Lightweight Magnesium Bipolar Plates of Direct NaBH4/H2O2 Fuel Cell for AIP Application

Abstract Fuel cell based power systems have high energy density. However, using H2 gas as fuel and O2 as oxidizer in aerospace, UAV or underwater like an AIP (Air Independent Propulsion) environment has restrictions in terms of efficient storage. The direct borohydride hydrogen peroxide fuel cell (DBPFC) which uses aqueous NaBH4 solution as fuel and H2O2 solution as oxidizer has great advantages over the H2/O2 fuel cell in terms of storage efficiency, energy density and power density. These excellent characteristics make the DBPFC an appropriate power source and propulsion system for AIP systems. In this study, lightweight magnesium bipolar plates for DBPFC has been fabricated and evaluated for application in unmanned underwater vehicles. Although magnesium has many favorable properties such as lightweight, high electric conductivity and machinability, low corrosion resistance restricted its use as a bipolar plate. Corrosion resistive metal, Au electroplated magnesium bipolar plates exhibited the highest power density and the promising candidate for future aerospace, UAV and underwater propulsion systems.

[1]  K. Scott,et al.  Influence of operation conditions on direct borohydride fuel cell performance , 2006 .

[2]  Frank Holcomb,et al.  Engineering of the bipolar stack of a direct NaBH4 fuel cell , 2008 .

[3]  Jung-Ho Wee,et al.  Applications of proton exchange membrane fuel cell systems , 2007 .

[4]  M. Kimble,et al.  Development of Corrosion-Resistant Coatings for Fuel Cell Bipolar Plates , 1999 .

[5]  G. Jackson,et al.  Modeling the performance of an ideal NaBH 4 –H 2 O 2 direct borohydride fuel cell , 2014 .

[6]  Yunfeng Song,et al.  Carbon supported palladium hollow nanospheres as anode catalysts for direct borohydride-hydrogen peroxide fuel cells , 2012 .

[7]  H. I. Sarac,et al.  Effects of operation conditions on direct borohydride fuel cell performance , 2008 .

[8]  A. Shukla,et al.  A 28-W portable direct borohydride–hydrogen peroxide fuel-cell stack , 2006 .

[9]  C. Arges,et al.  Bipolar polymer electrolyte interfaces for hydrogen–oxygen and direct borohydride fuel cells , 2014 .

[10]  Sejin Kwon,et al.  Evaluation of Silver-coated Magnesium Bipolar Plate for Lightweight PEM Fuel Cell Stack , 2014 .

[11]  George H. Miley,et al.  Cathode electrocatalyst selection and deposition for a direct borohydride/hydrogen peroxide fuel cell , 2007 .

[12]  Guiling Wang,et al.  A direct NaBH4-H2O2 fuel cell using Ni foam supported Au nanoparticles as electrodes , 2010 .

[13]  Heli Wang,et al.  Stainless steel as bipolar plate material for polymer electrolyte membrane fuel cells , 2003 .

[14]  R. Buchheit,et al.  Direct borohydride fuel cell using Ni-based composite anodes , 2010 .

[15]  Rodney L. Burton,et al.  NaBH4/H2O2 fuel cells for air independent power systems , 2008 .

[16]  L. Zhixiang,et al.  Influence of operation conditions on direct NaBH4/H2O2 fuel cell performance , 2010 .

[17]  Sejin Kwon,et al.  Effect of heat treatment of electrodes on direct borohydride-hydrogen peroxide fuel cell performance , 2014 .

[18]  D. Mahajan,et al.  Metal bipolar plates for PEM fuel cell—A review , 2007 .

[19]  A. K. Shukla,et al.  An alkaline direct borohydride fuel cell with hydrogen peroxide as oxidant , 2005 .

[20]  César A.C. Sequeira,et al.  Direct borohydride/peroxide fuel cells using Prussian Blue cathodes , 2012 .

[21]  Ying Wang,et al.  Carbon-Supported Au Hollow Nanospheres as Anode Catalysts for Direct Borohydride−Hydrogen Peroxide Fuel Cells , 2009 .

[22]  R. A. Antunes,et al.  Corrosion of metal bipolar plates for PEM fuel cells: A review , 2010 .

[23]  Jenn-Jiang Hwang,et al.  Development of a lightweight fuel cell vehicle , 2005 .

[24]  Sejin Kwon,et al.  Electrocatalysts supported on multiwalled carbon nanotubes for direct borohydride–hydrogen peroxide fuel cell , 2014 .

[25]  C. Ponce de León,et al.  Direct borohydride fuel cells , 2006 .

[26]  D. Ross,et al.  Hydrogen storage: The major technological barrier to the development of hydrogen fuel cell cars , 2006 .

[27]  David L. Carroll,et al.  Direct NaBH4/H2O2 fuel cells , 2007 .

[28]  A. Shukla,et al.  A Direct Borohydride/Hydrogen Peroxide Fuel Cell with Reduced Alkali Crossover , 2007 .