A study of surface changes of wood-polypropylene composites as the result of exterior weathering

Outdoor applications of composites raised questions about their durability. In this study, the effects of outdoor weathering on the properties of wood-polypropylene composites with and without pigments were examined. The composites were placed outdoors for one year, and their colour changes were evaluated after 1, 3, 6, 9 and 12 months of weathering. The weathering resulted in considerable colour fading of the composites. Composites containing darker colour pigments had better colour stability. Scanning electron microscopy analysis revealed that surface cracks caused by weathering in a wood-polypropylene composite having a higher polypropylene content were less abundant, and the deterioration of the surface layer was lower compared to composites containing less polymer. Measurements of melting temperatures by differential scanning calorimetry gave a consistent picture of polypropylene degradation in the surface layer. After weathering, a decrease in Charpy impact strength was found for composites characterised by higher moisture absorption.

[1]  Mohini Sain,et al.  The efficacy of photostabilizers on the color change of wood filled plastic composites , 2006 .

[2]  P. D. Evans,et al.  Degradation of wood surfaces during natural weathering. Effects on lignin and cellulose and on the adhesion of acrylic latex primers , 1996, Wood Science and Technology.

[3]  H. Kaczmarek,et al.  Effect of short wavelength UV-irradiation on ageing of polypropylene/cellulose compositions , 2005 .

[4]  D. Hon,et al.  Surface degradation of wood by ultraviolet light , 1984 .

[5]  M. Beg,et al.  Accelerated weathering of unbleached and bleached Kraft wood fibre reinforced polypropylene composites , 2008 .

[6]  Diène Ndiaye,et al.  Durability of wood polymer composites: Part 1. Influence of wood on the photochemical properties , 2008 .

[7]  R. Rowell,et al.  Weathering Performance of Plant-Fiber/Thermoplastic Composites , 2000 .

[8]  J. R. White,et al.  Photodegradation of talc-filled polypropylene , 1996 .

[9]  J. R. White,et al.  Crystallization and melting behaviour of photodegraded polypropylene — II. Re-crystallization of degraded molecules , 1997 .

[10]  T. Kärki,et al.  Physical and Mechanical Properties of Wood-Polypropylene Composites Made with Virgin and/or Recycled Polypropylene , 2011 .

[11]  Uwe Müller,et al.  Yellowing and IR-changes of spruce wood as result of UV-irradiation. , 2003, Journal of photochemistry and photobiology. B, Biology.

[12]  D. Hon,et al.  Weathering characteristics of hardwood surfaces , 1986, Wood Science and Technology.

[13]  R. Långström,et al.  UV aging of poly(propylene)/wood‐fiber composites , 2004 .

[14]  W. Cantwell,et al.  The influence of moisture on the mechanical properties of wood polymer composites , 2006 .

[15]  K. Pandey A study of chemical structure of soft and hardwood and wood polymers by FTIR spectroscopy , 1999 .

[16]  P. Evans,et al.  Studies of the degradation and protection of wood surfaces , 2004, Wood Science and Technology.

[17]  K. Pandey,et al.  Study of the effect of photo-irradiation on the surface chemistry of wood , 2005 .

[18]  T. Kärki,et al.  Effects of water immersion‐freeze‐thaw cycling on the properties of wood‐polypropylene composites containing pigments , 2011 .

[19]  L. Matuana,et al.  Ultraviolet weathering of photostabilized wood-flour-filled high-density polyethylene composites†‡ , 2003 .

[20]  B. Dawson-Andoh,et al.  Colorimetric and vibrational spectroscopic characterization of weathered surfaces of wood and rigid polyvinyl chloride–wood flour composite lumber , 2009, Wood Science and Technology.

[21]  A. Pitman,et al.  FTIR studies of the changes in wood chemistry following decay by brown-rot and white-rot fungi , 2003 .

[22]  C. Sinturel,et al.  Influence of the exposure parameters on the mechanism of photooxidation of polypropylene , 1999 .

[23]  M. Wolcott,et al.  Wood plastic composites weathering: Visual appearance and chemical changes , 2008 .

[24]  F. Mantia,et al.  Accelerated weathering of polypropylene/wood flour composites , 2008 .

[25]  Laurent M. Matuana,et al.  Characterization of weathered wood–plastic composite surfaces using FTIR spectroscopy, contact angle, and XPS ☆ , 2007 .

[26]  N. Stark Effect of weathering cycle and manufacturing method on performance of wood flour and high-density polyethylene composites†‡ , 2006 .

[27]  A. Klyosov Water Absorption by Composite Materials and Related Effects , 2007 .

[28]  L. Matuana,et al.  Surface chemistry and mechanical property changes of wood-flour/high-density-polyethylene composites after accelerated weathering , 2004 .

[29]  L. Matuana,et al.  Effect of processing method on surface and weathering characteristics of wood–flour/HDPE composites , 2004 .

[30]  X. Colom,et al.  FTIR and DSC study of HDPE structural changes and mechanical properties variation when exposed to weathering aging during Canadian winter , 1996 .

[31]  D. Hon,et al.  Wood and Cellulosic Chemistry , 1990 .

[32]  P. Garriga,et al.  Structural analysis of photodegraded wood by means of FTIR spectroscopy , 2003 .

[33]  Koichi Yamamoto,et al.  Surface deterioration of wood-flour polypropylene composites by weathering trials , 2007, Journal of Wood Science.

[34]  J. R. White,et al.  Crystallization and melting behaviour of photodegraded polypropylene — I. Chemi-crystallization , 1997 .

[35]  Mohini Sain,et al.  Interface Modification and Mechanical Properties of Natural Fiber-Polyolefin Composite Products , 2005 .