maghemite nanoparticles and human fibroblasts: A physicochemical and cyto-genotoxical study. , 2006, Environmental science & technology.

[9]  Benjamin Gilbert,et al.  Stable cluster formation in aqueous suspensions of iron oxyhydroxide nanoparticles. , 2006, Journal of colloid and interface science.

[10]  Rickerby David,et al.  Report from the Workshop on Nanotechnologies for Environmental Remediation , 2007 .

[11]  Paul G Tratnyek,et al.  Rapid dechlorination of polychlorinated dibenzo-p-dioxins by bimetallic and nanosized zerovalent iron. , 2008, Environmental science & technology.

[12]  Krzysztof Matyjaszewski,et al.  Ionic strength and composition affect the mobility of surface-modified Fe0 nanoparticles in water-saturated sand columns. , 2008, Environmental science & technology.

[13]  B. Chisholm,et al.  Remediation of alachlor and atrazine contaminated water with zero-valent iron nanoparticles , 2009, Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes.

[14]  G. Lowry,et al.  Towards a definition of inorganic nanoparticles from an environmental, health and safety perspective. , 2009, Nature nanotechnology.

[15]  R. Tilton,et al.  Adsorbed polyelectrolyte coatings decrease Fe(0) nanoparticle reactivity with TCE in water: conceptual model and mechanisms. , 2009, Environmental science & technology.

[16]  Pedro J J Alvarez,et al.  Effects of nano-scale zero-valent iron particles on a mixed culture dechlorinating trichloroethylene. , 2010, Bioresource technology.

[17]  Gregory V. Lowry,et al.  Chemical transformations during aging of zerovalent iron nanoparticles in the presence of common groundwater dissolved constituents. , 2010, Environmental science & technology.

[18]  Pedro J J Alvarez,et al.  Adsorbed polymer and NOM limits adhesion and toxicity of nano scale zerovalent iron to E. coli. , 2010, Environmental science & technology.

[19]  Khara D Grieger,et al.  Environmental benefits and risks of zero-valent iron nanoparticles (nZVI) for in situ remediation: risk mitigation or trade-off? , 2010, Journal of contaminant hydrology.

[20]  Kelvin B. Gregory,et al.  Impact of nanoscale zero valent iron on geochemistry and microbial populations in trichloroethylene contaminated aquifer materials. , 2010, Environmental science & technology.

[21]  R. Singh,et al.  Degradation of lindane contaminated soil using zero-valent iron nanoparticles. , 2011, Journal of biomedical nanotechnology.

[22]  R. Bardos,et al.  A Risk/Benefit Approach to the Application of Iron Nanoparticles for the Remediation of Contaminated Sites in the Environment , 2011 .

[23]  Rajandrea Sethi,et al.  A Comparison Between Field Applications of Nano-, Micro-, and Millimetric Zero-Valent Iron for the Remediation of Contaminated Aquifers , 2011 .

[24]  Barbara Karn,et al.  Nanotechnology and in situ remediation: a review of the benefits and potential risks. , 2011, Ciencia & saude coletiva.

[25]  Heechul Choi,et al.  Removal of trichloroethylene DNAPL trapped in porous media using nanoscale zerovalent iron and bimetallic nanoparticles: direct observation and quantification. , 2012, Journal of hazardous materials.

[26]  M. C. Lobo,et al.  Assessing the impact of zero-valent iron (ZVI) nanotechnology on soil microbial structure and functionality: a molecular approach. , 2012, Chemosphere.

[27]  E. Joner,et al.  Ecotoxicological effects on earthworms of fresh and aged nano-sized zero-valent iron (nZVI) in soil. , 2012, Chemosphere.

[28]  D. O’Carroll,et al.  Nanoscale zero valent iron and bimetallic particles for contaminated site remediation , 2013 .

[29]  C. Fajardo,et al.  Transcriptional and proteomic stress responses of a soil bacterium Bacillus cereus to nanosized zero-valent iron (nZVI) particles. , 2013, Chemosphere.

[30]  Impact of Fe and Ni/Fe nanoparticles on biodegradation of phenol by the strain Bacillus fusiformis (BFN) at various pH values. , 2013, Bioresource technology.

[31]  N. Ruiz,et al.  Travel distance and transformation of injected emulsified zerovalent iron nanoparticles in the subsurface during two and half years. , 2013, Water research.

[32]  E. Joner,et al.  Effects of nano-sized zero-valent iron (nZVI) on DDT degradation in soil and its toxicity to collembola and ostracods. , 2013, Chemosphere.

[33]  M. Lopez,et al.  Uranium removal from a contaminated effluent using a combined microbial and nanoparticle system. , 2013, New biotechnology.

[34]  Paul G Tratnyek,et al.  Field-scale transport and transformation of carboxymethylcellulose-stabilized nano zero-valent iron. , 2013, Environmental Science and Technology.

[35]  M. Černík,et al.  In-Situ Combination of Bio and Abio Remediation of Chlorinated Ethenes , 2013 .