Wastewater Treatment and Reclamation: A Review of Pulp and Paper Industry Practices and Opportunities

The pulp and paper (P&P) industry worldwide has achieved substantial progress in treating both process water and wastewater, thus limiting the discharge of pollutants to receiving waters. This review covers a variety of wastewater treatment methods, which provide P&P companies with cost-effective ways to limit the release of biological or chemical oxygen demand, toxicity, solids, color, and other indicators of pollutant load. Conventional wastewater treatment systems, often comprising primary clarification followed by activated sludge processes, have been widely implemented in the P&P industry. Higher levels of pollutant removal can be achieved by supplementary treatments, which can include anaerobic biological stages, advanced oxidation processes, bioreactors, and membrane filtration technologies. Improvements in the performance of wastewater treatment operations often can be achieved by effective measurement technologies and by strategic addition of agents including coagulants, flocculants, filter aids, and optimized fungal or bacterial cultures. In addition, P&P mills can implement upstream process changes, including dissolved-air-flotation (DAF) systems, filtration save-alls, and kidney-like operations to purify process waters, thus reducing the load of pollutants and the volume of effluent being discharged to end-of-pipe wastewater treatment plants.

[1]  K. Vice,et al.  EPA announces framework for cluster rule effluent limitations guidelines , 1996 .

[2]  Deepa K Tiku,et al.  Effectiveness of Treatment Technologies for Wastewater Pollution Generated by Indian Pulp Mills , 2007, Environmental monitoring and assessment.

[3]  M. Hunsom,et al.  Treatment of wastewater from pulp and paper mill industry by electrochemical methods in membrane reactor. , 2012, Journal of environmental management.

[4]  N. Kishimoto,et al.  Treatment of paper and pulp mill wastewater by ozonation combined with electrolysis. , 2010 .

[5]  I. Thakur.  Structural and functional characterization of a stable, 4-chlorosalicylic-acid-degrading, bacterial community in a chemostat , 1995, World journal of microbiology & biotechnology.

[6]  A. Lensu,et al.  Dissolution and spatial distribution of resin acids and retene in sediments contaminated by pulp and paper industry , 2010 .

[7]  P. Hodson,et al.  Effect of tertiary coagulation and flocculation treatment on effluent quality from a bleached kraft mill , 1998 .

[8]  Huijuan Liu,et al.  Role of aluminum speciation in the removal of disinfection byproduct precursors by a coagulation process. , 2008, Environmental science & technology.

[9]  G. Lyberatos,et al.  Biological phenol removal using suspended growth and packed bed reactors , 2005 .

[10]  B. Moodley,et al.  The electro-oxidation of lignin in Sappi Saiccor dissolving pulp mill effluent , 2011 .

[11]  M. Umamaheswari.  BIOETHANOL PRODUCTION FROM CELLULOSIC MATERIALS , 2010 .

[12]  A. Ragauskas,et al.  Lignin Structural Alterations in Thermochemical Pretreatments with Limited Delignification , 2015, BioEnergy Research.

[13]  Theodore J. Heindel,et al.  Fundamentals of flotation deinking , 1997 .

[14]  John P. Wilson,et al.  Clarifier Design Concept—Larger is Better , 1997 .

[15]  S. Dentel,et al.  Using Streaming Current Detectors in Water Treatment , 1989 .

[16]  M. Ikonomou,et al.  Assessment of chlorinated dibenzo-p-dioxin and dibenzofuran trends in sediment and crab hepatopancreas from pulp mill and harbor sites using multivariate- and index-based approaches. , 2002, Environmental science & technology.

[17]  R. Alén,et al.  Organic materials in black liquors of soda-AQ pulping of hot-water-extracted birch (Betula pendula) sawdust , 2015 .

[18]  S. Sinkkonen.  PCDTs in the environment , 1997 .

[19]  L. Mina,et al.  Cationic starch in the wet end: its contribution to interfibre bonding , 1994 .

