Litchi chinensis peel biomass as green adsorbent for cadmium (Cd) ions removal from aqueous solutions

An intensive research of the use of waste biomass for water remediation has led to the exploration of novel founts of these materials. One example is Litchi chinensis peels. This work describes the use of Litchi peels biowaste for the effective removal of Cadmium(II) ions and the influence of environmental variables like pH, sorbent dose, concentration of sorbate and physico-chemical treatments on Cd(II) adsorption capacity. The optimum experimental conditions for the maximum metal uptake were based on pH 5, particle size 43 μm and a contact time of 60 min. Cd(II) sorption data fitted well to pseudo-second-order kinetic model and Freundlich adsorption isotherms model. According to Freundlich adsorption isotherm the qmax was found to be 15.27 mg/g. Fourier-transforms infrared spectroscopic analysis of waste biomass exposed the presence of various alkane, alcohol, amines, and oxygen bound groups. The results of this study revealed that Litchi waste biomass is a promising, inexpensive and eco-friendly bio-material that can easily be used for removing high levels of Cd ions from wastewater.

[1]  Chunping Yang,et al.  Effects of Pretreatment Methods of Wheat Straw on Adsorption of Cd(II) from Waterlogged Paddy Soil , 2019, International journal of environmental research and public health.

[2]  Peter Åkerbäck,et al.  DIN , 2019, Springer Reference Medizin.

[3]  T. Jin,et al.  The references level of cadmium intake for renal dysfunction in a Chinese population , 2018, Scientific Reports.

[4]  M. Nishijo,et al.  Bone Fracture Risk and Renal Dysfunction in a Highly Cadmium Exposed Thai Population , 2018, Journal of research in health sciences.

[5]  H. Nakagawa,et al.  Cancer Mortality in Residents of the Cadmium-Polluted Jinzu River Basin in Toyama, Japan , 2018, Toxics.

[6]  M. Nishijo,et al.  615 Bone metabolism abnormality and renal dysfunction in cadmium exposed farmer from thailand , 2018 .

[7]  X. J. Chen,et al.  Biosorption of Cd(II) from synthetic wastewater using dry biofilms from biotrickling filters , 2018, International Journal of Environmental Science and Technology.

[8]  F. Pagnanelli,et al.  Biosorption of toxic metals: Effect of pH, reversibility and comparison with a kaolin as adsorbent material , 2017 .

[9]  H. Nakagawa,et al.  Effects of aging on cadmium concentrations and renal dysfunction in inhabitants in cadmium‐polluted regions in Japan , 2017, Journal of applied toxicology : JAT.

[10]  Jinhuai Liu,et al.  Removal of cadmium and lead ions from water by sulfonated magnetic nanoparticle adsorbents. , 2017, Journal of colloid and interface science.

[11]  M. Awasthi,et al.  Spatial distribution and risk assessment of heavy metals in soil near a Pb/Zn smelter in Feng County, China. , 2017, Ecotoxicology and environmental safety.

[12]  J. Zuo,et al.  Performance and mechanism for cadmium and lead adsorption from water and soil by corn straw biochar , 2017, Frontiers of Environmental Science & Engineering.

[13]  Z. Aksu,et al.  Cationic surfactant-modified biosorption of anionic dyes by dried Rhizopus arrhizus , 2017, Environmental technology.

[14]  S. Rezania,et al.  Comprehensive review on phytotechnology: Heavy metals removal by diverse aquatic plants species from wastewater. , 2016, Journal of hazardous materials.

[15]  H. Rezaei Biosorption of chromium by using Spirulina sp. , 2016 .

[16]  M. Lloréns,et al.  Biosorption of cadmium (II) from aqueous solutions by natural and modified non-living leaves of Posidonia oceanica , 2016, Environmental Science and Pollution Research.

[17]  G. Zeng,et al.  Biosorption of Pb(II) Ions from Aqueous Solutions by Waste Biomass from Biotrickling Filters: Kinetics, Isotherms, and Thermodynamics , 2016 .

[18]  S. Cravo,et al.  Fluoroquinolones biosorption onto microbial biomass: activated sludge and aerobic granular sludge , 2016 .

[19]  M. Komárek,et al.  Lead and cadmium sorption mechanisms on magnetically modified biochars. , 2016, Bioresource technology.

[20]  K. Prasad,et al.  Structure identification of a polysaccharide purified from litchi (Litchi chinensis Sonn.) pulp. , 2016, Carbohydrate polymers.

[21]  N. Bhardwaj,et al.  Some Hazardous Effects of Cadmium on Human Health: a Short Review , 2016, International Journal of Advance Research and Innovation.

[22]  G. Mohamed,et al.  Litchi chinensis: medicinal uses, phytochemistry, and pharmacology. , 2015, Journal of ethnopharmacology.

[23]  Fadzlin Md Sairan,et al.  Perspectives of phytoremediation using water hyacinth for removal of heavy metals, organic and inorganic pollutants in wastewater. , 2015, Journal of environmental management.

[24]  G. Kyzas,et al.  Progress in batch biosorption of heavy metals onto algae , 2015 .

[25]  T. M. Zewail,et al.  Kinetic study of heavy metal ions removal by ion exchange in batch conical air spouted bed , 2015 .

[26]  S. Dampare,et al.  Source apportionment and pollution evaluation of heavy metals in water and sediments of Buriganga River, Bangladesh, using multivariate analysis and pollution evaluation indices , 2014, Environmental Monitoring and Assessment.

[27]  J. Dhote,et al.  REVIEW OF HEAVY METALS IN DRINKING WATER AND THEIR EFFECT ON HUMAN HEALTH , 2013 .

[28]  A. Nayak,et al.  Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles , 2012 .

[29]  L. Benbrahim-Tallaa,et al.  Metal ions in human cancer development. , 2011, Metal ions in life sciences.

[30]  Jiaqiang Wang,et al.  Biosorption of zinc(II) from aqueous solution by dried activated sludge. , 2010, Journal of environmental sciences.

[31]  Can Chen,et al.  Biosorbents for heavy metals removal and their future. , 2009, Biotechnology advances.

[32]  M. Hanif,et al.  Polypogon monspeliensis waste biomass: A potential biosorbent for Cd (II) , 2009 .

[33]  W. Ngah,et al.  Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: a review. , 2008, Bioresource technology.

[34]  Can Chen,et al.  Biosorption of heavy metals by Saccharomyces cerevisiae: a review. , 2006, Biotechnology advances.

[35]  M. Waalkes Cadmium carcinogenesis in review. , 2000, Journal of inorganic biochemistry.

[36]  Suess Examination of water for pollution control: A reference handbook. Sampling, data analysis and laboratory equipment , 1982 .