A view of the future of molecular electronics

Abstract The article describes some prevailing thoughts and an approach to the development of molecular circuit elements for molecular electronics. Three basic principles are proposed and exemplified by a particular example of a suitable molecule. The model relies upon the current state of the art in science and technology.

[1]  A. Messiah Quantum Mechanics , 1961 .

[2]  Arthur T. Hubbard,et al.  Electrochemistry of chemisorbed molecules. I. Reactants connected to electrodes through olefinic substituents , 1973 .

[3]  Herbert Taub,et al.  Digital Circuits And Microprocessors , 1981 .

[4]  R. Marcus,et al.  Electron transfers in chemistry and biology , 1985 .

[5]  Stuart W. Staley,et al.  Electron-transfer valence tautomerism. The bicyclooctatetraenyl and 1,2-dicyclooctatetraenylethylene dianions , 1985 .

[6]  George M. Whitesides,et al.  Improved adhesion of thin conformal organic films to metal surfaces , 1986 .

[7]  J. Verhoeven,et al.  Through-bond charge transfer interaction and photoinduced charge separation , 1986 .

[8]  Dwaine O. Cowan,et al.  The Organic Solid State. , 1986 .

[9]  R. Feynman Quantum mechanical computers , 1986 .

[10]  D. Allara,et al.  Spontaneously organized molecular assemblies. 4. Structural characterization of n-alkyl thiol monolayers on gold by optical ellipsometry, infrared spectroscopy, and electrochemistry , 1987 .

[11]  J. J. Hopfield,et al.  Effect of exothermicity on electron transfer rates in photosynthetic molecular models , 1987, Nature.

[12]  Walter Huber,et al.  The Dependence of Intramolecular Electron Transfer on Structure in a Spiro Compound Containing Two Cyclooctatetraene Moieties , 1987 .

[13]  A. Aviram Molecules for memory, logic and amplification , 1988 .

[14]  D. P. Kern,et al.  Direct deposition of 10‐nm metallic features with the scanning tunneling microscope , 1988 .

[15]  Sean Washburn,et al.  Quantum Interference Fluctuations in Disordered Metals , 1988 .

[16]  Nikola Batina,et al.  Molecular Adsorption at Well-Defined Platinum Surfaces: Voltammetry Assisted by Auger Spectroscopy, Electron Energy-Loss Spectroscopy, and Low-Energy Electron Diffraction , 1988 .

[17]  K. Likharev Correlated discrete transfer of single electrons in ultrasmall tunnel junctions , 1988 .

[18]  R.H. Dennard,et al.  Inverter performance of deep-submicrometer MOSFETs , 1988, IEEE Electron Device Letters.

[19]  Abraham Ulman,et al.  Packing and Molecular Orientation of Alkanethiol Monolayers on Gold Surfaces , 1989 .

[20]  G M Whitesides,et al.  Orthogonal Self-Assembled Monolayers: Alkanethiols on Gold and Alkane Carboxylic Acids on Alumina , 1989, Science.

[21]  E. Clementi,et al.  Electric-field induced intramolecular electron transfer in spiro .pi.-electron systems and their suitability as molecular electronic devices. A theoretical study , 1990 .

[22]  Adrian T. Wong,et al.  Electron and energy transfer through bridged systems. 6. Molecular switches: the critical field in electric field activated bistable molecules , 1990 .

[23]  J. Tour,et al.  Extended orthogonally fused conducting oligomers for molecular electronic devices , 1991 .