[20]  John Gregory,et al.  Rates of flocculation of latex particles by cationic polymers , 1973 .

[21]  R. Miranda,et al.  Separation of Contaminants from Deinking Process Water by Dissolved Air Flotation: Effect of Flocculant Charge Density , 2008 .

[22]  C. D. Cox,et al.  Polyelectrolyte selection for water treatment , 1985 .

[23]  G. Waghorn,et al.  Greenhouse gas emissions. , 2008 .

[24]  G. Park.  Synthetic polymer membranes , 1972 .

[25]  J. Kennedy,et al.  Continuous biobleaching of black liquor from the pulp and paper industry using an immobilized cell system , 1998 .

[26]  J. Kallas,et al.  Membrane filtration and ozone treatment of biologically treated effluents from the pulp and paper industry , 2008 .

[27]  Jun Wang,et al.  Impact of Optimized Flow Pattern on Pollutant Removal and Biogas Production Rate Using Wastewater Anaerobic Fermentation , 2015 .

[28]  M. Hubbe,et al.  CELLULOSIC SUBSTRATES FOR REMOVAL OF POLLUTANTS FROM AQUEOUS SYSTEMS: A REVIEW. 2. DYES , 2011 .

[29]  J. Turrens,et al.  Mitochondrial formation of reactive oxygen species , 2003, The Journal of physiology.

[30]  A. Jafari,et al.  Application of Response Surface Methodology for , 2012 .

[31]  D. Wise,et al.  An intergrated waste survey and environmental effects of COGIDO, a bleached pulp and paper mill in Vietnam, on the receiving waterbody , 1996 .

[32]  J. Field,et al.  Acute and sub-acute toxicity of bark tannins in carp (Cyprinus carpio L.). , 1989 .

[33]  Turan Yilmaz,et al.  A comparison of the performance of mesophilic and thermophilic anaerobic filters treating papermill wastewater. , 2008, Bioresource technology.

[34]  Deepa K Tiku,et al.  Holistic bioremediation of pulp mill effluents using autochthonous bacteria. , 2010 .

[35]  T. Tuhkanen,et al.  Ozonation of Pulp Mill Effluent Prior to Activated Sludge Treatment , 1997 .

[36]  H. Kawaguchi.  Photolysis of 2-chlorophenol in natural waters , 1992 .

[37]  R. C. Howard,et al.  The effect of cationic starch on the tensile strength of paper , 1989 .

[38]  Olanrewaju Sanusi,et al.  Pulp and Paper Mill Effluents Management , 2009 .

[39]  Á. Blanco,et al.  Comparison of different wastewater treatments for removal of selected endocrine-disruptors from paper mill wastewaters , 2012, Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering.

[40]  Aniruddha B. Pandit,et al.  A review of imperative technologies for wastewater treatment II: hybrid methods , 2004 .

[41]  A. Schecter,et al.  Levels of dioxins, dibenzofurans and other chlorinated xenobiotics in human milk from the Soviet Union , 1990 .

[42]  A. Gürses,et al.  The removal of lignin and phenol from paper mill effluents by electrocoagulation. , 2008, Journal of environmental management.

[43]  C. Negro,et al.  Optimization of Pitch Removal by Dissolved Air Flotation in a Eucalyptus Kraft Mill , 2005 .

[44]  Noemí Merayo,et al.  Assessing the application of advanced oxidation processes, and their combination with biological treatment, to effluents from pulp and paper industry. , 2013, Journal of hazardous materials.

[45]  S. Wong,et al.  Optimization of coagulation-flocculation process for pulp and paper mill effluent by response surface methodological analysis. , 2007, Journal of hazardous materials.

[46]  T. Lundell,et al.  Novel thermotolerant laccases produced by the white-rot fungus Physisporinus rivulosus , 2007, Applied Microbiology and Biotechnology.

