Pyrolysis of empty oil palm fruit bunches using the quartz fluidised- fixed bed reactor

In this study, pyrolysis of oil palm empty fruit bunches (EFB) was investigated using a quartz fluidized-fixed bed reactor. The effects of pyrolysis temperatures, particle sizes, heating rates, different oil palm biomass and different type of fluidised beds material on the yields of the products were investigated. The temperature of pyrolysis and heating rate were varied in the range 300-700 ÂoC and 10-100 ÂoC min-1 respectively. The particle size was varied in the range of <90, 91-106, 107-125 and 126-250 I¼m. EFB, trunk, frond and fiber were used to investigate effect of different oil palm biomass on pyrolysis yields. Meanwhile, zircon sand, spent bleaching earth and spent bleaching earth washing with hexane were used to investigate effect of different type of fluidised bed material on pyrolysis yields. The products obtained from pyrolysis of EFB were bio-oil, char and gas. The maximum bio-oil yield was 42.28% obtained at 500 ÂoC, with a heating rate of 100 ÂoC min-1 and particle size of 91-106 I¼m. The maximum product yield of char was 41.56% obtained at pyrolysis temperature of 300 ÂoC, heating rate of 30 ÂoC min-1 and particle size of 91 – 106 I¼m. Meanwhile, the optimum yield of gas was 46.00% could be achieved at the pyrolysis temperature of 700 ÂoC, heating rate of 30 ÂoC min-1 and particle size of 91 – 106 I¼m. The calorific value, total ash, density, total acid, moisture content, pH and elemental analysis of bio-oil were determined. Characterisation of the char includes calorific value, surface area, total volume pore and elemental analysis. The gases detected were carbon monoxide, carbon dioxide, methane, ethane and ethylene depending on the pyrolysis temperature.

[1]  W. Tsai,et al.  Fast pyrolysis of rice straw, sugarcane bagasse and coconut shell in an induction-heating reactor , 2006 .

[2]  A. Pütün,et al.  Fast pyrolysis of soybean cake: product yields and compositions. , 2006, Bioresource technology.

[3]  S. Şensöz,et al.  Influence of particle size on the pyrolysis of rapeseed (Brassica napus L.) , 2000 .

[4]  J. F. González,et al.  Fixed-bed pyrolysis of Cynara cardunculus L. Product yields and compositions , 2000 .

[5]  H. F. Gerçel,et al.  The production and evaluation of bio-oils from the pyrolysis of sunflower-oil cake , 2002 .

[6]  Rong Yan,et al.  Mechanism of Palm Oil Waste Pyrolysis in a Packed Bed , 2006 .

[7]  M. Asadullah,et al.  Jute stick pyrolysis for bio-oil production in fluidized bed reactor. , 2008, Bioresource technology.

[8]  A. Lua,et al.  Characterization of chars pyrolyzed from oil palm stones for the preparation of activated carbons , 1998 .

[9]  C. Acikgoz,et al.  Flash pyrolysis of linseed (Linum usitatissimum L.) for production of liquid fuels , 2007 .

[10]  R. Z. Vigouroux PYROLYSIS OF BIOMASS ∞ Rapid Pyrolysis at High Temperature ∞ Slow Pyrolysis for Active Carbon Preparation , 2001 .

[11]  Ayşe Eren Pütün,et al.  Bio-oil production from pyrolysis and steam pyrolysis of soybean-cake: product yields and composition , 2002 .

[12]  Damon Honnery,et al.  Combustion properties of slow pyrolysis bio-oil produced from indigenous Australian species , 2006 .

[13]  G. Staudinger,et al.  Effects of particle size, heating rate and pressure on measurement of pyrolysis kinetics by thermogravimetric analysis , 1997 .

[14]  Paul T. Williams,et al.  Influence of temperature on the products from the flash pyrolysis of biomass , 1996 .

[15]  K. Sjöström,et al.  Reactivity of char from pyrolysis of birch wood , 1997 .

[16]  B. Ahring,et al.  Ethanol Potential for Empty Fruit Bunches Pre-treated by Wet-Explosion , 2005 .

[17]  Filiz Karaosmanoglu,et al.  Biofuel production using slow pyrolysis of the straw and stalk of the rapeseed plant , 1999 .

