Introduction to Brominated Flame Retardants: Commercially Products, Applications, and Physicochemical Properties

In order to meet fire safety regulations, flame retardants (FRs) are applied to combustible materials such as polymers, plastics, wood, paper, and textiles. Approximately, 25% of all FRs contain bromine as the active ingredient. More than 80 different aliphatic, cyclo-aliphatic, aromatic, and polymeric compounds are used as brominated flame retardants (BFRs). BFRs, such as polibrominated biphenyls (PBBs), polybrominated diphenyl ethers (PBDEs), hexabromocyclododecane (HBCD), and tetrabromobisphenol A (TBBPA), have been used in different consumer products in large quantities and consequently they were detected in the environment. In this chapter, an overview of the production, application, and properties of most commonly used BFRs is presented.

[1]  A. Stec,et al.  Polymers and Fire , 2009 .

[2]  Adrian Covaci,et al.  Hexabromocyclododecanes (HBCDs) in the environment and humans: a review. , 2006, Environmental science & technology.

[3]  C. Marvin,et al.  Factors influencing enantiomeric fractions of hexabromocyclododecane measured using liquid chromatography/tandem mass spectrometry. , 2007, Rapid communications in mass spectrometry : RCM.

[4]  Kevin W. George,et al.  Microbial O-methylation of the flame retardant tetrabromobisphenol-A. , 2008, Environmental science & technology.

[5]  H. Neels,et al.  Recent developments in the analysis of brominated flame retardants and brominated natural compounds. , 2007, Journal of chromatography. A.

[6]  Shin-ichi Sakai,et al.  Environmental release and behavior of brominated flame retardants. , 2003, Environment international.

[7]  B. Jansson,et al.  Analysis of tetrabromobisphenol A in a product and environmental samples , 1995 .

[8]  Mohamed Abou-Elwafa Abdallah,et al.  Analytical and environmental aspects of the flame retardant tetrabromobisphenol-A and its derivatives. , 2009, Journal of chromatography. A.

[9]  Kjell Öberg,et al.  Chemical characterization of brominated flame retardants and identification of structurally representative compounds , 2006, Environmental toxicology and chemistry.

[10]  K. Norén,et al.  Analysis of polybrominated diphenyl ethers in Swedish human milk. A time-related trend study, 1972-1997. , 1999, Journal of toxicology and environmental health. Part A.

[11]  Charles A. Wilkie,et al.  Fire retardancy of polymeric materials , 2000 .

[12]  Richard J Wenning,et al.  The significance of brominated flame retardants in the environment: current understanding, issues and challenges. , 2002, Chemosphere.

[13]  C. Marvin,et al.  Refinements to the diastereoisomer-specific method for the analysis of hexabromocyclododecane. , 2005, Rapid communications in mass spectrometry : RCM.

[14]  K. Kay,et al.  Polybrominated biphenyls (PBB) environmental contamination in Michigan, 1973-1976. , 1977, Environmental research.

[15]  Carlo Crescenzi,et al.  Determination of the flame retardant tetrabromobisphenol A in air samples by liquid chromatography-mass spectrometry. , 2006, Journal of chromatography. A.

[16]  E. Pelletier,et al.  LC-ESI-MS-MS method for the analysis of tetrabromobisphenol A in sediment and sewage sludge. , 2004, The Analyst.

[17]  Ǻ. Bergman,et al.  An overview of commercially used brominated flame retardants, their applications, their use patterns in different countries/regions and possible modes of release. , 2003, Environment international.

[18]  D. Barceló,et al.  Identification and trace level determination of brominated flame retardants by liquid chromatography/quadrupole linear ion trap mass spectrometry. , 2008, Rapid communications in mass spectrometry : RCM.

[19]  A. Schecter,et al.  Polybrominated Diphenyl Ethers (PBDEs) and Hexabromocyclodecane (HBCD) in Composite U.S. Food Samples , 2009, Environmental health perspectives.

[20]  Mehran Alaee,et al.  Distribution of hexabromocyclododecane in Detroit River suspended sediments. , 2006, Chemosphere.

[21]  K. Norén,et al.  Certain organochlorine and organobromine contaminants in Swedish human milk in perspective of past 20-30 years. , 2000, Chemosphere.

[22]  P. Darnerud Toxic effects of brominated flame retardants in man and in wildlife. , 2003, Environment international.

[23]  Michael J. Karter,et al.  FIRE LOSS IN THE UNITED STATES 2007 , 2008 .

[24]  A. Covaci,et al.  Hexabromocyclododecane in marine species from the Western Scheldt Estuary: diastereoisomer- and enantiomer-specific accumulation. , 2005, Environmental science & technology.

[25]  C. A. Wit,et al.  Emerging Brominated Flame Retardants in the Environment , 2010 .

[26]  Steven Morris,et al.  Distribution and fate of HBCD and TBBPA brominated flame retardants in North Sea estuaries and aquatic food webs. , 2004, Environmental science & technology.

[27]  Robin J. Law,et al.  Brominated flame retardants in the European chemicals policy of REACH-Regulation and determination in materials. , 2009, Journal of chromatography. A.

[28]  K. Ballschmiter,et al.  Analysis of polychlorinated biphenyls (PCB) by glass capillary gas chromatography , 1980 .

[29]  H. Kay Environmental Health Criteria , 1980 .

[30]  H. Hühnerfuss Chromatographic enantiomer separation of chiral xenobiotics and their metabolites--a versatile tool for process studies in marine and terrestrial ecosystems. , 2000, Chemosphere.

[31]  J. Boer,et al.  Polybrominated Biphenyls and Diphenylethers , 2000 .

[32]  S. Morris,et al.  Levels and trends of HBCD and BDEs in the European and Asian environments, with some information for other BFRs. , 2008, Chemosphere.

[33]  R. Letcher,et al.  Simultaneous determination of tetrabromobisphenol A, tetrachlorobisphenol A, bisphenol A and other halogenated analogues in sediment and sludge by high performance liquid chromatography-electrospray tandem mass spectrometry. , 2005, Journal of chromatography. A.

[34]  Xiaojun Luo,et al.  Spatial distribution and vertical profile of polybrominated diphenyl ethers, tetrabromobisphenol A, and decabromodiphenylethane in river sediment from an industrialized region of South China. , 2009, Environmental pollution.

[35]  Akira Nakajima,et al.  Neurobehavioral effects of tetrabromobisphenol A, a brominated flame retardant, in mice. , 2009, Toxicology letters.

[36]  Jurgen H. Troitzsch,et al.  International Plastics Flammability Handbook: Principles - Regulations - Testing and Approval , 1990 .