Bioinspired, Multidisciplinary, Iterative Catalyst Design Creates the Highest Performance Peroxidase Mimics and the Field of Sustainable Ultradilute Oxidation Catalysis (SUDOC)

Oxidation catalysts called NewTAMLs, macrocyclic complexes with TAML carbonamido-N donors replaced by more nucleophile-resistant binders, sulfonamido-N, for example, [Fe{4-NO2C6H3-1,2-(NCOCMe2NSO2)...

[1]  Howard Hu,et al.  Prenatal fluoride exposure and attention deficit hyperactivity disorder (ADHD) symptoms in children at 6-12 years of age in Mexico City. , 2018, Environment international.

[2]  Longzhu Q. Shen,et al.  Structural, Mechanistic, and Ultradilute Catalysis Portrayal of Substrate Inhibition in the TAML-Hydrogen Peroxide Catalytic Oxidation of the Persistent Drug and Micropollutant, Propranolol. , 2018, Journal of the American Chemical Society.

[3]  B. Glass,et al.  Advanced oxidation process-mediated removal of pharmaceuticals from water: A review. , 2018, Journal of environmental management.

[4]  M. Ehrampoush,et al.  Impact of Drinking Water Fluoride on Human Thyroid Hormones: A Case- Control Study , 2018, Scientific Reports.

[5]  Longzhu Q. Shen,et al.  Iron(III) Ejection from a "Beheaded" TAML Activator: Catalytically Relevant Mechanistic Insight into the Deceleration of Electrophilic Processes by Electron Donors. , 2017, Inorganic chemistry.

[6]  A. Ryabov,et al.  Targeting of High-Valent Iron-TAML Activators at Hydrocarbons and Beyond. , 2017, Chemical reviews.

[7]  R. Gil,et al.  Homogeneous Catalysis Under Ultradilute Conditions: TAML/NaClO Oxidation of Persistent Metaldehyde. , 2017, Journal of the American Chemical Society.

[8]  A. Ryabov,et al.  A "Beheaded" TAML Activator: A Compromised Catalyst that Emphasizes the Linearity between Catalytic Activity and pKa. , 2016, Inorganic chemistry.

[9]  Ana M Soto,et al.  Minireview: Endocrine Disruptors: Past Lessons and Future Directions. , 2016, Molecular endocrinology.

[10]  A. Ryabov,et al.  Unifying Evaluation of the Technical Performances of Iron-Tetra-amido Macrocyclic Ligand Oxidation Catalysts. , 2016, Journal of the American Chemical Society.

[11]  A C Gore,et al.  EDC-2: The Endocrine Society's Second Scientific Statement on Endocrine-Disrupting Chemicals. , 2015, Endocrine reviews.

[12]  Judy Strickland,et al.  A Curated Database of Rodent Uterotrophic Bioactivity , 2015, Environmental health perspectives.

[13]  Longzhu Q. Shen,et al.  Removal of ecotoxicity of 17α-ethinylestradiol using TAML/peroxide water treatment , 2015, Scientific Reports.

[14]  A. Ryabov,et al.  Reactivity and operational stability of N-tailed TAMLs through kinetic studies of the catalyzed oxidation of orange II by H2 O2 : synthesis and X-ray structure of an N-phenyl TAML. , 2015, Chemistry.

[15]  C. Stamm,et al.  Reducing the discharge of micropollutants in the aquatic environment: the benefits of upgrading wastewater treatment plants. , 2014, Environmental science & technology.

[16]  A. Ryabov,et al.  Estimation of rate constants in nonlinear reactions involving chemical inactivation of oxidation catalysts , 2014, Journal of Mathematical Chemistry.

[17]  Robert L. Tanguay,et al.  Zebrafish Assays as Developmental Toxicity Indicators in The Design of TAML Oxidation Catalysts. , 2013, Green chemistry : an international journal and green chemistry resource : GC.

[18]  L. Giudice,et al.  State of the Science of Endocrine Disrupting Chemicals - 2012 , 2012 .

[19]  John P Sumpter,et al.  Predicted‐no‐effect concentrations for the steroid estrogens estrone, 17β‐estradiol, estriol, and 17α‐ethinylestradiol , 2012, Environmental toxicology and chemistry.

[20]  Laura N. Vandenberg,et al.  Hormones and endocrine-disrupting chemicals: low-dose effects and nonmonotonic dose responses. , 2012, Endocrine reviews.

