Pipe Models for Entangled Fluids under Strong Shear
暂无分享,去创建一个
We study the rheology of polymers and other entangled fluids at high shear rate, where reptation theories (such as that of Doi and Edwards) predict, unphysically, a decreasing shear stress. A modification of the tube model, based on the concept of a dumbbell confined to a pipe, was recently proposed by Cates, McLeish, and Marrucci. We show that their heuristic calculations correspond to a situation where the transverse dimension dy of the dumbbell (perpendicular to the tube) remains constant in time. We perform an exact analysis, allowing dy to fluctuate subject to the constraint of the pipe, and also study a more detailed model-a Rouse chain confined to a pipe