[47]  K. Balakrishna,et al.  Design and Verification , 2015 .

[48]  L Yerushalmi,et al.  Estimation of greenhouse gas generation in wastewater treatment plants--model development and application. , 2010, Chemosphere.

[49]  S. Itakura,et al.  Hydroxyl radical generation by an extracellular low-molecular-weight substance and phenol oxidase activity during wood degradation by the white-rot basidiomycete Trametes versicolor. , 1999, Journal of biotechnology.

[50]  Martha Salcudean,et al.  Computational modelling of large aerated lagoon hydraulics. , 2007, Water research.

[51]  Jing-tang Zheng,et al.  Photocatalytic treatment of wastewater from paper mill by TiO2 loaded on activated carbon fibers , 2007 .

[52]  A. Zaidi,et al.  Ultra- and Nano-Filtration in Advanced Effluent Treatment Schemes for Pollution Control in the Pulp and Paper Industry , 1992 .

[53]  Dard Hunter,et al.  Papermaking: The History and Technique of an Ancient Craft , 2011 .

[54]  Bilson Shukla.  Benefits of paper mill white water recovery using backwash filtration system , 2012 .

[55]  I. Thakur.  Screening and identification of microbial strains for removal of colour and adsorbable organic halogens in pulp and paper mill effluent , 2004 .

[56]  E. Souaya,et al.  A comparative study among different photochemical oxidation processes to enhance the biodegradability of paper mill wastewater. , 2011, Journal of hazardous materials.

[57]  Linyang Gu,et al.  Electrochemical oxidation of pulp and paper making wastewater assisted by transition metal modified kaolin. , 2007, Journal of hazardous materials.

[58]  R. Malisch,et al.  Increase of the PCDD/F-contamination of milk, butter and meat samples by use of contaminated citrus pulp. , 2000, Chemosphere.

[59]  John Gregory,et al.  Organic polyelectrolytes in water treatment. , 2007, Water research.

[60]  D. Jenkins,et al.  Unified theory of filamentous activated sludge bulking , 1978 .

[61]  Guohua Chen.  Electrochemical technologies in wastewater treatment , 2004 .

[62]  K. Vice,et al.  The cluster rule : A summary of phase I , 1998 .

[63]  C. Luthe,et al.  The role of dibenzo-p-dioxin and dibenzofuran precursors in the formation of tetrachlorinated dibenzo-p-dioxins/-furans during bleaching , 1996 .

[64]  B. Pavelić,et al.  Use of ozone , 2012 .

[65]  V. Chen,et al.  Fouling in Membrane Bioreactors , 2013 .

[66]  Hassan Pahlavanzadeh,et al.  Influence of different combinations of aluminum and iron electrode on electrocoagulation efficiency: Application to the treatment of paper mill wastewater , 2011 .

[67]  N. Durán,et al.  Advanced oxidation of a pulp mill bleaching wastewater. , 1999, Chemosphere.

[68]  A. B. Mckague.  Phenolic constituents in pulp mill process streams , 1981 .

[69]  Meisam Tabatabaei,et al.  Importance of the methanogenic archaea populations in anaerobic wastewater treatments , 2010 .

[70]  C. Chiemchaisri,et al.  Effects of ozonation process on lignin-derived compounds in pulp and paper mill effluents. , 2007, Journal of hazardous materials.

[71]  Francesc Torrades,et al.  Experimental design of Fenton and photo-Fenton reactions for the treatment of cellulose bleaching effluents. , 2003, Chemosphere.

[72]  J. Tiedje,et al.  Microbial reductive dehalogenation. , 1992, Microbiological reviews.

[73]  S. Baig,et al.  Ozone treatment for biorefractory COD removal. , 2001, Water science and technology : a journal of the International Association on Water Pollution Research.

[74]  Vivek V. Ranade,et al.  Industrial Wastewater Treatment, Recycling and Reuse , 2014 .