[18]  H. F. Gerçel Production and characterization of pyrolysis liquids from sunflower-pressed bagasse. , 2002, Bioresource technology.

[19]  B. Ghosh,et al.  Physical and thermochemical characterization of rice husk char as a potential biomass energy source. , 2006, Bioresource technology.

[20]  S. Şensöz,et al.  Characterization of the pyrolysis oil produced in the slow pyrolysis of sunflower-extracted bagasse , 2001 .

[21]  Anthony V. Bridgwater,et al.  A Review of Biomass Pyrolysis and Pyrolysis Technologies , 1991 .

[22]  Ö. Onay,et al.  Fast pyrolysis of rape seed in a well-swept fixed-bed reactor , 2001 .

[23]  Li-bin Wu,et al.  Analysis and upgrading of bio-petroleum from biomass by direct deoxy-liquefaction , 2008 .

[24]  Zheng Jilu,et al.  Bio-oil from fast pyrolysis of rice husk: Yields and related properties and improvement of the pyrolysis system , 2007 .

[25]  M. Islam,et al.  Pyrolytic oil from fixed bed pyrolysis of municipal solid waste and its characterization , 2005 .

[26]  Paul T. Williams,et al.  The influence of temperature and heating rate on the slow pyrolysis of biomass , 1996 .

[27]  W. Tsai,et al.  Fast pyrolysis of rice husk: Product yields and compositions. , 2007, Bioresource technology.

[28]  Jean-Pierre Caliman,et al.  STUDY OF MINERAL NUTRIENT LOSSES FROM OIL PALM EMPTY FRUIT BUNCHES DURING TEMPORARY STORAGE , 2004 .

[29]  A. Pütün,et al.  Slow pyrolysis of pistachio shell , 2007 .

[30]  Mohamad Azri Sukiran,et al.  Bio-oils from Pyrolysis of Oil Palm Empty Fruit Bunches , 2009 .

[31]  A. Pütün,et al.  Comparative analysis of pyrolysis oils and its subfractions under different atmospheric conditions , 2006 .

[32]  S. Şensöz,et al.  Flash pyrolysis of sunflower oil cake for production of liquid fuels , 2001 .

[33]  M. Hajaligol,et al.  Characterization of chars from pyrolysis of lignin , 2004 .

[34]  Ö. Onay Influence of pyrolysis temperature and heating rate on the production of bio-oil and char from safflower seed by pyrolysis, using a well-swept fixed-bed reactor , 2007 .

[35]  Mohamad Azri Sukiran,et al.  Bio-oils from Pyrolysis of Oil Palm Empty Fruit Bunches , 2009 .

[36]  Filiz Karaosmanoglu,et al.  Production and characterization of bio-oil and biochar from rapeseed cake , 2004 .

[37]  S. Şensöz Slow pyrolysis of wood barks from Pinus brutia Ten. and product compositions. , 2003, Bioresource technology.

[38]  Luís Augusto Barbosa Cortez,et al.  Unidimensional heat transfer analysis of elephant grass and sugar cane bagasse slow pyrolysis in a fixed bed reactor , 2005 .

[39]  C. Seng,et al.  Adsorption of chromium(VI) and nickel(II) ions on acid- and heat-activated deoiled spent bleaching clay , 2001 .

[40]  Başak Burcu Uzun,et al.  Composition of products obtained via fast pyrolysis of olive-oil residue: effect of pyrolysis temperature. , 2007 .

[41]  Zhong-yang Luo,et al.  Biomass pyrolysis/gasification for product gas production: the overall investigation of parametric effects , 2003 .

[42]  D. Mohan,et al.  Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review , 2006 .

[43]  Chun-Zhu Li,et al.  Pyrolysis of a Victorian brown coal and gasification of nascent char in CO2 atmosphere in a wire-mesh reactor , 2004 .

[44]  C. Seng,et al.  Solvent efficiency for oil extraction from spent bleaching clay , 2000 .

[45]  A. Bridgwater,et al.  An overview of fast pyrolysis of biomass , 1999 .

[46]  K. Sjöström,et al.  Rapid pyrolysis of agricultural residues at high temperature , 2002 .

[47]  C. Acikgoz,et al.  Fast pyrolysis of linseed: product yields and compositions , 2004 .