Exceptional electromagnetic interference shielding properties of ferromagnetic microwires enabled polymer composites

We present systematic studies of the electromagnetic interference (EMI) shielding and microwave properties of a new class of shielding material, i.e., the ferromagnetic microwires-embedded polymer composites. We show that at 1–2 GHz the shielding effectiveness (SE) of the continuous-wire composite reaches a high value of 18 dB (98.4% attenuation) for a very low filler loading of 0.024% and a thickness of 0.64 mm. The normalized SE of this new composite is about 70 times higher than that of the bucky paper-based composite and is two to four orders of magnitude higher than those of other shielding candidate materials. Complex permeability, permittivity, and impedance experiments reveal that the absorption of electromagnetic radiation is a dominant mechanism for EMI shielding of the studied composites. The advantages of high shielding efficiency, good physical integrity, low fabrication costs, and multifunctionalities make them an attractive candidate material for a variety of technological applications.

[1]  V. N. Murray Progress in ferromagnetism research , 2006 .

[2]  F. Qin,et al.  Influence of varying metal-to-glass ratio on GMI effect in Co70.3Fe3.7B10Si13Cr3 amorphous glass-coated microwires , 2010 .

[3]  Changxin Chen,et al.  Electrical conductivity and electromagnetic interference shielding characteristics of multiwalled carbon nanotube filled polyacrylate composite films , 2008 .

[4]  M. A. Stuchly,et al.  Health effects of exposure to electromagnetic fields , 1995, 1995 IEEE Aerospace Applications Conference. Proceedings.

[5]  H. Rahman,et al.  Application of frequency sensitive surfaces in electromagnetic shielding , 1995 .

[6]  Michael R Wisnom,et al.  Large enhancement of GMI effect in polymer composites containing Co-based ferromagnetic microwires , 2007 .

[7]  D.D.L. Chung,et al.  Electrically conducting powder filled polyimidesiloxane , 1991 .

[8]  S. Tzeng,et al.  EMI shielding effectiveness of metal-coated carbon fiber-reinforced ABS composites , 2001 .

[9]  Liu Shunhua,et al.  Investigation of electrical conductivity and electromagnetic shielding effectiveness of polyaniline composite , 2005 .

[10]  S. Dhawan,et al.  Shielding behaviour of conducting polymer-coated fabrics in X-band, W-band and radio frequency range , 2002 .

[11]  S. Chen,et al.  Optimum injection molding processing condition on EMI shielding effectiveness of stainless steel fiber filled polycarbonate composite , 2008 .

[12]  D. P. Makhnovskiy,et al.  Tunable and Self-Sensing Microwave Composite Materials Incorporating Ferromagnetic Microwires , 2008 .

[13]  L. V. Panina,et al.  Magneto‐impedance effect in amorphous wires , 1994 .

[14]  Valentina Zhukova,et al.  Novel magnetic microwires-embedded composites for structural health monitoring applications , 2010 .

[15]  Qing Chen,et al.  Microwave Absorption Enhancement and Complex Permittivity and Permeability of Fe Encapsulated within Carbon Nanotubes , 2004 .

[16]  P. B. Jana,et al.  Effects of sample thickness and fiber aspect ratio on EMI shielding effectiveness of carbon fiber filled polychloroprene composites in the X-band frequency range , 1992 .

[17]  Vellar C. Plantz,et al.  Shielding theory and practice , 1988 .

[18]  Huy-Zu Cheng,et al.  The electromagnetic shielding effectiveness of carbon nanotubes polymer composites , 2007 .

[19]  Yutaka Shimada,et al.  Permeability and electromagnetic-interference characteristics of Fe–Si–Al alloy flakes–polymer composite , 1999 .

[20]  Hua-Xin Peng,et al.  Giant magnetoimpedance materials: Fundamentals and applications , 2008 .

[21]  J. Joo,et al.  EMI shielding intrinsically conducting polymer/PET textile composites , 2003 .

[22]  X. Tong Advanced Materials and Design for Electromagnetic Interference Shielding , 2008 .

[23]  D. Chung Electromagnetic interference shielding effectiveness of carbon materials , 2001 .

[24]  D. C. Trivedi,et al.  EMI shielding: Methods and materials—A review , 2009 .

[25]  Chunyi Zhi,et al.  Fabrication and microwave absorption of carbon nanotubes/CoFe2O4 spinel nanocomposite , 2006 .

[26]  Valentina Zhukova,et al.  Recent advances in studies of magnetically soft amorphous microwires , 2009 .

[27]  Mihail Ipatov,et al.  Co-based magnetic microwire and field-tunable multifunctional macro-composites , 2009 .

[28]  L. V. Panina,et al.  Preparation and properties of glass-coated microwires , 2002 .

[29]  Jan-Chan Huang,et al.  EMI shielding plastics: A review , 1995 .

[30]  Yang Shen,et al.  Enhanced microwave absorption in nickel/hexagonal-ferrite/polymer composites , 2006 .

[31]  J. Joo,et al.  Charge transport properties of composites of multiwalled carbon nanotube with metal catalyst and polymer: application to electromagnetic interference shielding ☆ , 2004 .

[32]  Chuck Zhang,et al.  Electromagnetic interference shielding properties of carbon nanotube buckypaper composites , 2009, Nanotechnology.

[33]  S. K. Dhawan,et al.  Electromagnetic shielding behaviour of conducting polyaniline composites , 2003 .

[34]  Dusan A. Pejakovic,et al.  Electrical conductivity and electromagnetic interference shielding of multiwalled carbon nanotube composites containing Fe catalyst , 2004 .

[35]  Christopher J. von Klemperer,et al.  Composite electromagnetic interference shielding materials for aerospace applications , 2009 .

[36]  W. Weir Automatic measurement of complex dielectric constant and permeability at microwave frequencies , 1974 .

[37]  S. Ramo,et al.  Fields and Waves in Communication Electronics , 1966 .

[38]  D. Chung,et al.  Electromagnetic interference shielding using continuous carbon-fiber carbon-matrix and polymer-matrix composites , 1999 .

[39]  G. F. Taylor A Method of Drawing Metallic Filaments and a Discussion of their Properties and Uses , 1924 .

[40]  L. Deng,et al.  Microwave absorbing performances of multiwalled carbon nanotube composites with negative permeability , 2007 .

[41]  Chi-Yuan Huang,et al.  Studies on the influence of double-layer electroless metal deposition on the electromagnetic interference shielding effectiveness of carbon fiber/ ABS composites , 2004 .