Fluorescence spectroscopic analysis of indocyanine green J aggregates in water

Abstract Indocyanine green in water forms J aggregates, which are observed as a red-shifted narrow absorption band at 890 nm. The fluorescence quantum distribution of the indocyanine green J aggregates was studied by continuous wave laser excitation at 834 nm. A fluorescence quantum yield of Ф F ≈ 3 × 10 −4 was measured. The fluorescence peak coincides with the absorption peak (no Stokes shift).

[1]  R. Birge,et al.  Lasing properties of several near-IR dyes for a nitrogen laser-pumped dye laser with an optical amplifier , 1982 .

[2]  A. Penzkofer,et al.  Nanometer particle size, pore size, and specific surface determination of colloidal suspensions and porous glasses by Rayleigh light scattering , 1995 .

[3]  Rosa Weigand,et al.  J-aggregation and disaggregation of indocyanine green in water , 1997 .

[4]  Christoph Abels,et al.  Absorption and Fluorescence Spectroscopic Investigation of Indocyanine Green , 1996 .

[5]  EDWIN E. JELLEY,et al.  Spectral Absorption and Fluorescence of Dyes in the Molecular State , 1936, Nature.

[6]  A. Penzkofer,et al.  PICOSECOND TRANSIENT SPECTRAL HOLE-BURNING STUDIES ON OXAZINE 750 IN A SILICATE XEROGEL , 1995 .

[7]  R. Gadonas,et al.  Annihilation of singlet excitons in J aggregates of pseudoisocyanine (PIC) studied by pico‐ and subpicosecond spectroscopy , 1988 .

[8]  H. Stiel,et al.  J-aggregates of pseudoisocyanine in solution: New data from nonlinear spectroscopy , 1988 .

[9]  Joseph H. Eberly,et al.  Organic Dye Laser Threshold , 1971 .

[10]  W. Blau,et al.  Theoretical analysis of S1-state lifetime measurements of dyes with picosecond laser pulses , 1983 .

[11]  H. Dorn,et al.  Temperature dependence of the fluorescence lifetime and quantum yield of pseudoisocyanine monomers , 1986 .

[12]  A. Herz Aggregation of sensitizing dyes in solution and their adsorption onto silver halides , 1977 .

[13]  A. Penzkofer,et al.  Saturable absorption and absorption recovery of indocyanine green J-aggregates in water , 1998 .

[14]  R. Gadonas,et al.  Picosecond kinetics and transient spectra of pseudoisocyanine monomers and J-aggregates in aqueous solution , 1981 .

[15]  D. Hercules Fluorescence and Phosphorescence Analysis: Principles and Applications , 1966 .

[16]  D. Wiersma,et al.  Optical Dynamics of Exciton and Polaron Formation in Molecular Aggregates , 1989 .

[17]  W. Kaiser,et al.  Ultrafast transient processes of monomers, dimers, and aggregates of pseudoisocyanine chloride (PIC) , 1982 .

[18]  H. Dorn,et al.  Scheibe-aggregates of Pseudoisocyanine in solution and in molecular monolayers , 1987 .

[19]  Makoto Taiji,et al.  Femtosecond nonlinear optical dynamics of excitons in J-aggregates , 1994 .

[20]  G. Kwant,et al.  Light-absorbing properties, stability, and spectral stabilization of indocyanine green. , 1976, Journal of applied physiology.

[21]  E. Knapp Lineshapes of molecular aggregates, exchange narrowing and intersite correlation , 1984 .

[22]  S. J. Strickler,et al.  Relationship between Absorption Intensity and Fluorescence Lifetime of Molecules , 1962 .

[23]  M. Daiber,et al.  Intersystem-Crossing and Excited-State Absorption in Eosin Y Solutions Determined by Picosecond Double Pulse Transient Absorption Measurements , 1992 .

[24]  J. Knoester Nonlinear optical line shapes of disordered molecular aggregates: Motional narrowing and the effect of intersite correlations , 1993 .

[25]  S. Dähne,et al.  Determination of the fluorescence decay time of the I aggregates of pseudoisocyanine , 1977 .

[26]  A. Penzkofer,et al.  Degree of aggregation of indocyanine green in aqueous solutions determined by Mie scattering , 1997 .

[27]  D. Webb,et al.  Photoluminescence of solutions , 1969 .

[28]  R. Gagel,et al.  Evidence for biexcitons and dynamic Stark effect in J-aggregates from femtosecond spectroscopy , 1994 .

[29]  M. Landthaler,et al.  Abels, W. Bäumler, Quantum Yield of Triplet Formation for Indocyanine Green, , 1997 .

[30]  H. Fromherz Münchener Chemische Gesellschaft , 1937 .

[31]  J. Lakowicz Principles of fluorescence spectroscopy , 1983 .

[32]  H. V. Hulst Light Scattering by Small Particles , 1957 .