[21]  A. Ryabov,et al.  Designing green oxidation catalysts for purifying environmental waters. , 2010, Journal of the American Chemical Society.

[22]  Brian C. Berry,et al.  Cycloaddition of CO2 to Epoxides Using a Highly Active Co(III) Complex of Tetraamidomacrocyclic Ligand , 2010 .

[23]  A. Ryabov,et al.  Design of more powerful iron-TAML peroxidase enzyme mimics. , 2009, Journal of the American Chemical Society.

[24]  Evan S. Beach,et al.  Activation of Hydrogen Peroxide by an Fe-TAML Complex in Strongly Alkaline Aqueous Solution: Homogeneous Oxidation Catalysis with Industrial Significance , 2009 .

[25]  C. Cramer,et al.  Universal solvation model based on solute electron density and on a continuum model of the solvent defined by the bulk dielectric constant and atomic surface tensions. , 2009, The journal of physical chemistry. B.

[26]  Benjamin D. Stanford,et al.  Pharmaceuticals and endocrine disrupting compounds in U.S. drinking water. , 2009, Environmental science & technology.

[27]  A. Ryabov,et al.  Catalase-peroxidase activity of iron(III)-TAML activators of hydrogen peroxide. , 2008, Journal of the American Chemical Society.

[28]  A. Ryabov,et al.  Mechanistically inspired design of Fe(III)-TAML peroxide-activating catalysts. , 2008, Journal of the American Chemical Society.

[29]  Sushil K. Khetan,et al.  Human pharmaceuticals in the aquatic environment: a challenge to Green Chemistry. , 2007, Chemical reviews.

[30]  Karen A Kidd,et al.  Collapse of a fish population after exposure to a synthetic estrogen , 2007, Proceedings of the National Academy of Sciences.

[31]  A. Ryabov,et al.  Activity-stability parameterization of homogeneous green oxidation catalysts. , 2006, Chemistry.

[32]  R. Schwarzenbach,et al.  The Challenge of Micropollutants in Aquatic Systems , 2006, Science.

[33]  P. Berget,et al.  "Green" oxidation catalysis for rapid deactivation of bacterial spores. , 2006, Angewandte Chemie.

[34]  W. Tsang,et al.  Acyl vs sulfonyl transfer in N-acyl beta-sultams and 3-oxo-beta-sultams. , 2004, Organic letters.

[35]  Duane E. Prasuhn,et al.  Understanding the mechanism of H(+)-induced demetalation as a design strategy for robust iron(III) peroxide-activating catalysts. , 2003, Journal of the American Chemical Society.

[36]  T. J. Collins TAML oxidant activators: a new approach to the activation of hydrogen peroxide for environmentally significant problems. , 2002, Accounts of chemical research.

[37]  Terry Collins,et al.  Toward Sustainable Chemistry , 2001, Science.

[38]  M. Page,et al.  Reactivity and Mechanism in the Hydrolysis of β-Sultams , 2000 .

[39]  T. Ternes,et al.  Pharmaceuticals and personal care products in the environment: agents of subtle change? , 1999, Environmental health perspectives.

[40]  C. P. Horwitz,et al.  Ligand Design Approach for Securing Robust Oxidation Catalysts , 1998 .

[41]  T. J. Collins Designing Ligands for Oxidizing Complexes , 1994 .

[42]  A. Becke Density-functional thermochemistry. III. The role of exact exchange , 1993 .

[43]  D. W. Margerum Metal peptide complexes , 1983 .

[44]  K. Chellappa,et al.  Ligand effects on the thermodynamic stabilization of copper(III)-peptide complexes. , 1977, Journal of the American Chemical Society.

[45]  W. Carmody Easily prepared wide range buffer series , 1963 .

[46]  P. George The chemical nature of the second hydrogen peroxide compound formed by cytochrome c peroxidase and horseradish peroxidase. I. Titration with reducing agents. , 1953, The Biochemical journal.

[47]  T. J. Collins,et al.  Review of the twenty-three year evolution of the first university course in green chemistry: teaching future leaders how to create sustainable societies , 2017 .

[48]  G. B. Buck Louis,et al.  Male Reproductive Disorders and Fertility Trends: Influences of Environment and Genetic Susceptibility. , 2016, Physiological reviews.

[49]  R. Moreira,et al.  Kinetics and mechanism of hydrolysis of N-amidomethylsulfonamides , 2001 .

[50]  J. Sumpter,et al.  Endocrine disruption in wildlife: a critical review of the evidence. , 1998, Critical reviews in toxicology.