论文信息 - Superhyperfine interaction of the SiH3 radical with Xe

Superhyperfine interaction of the SiH3 radical with Xe

The SiH3 radical formed by the reaction of SiH4 with H in a Xe matrix was investigated by ESR spectroscopy. In addition to the spectra of the radicals SiH3 and SiH5 reported by the present authors [J. Chem. Phys. 83, 4504 (1985)], well resolved new lines were observed superimposed on a broad background signal. These lines were attributed to the superhyperfine structure of a species interacting with xenon nucleus. The magnetic parameters for the species which give rise to the superhyperfine structure were determined.

S. Sato | N. Masaki | K. Shimokoshi | K. Nakamura

[1] W. Weltner,et al. Si2, SiH3, and HSiO molecules: ESR at 4 K , 1985 .

[2] S. Sato,et al. Free radicals formed by reaction of silane with hydrogen atoms in rare gas matrices at very low temperatures , 1985 .

[3] P. Raghunathan,et al. On the anisotropic electron spin resonance spectroscopic parameters and motional states of matrix-isolated silyl (SiH3) radical at low temperatures , 1980 .

[4] A. N. Jette,et al. Anisotropic hyperfine interactions of rare‐gas nuclei near trapped hydrogen atomsa) , 1979 .

[5] J. Morton,et al. Atomic parameters for paramagnetic resonance data , 1978 .

[6] P. H. Kasai,et al. ESR Studies of Cu, Ag, and Au Atoms Isolated in Rare‐Gas Matrices , 1971 .

[7] W. Gordy,et al. Electron Spin Resonance of Free Radicals Formed from Group-IV and Group-V Hydrides in Inert Matrices at Low Temperature , 1968 .