[75]  K. Eriksson,et al.  Microbial degradation of chlorolignins. , 1985, Environmental science & technology.

[76]  A. Oikari,et al.  Free and conjugated resin acids in the bile of rainbow trout,Salmo gairdneri , 1984, Bulletin of environmental contamination and toxicology.

[77]  Gustavo B. Menezes,et al.  Treatment of Pulp and Paper Mill Wastewater , 2012 .

[78]  Resources Canada.  Pulp and Paper Mills , 1983 .

[79]  R. Riffat.  Fundamentals of Wastewater Treatment and Engineering , 2012 .

[80]  D. G. Allen,et al.  Comparison of mesophilic and thermophilic aerobic biological treatment in sequencing batch reactors treating bleached kraft pulp mill effluent , 1999 .

[81]  F. Fiessinger,et al.  Aluminum chemistry in aqueous solution , 1989 .

[82]  M. Sain,et al.  Protein extraction from secondary sludge of paper mill wastewater and its utilization as a wood adhesive , 2011, BioResources.

[83]  F. Haghighat,et al.  Reductions in greenhouse gas (GHG) generation and energy consumption in wastewater treatment plants. , 2013, Water science and technology : a journal of the International Association on Water Pollution Research.

[84]  F. Kargı,et al.  Advanced oxidation treatment of pulp mill effluent for TOC and toxicity removals. , 2008, Journal of environmental management.

[85]  P. Weiland.  Biogas production: current state and perspectives , 2009, Applied Microbiology and Biotechnology.

[86]  J. K. Edzwald.  Dissolved air flotation and me. , 2010, Water research.

[87]  Chun-Han Ko,et al.  Enhanced chemical oxygen demand removal and flux reduction in pulp and paper wastewater treatment using laccase-polymerized membrane filtration. , 2010, Journal of hazardous materials.

[88]  B. D. Tripathi,et al.  Application of ozone based treatments of secondary effluents. , 2011, Bioresource technology.

[89]  B. F. Hrutfiord,et al.  Dioxin sources and mechanisms during pulp bleaching , 1992 .

[90]  Pierre Le-Clech,et al.  Fouling in membrane bioreactors used in wastewater treatment , 2006 .

[91]  R. Voss,et al.  An improved solvent-extraction based procedure for the gas chromatographic analysis of resin and fatty acids in pulp mill effluents , 1985 .

[92]  M. Marttinen,et al.  Food chain enrichment of organochlorine compounds and mercury in clean and polluted lakes of Finland , 1983 .

[93]  I. Ortiz,et al.  Assessment of PCDD/Fs formation in the Fenton oxidation of 2-chlorophenol: Influence of the iron dose applied. , 2015, Chemosphere.

[94]  J. Chovelon,et al.  The remediation of wastewater containing 4-chlorophenol using integrated photocatalytic and biological treatment. , 2010, Journal of photochemistry and photobiology. B, Biology.

[95]  F. M. Gama,et al.  Enzymatic versus chemical deinking of non-impact ink printed paper. , 2004, Journal of biotechnology.

[96]  J.-C. Lescot,et al.  Effluent treatment in pulp and paper mills: present technology and development trends , 1994 .

[97]  M. Gergov,et al.  Chlorinated organic compounds in effluent treatment at kraft mills , 1988 .

[98]  J. G. Dorica,et al.  Sludge dewatering practices at Canadian pulp and paper mills , 1999 .

[99]  L. Barton,et al.  Biochemistry, physiology and biotechnology of sulfate-reducing bacteria. , 2009, Advances in applied microbiology.

[100]  L. Chai,et al.  Biodegradation of kraft lignin by a bacterial strain Comamonas sp. B‐9 isolated from eroded bamboo slips , 2012, Journal of applied microbiology.

[101]  E. Fuente,et al.  Monitoring of Dissolved Air Flotation by Focused Beam Reflectance Measurement , 2006 .

[102]  I. Chairez,et al.  Remediation of lignin and its derivatives from pulp and paper industry wastewater by the combination of chemical precipitation and ozonation. , 2009, Journal of hazardous materials.

[103]  P. Bajpai,et al.  Reduction of organochlorine compounds in bleach plant effluents , 1997 .

[104]  G Thompson,et al.  The treatment of pulp and paper mill effluent: a review. , 2001, Bioresource technology.

[105]  M. Sillanpää,et al.  Effects of reaction conditions on nuclear laundry water treatment in Fenton process. , 2009, Journal of hazardous materials.

[106]  P. Dhakephalkar,et al.  Upflow anaerobic filter for the degradation of adsorbable organic halides (AOX) from bleach composite wastewater of pulp and paper industry. , 2009, Chemosphere.

[107]  A. Chopra,et al.  Removal of color, COD and lignin from Pulp and Paper Mill Effluent by Phanerochaete chrysosporium and Aspergillus fumigatus , 2012 .

[108]  N. Amin,et al.  Treatment of paper mill effluents in a batch-stirred electrochemical tank reactor , 2009 .

[109]  Debashis Bhattacharya,et al.  The New Possibility* , 1963 .

[110]  D. Lee,et al.  Sonication of pulp and paper effluent. , 2009, Ultrasonics sonochemistry.

[111]  Omprakash Sarkar,et al.  Bioelectrochemical treatment of paper and pulp wastewater in comparison with anaerobic process: integrating chemical coagulation with simultaneous power production. , 2014, Bioresource technology.

[112]  Jining Chen,et al.  Alternative policy assessment for water pollution control in China's pulp and paper industry , 2012 .

[113]  Effect of Process Parameters on Greenhouse Gas Generation by Wastewater Treatment Plants , 2011, Water environment research : a research publication of the Water Environment Federation.

[114]  L. Turrio-Baldassarri,et al.  PCDDs and PCDFs , 2013 .

[115]  Darja B. Žarković,et al.  Simple and cost-effective measures for the improvement of paper mill effluent treatment – A case study , 2011 .

[116]  H. Paulapuro,et al.  Removal of dissolved organic compounds from paper machine whitewater by membrane bioreactors: a comparative analysis , 1999 .

[117]  K. Kringstad,et al.  Spent liquors from pulp bleaching. , 1984, Environmental science & technology.

[118]  I. Vergili,et al.  The effect of transmembrane pressure and pH on treatment of paper machine process waters by using a two-step nanofiltration process: flux decline analysis. , 2010 .

[119]  G. Leslie,et al.  Comparison of treatment options for removal of recalcitrant dissolved organic matter from paper mill effluent. , 2010, Chemosphere.

[120]  I. Koster,et al.  Inhibition of Methanogenesis from Acetate in Granular Sludge by Long-Chain Fatty Acids , 1987, Applied and environmental microbiology.

[121]  L. Heuts,et al.  Full scale implementation of the nutrient limited BAS process at Södra Cell Värö. , 2004, Water science and technology : a journal of the International Association on Water Pollution Research.

[122]  You-ming Li,et al.  Effect of Ozonation on Recalcitrant Chemical Oxygen Demand (COD), Color, and Biodegradability of Hardwood Kraft Pulp (KP) Bleaching Effluent , 2014 .

[123]  J Rodríguez,et al.  Photocatalytic degradation of cellulose bleaching effluent by supported TiO2 and ZnO. , 2000, Chemosphere.

[124]  E. Strazdins.  The chemistry of alum in papermaking , 1986 .

[125]  M. I. Maldonado,et al.  Tertiary treatment of pulp mill wastewater by solar photo-Fenton. , 2012, Journal of hazardous materials.

[126]  J. Kallas,et al.  Combination of coagulation and catalytic wet oxidation for the treatment of pulp and paper mill effluents. , 2001, Water science and technology : a journal of the International Association on Water Pollution Research.